tert-Butyl N-[(11-exo-benzyl­oxy­carbonyl-8-oxopenta­cyclo­[5.4.0.0(2,6).0(3,10).0(5,9)]undecane-11-endo-yloxy)carbon­yl­methyl]carbamate

The structure of the title compound, C(26)H(29)NO(7), at 173 K has an inter­molecular N—H⋯O hydrogen bond. This is one of the few examples where a mono-ketone penta­cyclo­undecane (PCU) mol­ecule exibits hydrogen bonding in the solid state. The dihedral angles of the amide and ester groups are norma...

Descripción completa

Detalles Bibliográficos
Autores principales: Karpoormath, Rajshekhar, Govender, Thavendran, Govender, Patrick, Kruger, Hendrik G., Maguire, Glenn E. M.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983419/
https://www.ncbi.nlm.nih.gov/pubmed/21587584
http://dx.doi.org/10.1107/S1600536810036627
_version_ 1782191878143213568
author Karpoormath, Rajshekhar
Govender, Thavendran
Govender, Patrick
Kruger, Hendrik G.
Maguire, Glenn E. M.
author_facet Karpoormath, Rajshekhar
Govender, Thavendran
Govender, Patrick
Kruger, Hendrik G.
Maguire, Glenn E. M.
author_sort Karpoormath, Rajshekhar
collection PubMed
description The structure of the title compound, C(26)H(29)NO(7), at 173 K has an inter­molecular N—H⋯O hydrogen bond. This is one of the few examples where a mono-ketone penta­cyclo­undecane (PCU) mol­ecule exibits hydrogen bonding in the solid state. The dihedral angles of the amide and ester groups are normal and unaffected by the cage structure. A longer than normal C—C bond [1.571 (4) Å] was found within the cage structure.
format Text
id pubmed-2983419
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29834192010-12-30 tert-Butyl N-[(11-exo-benzyl­oxy­carbonyl-8-oxopenta­cyclo­[5.4.0.0(2,6).0(3,10).0(5,9)]undecane-11-endo-yloxy)carbon­yl­methyl]carbamate Karpoormath, Rajshekhar Govender, Thavendran Govender, Patrick Kruger, Hendrik G. Maguire, Glenn E. M. Acta Crystallogr Sect E Struct Rep Online Organic Papers The structure of the title compound, C(26)H(29)NO(7), at 173 K has an inter­molecular N—H⋯O hydrogen bond. This is one of the few examples where a mono-ketone penta­cyclo­undecane (PCU) mol­ecule exibits hydrogen bonding in the solid state. The dihedral angles of the amide and ester groups are normal and unaffected by the cage structure. A longer than normal C—C bond [1.571 (4) Å] was found within the cage structure. International Union of Crystallography 2010-09-25 /pmc/articles/PMC2983419/ /pubmed/21587584 http://dx.doi.org/10.1107/S1600536810036627 Text en © Karpoormath et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Karpoormath, Rajshekhar
Govender, Thavendran
Govender, Patrick
Kruger, Hendrik G.
Maguire, Glenn E. M.
tert-Butyl N-[(11-exo-benzyl­oxy­carbonyl-8-oxopenta­cyclo­[5.4.0.0(2,6).0(3,10).0(5,9)]undecane-11-endo-yloxy)carbon­yl­methyl]carbamate
title tert-Butyl N-[(11-exo-benzyl­oxy­carbonyl-8-oxopenta­cyclo­[5.4.0.0(2,6).0(3,10).0(5,9)]undecane-11-endo-yloxy)carbon­yl­methyl]carbamate
title_full tert-Butyl N-[(11-exo-benzyl­oxy­carbonyl-8-oxopenta­cyclo­[5.4.0.0(2,6).0(3,10).0(5,9)]undecane-11-endo-yloxy)carbon­yl­methyl]carbamate
title_fullStr tert-Butyl N-[(11-exo-benzyl­oxy­carbonyl-8-oxopenta­cyclo­[5.4.0.0(2,6).0(3,10).0(5,9)]undecane-11-endo-yloxy)carbon­yl­methyl]carbamate
title_full_unstemmed tert-Butyl N-[(11-exo-benzyl­oxy­carbonyl-8-oxopenta­cyclo­[5.4.0.0(2,6).0(3,10).0(5,9)]undecane-11-endo-yloxy)carbon­yl­methyl]carbamate
title_short tert-Butyl N-[(11-exo-benzyl­oxy­carbonyl-8-oxopenta­cyclo­[5.4.0.0(2,6).0(3,10).0(5,9)]undecane-11-endo-yloxy)carbon­yl­methyl]carbamate
title_sort tert-butyl n-[(11-exo-benzyl­oxy­carbonyl-8-oxopenta­cyclo­[5.4.0.0(2,6).0(3,10).0(5,9)]undecane-11-endo-yloxy)carbon­yl­methyl]carbamate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983419/
https://www.ncbi.nlm.nih.gov/pubmed/21587584
http://dx.doi.org/10.1107/S1600536810036627
work_keys_str_mv AT karpoormathrajshekhar tertbutyln11exobenzyloxycarbonyl8oxopentacyclo5400260310059undecane11endoyloxycarbonylmethylcarbamate
AT govenderthavendran tertbutyln11exobenzyloxycarbonyl8oxopentacyclo5400260310059undecane11endoyloxycarbonylmethylcarbamate
AT govenderpatrick tertbutyln11exobenzyloxycarbonyl8oxopentacyclo5400260310059undecane11endoyloxycarbonylmethylcarbamate
AT krugerhendrikg tertbutyln11exobenzyloxycarbonyl8oxopentacyclo5400260310059undecane11endoyloxycarbonylmethylcarbamate
AT maguireglennem tertbutyln11exobenzyloxycarbonyl8oxopentacyclo5400260310059undecane11endoyloxycarbonylmethylcarbamate

Ejemplares similares