(2,2′-Bipyridine-κ(2) N,N′)hydroxido[N-(4-tolyl­sulfonyl)­alaninato-κ(2) N,O (1)]copper(II) hemihydrate

In the title complex, [Cu(C(10)H(12)NO(4)S)(OH)(C(10)H(8)N(2))]·0.5H(2)O, the Cu(II) ion shows a distorted square-pyramidal coordination geometry with two N atoms from the 2,2′-bipyridine ligand and one N and one O atom from the N-tosyl-α-alaninato ligand forming the basis of the coordination polyhe...

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Detalles Bibliográficos
Autor principal: Huang, Miao-Ling
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983414/
https://www.ncbi.nlm.nih.gov/pubmed/21587449
http://dx.doi.org/10.1107/S1600536810037529
Descripción
Sumario:In the title complex, [Cu(C(10)H(12)NO(4)S)(OH)(C(10)H(8)N(2))]·0.5H(2)O, the Cu(II) ion shows a distorted square-pyramidal coordination geometry with two N atoms from the 2,2′-bipyridine ligand and one N and one O atom from the N-tosyl-α-alaninato ligand forming the basis of the coordination polyhedron and another O atom of the hydroxo group acting as the apex of the pyramid. The solvent water mol­ecule is statistically disordered over two positions.

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