Bromidotricarbon­yl[4-iodo-N-(pyridin-2-yl­methyl­idene)aniline-κ(2) N,N′]rhenium(I)

In the title compound, [ReBr(C(12)H(9)IN(2))(CO)(3)], the coordination geometry of the Re(I) ion is a distorted fac-ReC(3)BrN(2) octa­hedron, arising from the N,N′-bidentate ligand, a bromide ion and a facial arrangement of three carbonyl ligands. The dihedral angle between the aromatic rings in the...

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Detalles Bibliográficos
Autores principales: Dehghanpour, Saeed, Mahmoudi, Ali
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983412/
https://www.ncbi.nlm.nih.gov/pubmed/21587465
http://dx.doi.org/10.1107/S1600536810037104
Descripción
Sumario:In the title compound, [ReBr(C(12)H(9)IN(2))(CO)(3)], the coordination geometry of the Re(I) ion is a distorted fac-ReC(3)BrN(2) octa­hedron, arising from the N,N′-bidentate ligand, a bromide ion and a facial arrangement of three carbonyl ligands. The dihedral angle between the aromatic rings in the 4-iodo-N-(pyridin-2-yl­methyl­idene)aniline ligand is 46.2 (3)°. The bromide ion and its corresponding trans CO mol­ecule are disordered over two sets of sites in a 0.966 (3):0.034 (3) ratio.

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