[Benz­yl(2-pyridyl­methyl­idene)amine]­dichloridomercury(II)

The Hg(II) ion in the title complex, [HgCl(2)(C(13)H(12)N(2))], adopts a distorted tetra­hedral geometry being coordinated by two Cl anions and by two N atoms of the benz­yl(2-pyridyl­methyl­ene)amine ligand. The Cl—Hg—Cl plane is twisted at 70.1 (1)° from the mean plane of the chelate ring. In the...

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Detalles Bibliográficos
Autores principales: Kim, Young-Inn, Kang, Sung Kwon
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983418/
https://www.ncbi.nlm.nih.gov/pubmed/21587400
http://dx.doi.org/10.1107/S1600536810035889
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author Kim, Young-Inn
Kang, Sung Kwon
author_facet Kim, Young-Inn
Kang, Sung Kwon
author_sort Kim, Young-Inn
collection PubMed
description The Hg(II) ion in the title complex, [HgCl(2)(C(13)H(12)N(2))], adopts a distorted tetra­hedral geometry being coordinated by two Cl anions and by two N atoms of the benz­yl(2-pyridyl­methyl­ene)amine ligand. The Cl—Hg—Cl plane is twisted at 70.1 (1)° from the mean plane of the chelate ring. In the crystal structure, inter­molecular π–π inter­actions [centroid–centroid distance = 3.793 (3) Å] between the aromatic rings link the mol­ecules into zigzag chains extending along [010].
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spelling pubmed-29834182010-12-30 [Benz­yl(2-pyridyl­methyl­idene)amine]­dichloridomercury(II) Kim, Young-Inn Kang, Sung Kwon Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Hg(II) ion in the title complex, [HgCl(2)(C(13)H(12)N(2))], adopts a distorted tetra­hedral geometry being coordinated by two Cl anions and by two N atoms of the benz­yl(2-pyridyl­methyl­ene)amine ligand. The Cl—Hg—Cl plane is twisted at 70.1 (1)° from the mean plane of the chelate ring. In the crystal structure, inter­molecular π–π inter­actions [centroid–centroid distance = 3.793 (3) Å] between the aromatic rings link the mol­ecules into zigzag chains extending along [010]. International Union of Crystallography 2010-09-11 /pmc/articles/PMC2983418/ /pubmed/21587400 http://dx.doi.org/10.1107/S1600536810035889 Text en © Kim and Kang 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kim, Young-Inn
Kang, Sung Kwon
[Benz­yl(2-pyridyl­methyl­idene)amine]­dichloridomercury(II)
title [Benz­yl(2-pyridyl­methyl­idene)amine]­dichloridomercury(II)
title_full [Benz­yl(2-pyridyl­methyl­idene)amine]­dichloridomercury(II)
title_fullStr [Benz­yl(2-pyridyl­methyl­idene)amine]­dichloridomercury(II)
title_full_unstemmed [Benz­yl(2-pyridyl­methyl­idene)amine]­dichloridomercury(II)
title_short [Benz­yl(2-pyridyl­methyl­idene)amine]­dichloridomercury(II)
title_sort [benz­yl(2-pyridyl­methyl­idene)amine]­dichloridomercury(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983418/
https://www.ncbi.nlm.nih.gov/pubmed/21587400
http://dx.doi.org/10.1107/S1600536810035889
work_keys_str_mv AT kimyounginn benzyl2pyridylmethylideneaminedichloridomercuryii
AT kangsungkwon benzyl2pyridylmethylideneaminedichloridomercuryii

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