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(2,2′-Bipyridine-κ(2) N,N′)hydroxido[N-(4-tolylsulfonyl)alaninato-κ(2) N,O (1)]copper(II) hemihydrate
In the title complex, [Cu(C(10)H(12)NO(4)S)(OH)(C(10)H(8)N(2))]·0.5H(2)O, the Cu(II) ion shows a distorted square-pyramidal coordination geometry with two N atoms from the 2,2′-bipyridine ligand and one N and one O atom from the N-tosyl-α-alaninato ligand forming the basis of the coordination polyhe...
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| Formato: | Texto |
| Lenguaje: | English |
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International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983414/ https://www.ncbi.nlm.nih.gov/pubmed/21587449 http://dx.doi.org/10.1107/S1600536810037529 |
| _version_ | 1782191876961468416 |
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| author | Huang, Miao-Ling |
| author_facet | Huang, Miao-Ling |
| author_sort | Huang, Miao-Ling |
| collection | PubMed |
| description | In the title complex, [Cu(C(10)H(12)NO(4)S)(OH)(C(10)H(8)N(2))]·0.5H(2)O, the Cu(II) ion shows a distorted square-pyramidal coordination geometry with two N atoms from the 2,2′-bipyridine ligand and one N and one O atom from the N-tosyl-α-alaninato ligand forming the basis of the coordination polyhedron and another O atom of the hydroxo group acting as the apex of the pyramid. The solvent water molecule is statistically disordered over two positions. |
| format | Text |
| id | pubmed-2983414 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29834142010-12-30 (2,2′-Bipyridine-κ(2) N,N′)hydroxido[N-(4-tolylsulfonyl)alaninato-κ(2) N,O (1)]copper(II) hemihydrate Huang, Miao-Ling Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cu(C(10)H(12)NO(4)S)(OH)(C(10)H(8)N(2))]·0.5H(2)O, the Cu(II) ion shows a distorted square-pyramidal coordination geometry with two N atoms from the 2,2′-bipyridine ligand and one N and one O atom from the N-tosyl-α-alaninato ligand forming the basis of the coordination polyhedron and another O atom of the hydroxo group acting as the apex of the pyramid. The solvent water molecule is statistically disordered over two positions. International Union of Crystallography 2010-09-30 /pmc/articles/PMC2983414/ /pubmed/21587449 http://dx.doi.org/10.1107/S1600536810037529 Text en © Miao-Ling Huang 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Huang, Miao-Ling (2,2′-Bipyridine-κ(2) N,N′)hydroxido[N-(4-tolylsulfonyl)alaninato-κ(2) N,O (1)]copper(II) hemihydrate |
| title | (2,2′-Bipyridine-κ(2)
N,N′)hydroxido[N-(4-tolylsulfonyl)alaninato-κ(2)
N,O
(1)]copper(II) hemihydrate |
| title_full | (2,2′-Bipyridine-κ(2)
N,N′)hydroxido[N-(4-tolylsulfonyl)alaninato-κ(2)
N,O
(1)]copper(II) hemihydrate |
| title_fullStr | (2,2′-Bipyridine-κ(2)
N,N′)hydroxido[N-(4-tolylsulfonyl)alaninato-κ(2)
N,O
(1)]copper(II) hemihydrate |
| title_full_unstemmed | (2,2′-Bipyridine-κ(2)
N,N′)hydroxido[N-(4-tolylsulfonyl)alaninato-κ(2)
N,O
(1)]copper(II) hemihydrate |
| title_short | (2,2′-Bipyridine-κ(2)
N,N′)hydroxido[N-(4-tolylsulfonyl)alaninato-κ(2)
N,O
(1)]copper(II) hemihydrate |
| title_sort | (2,2′-bipyridine-κ(2)
n,n′)hydroxido[n-(4-tolylsulfonyl)alaninato-κ(2)
n,o
(1)]copper(ii) hemihydrate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983414/ https://www.ncbi.nlm.nih.gov/pubmed/21587449 http://dx.doi.org/10.1107/S1600536810037529 |
| work_keys_str_mv | AT huangmiaoling 22bipyridinek2nnhydroxidon4tolylsulfonylalaninatok2no1copperiihemihydrate |