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tert-Butyl N-[(11-exo-benzyloxycarbonyl-8-oxopentacyclo[5.4.0.0(2,6).0(3,10).0(5,9)]undecane-11-endo-yloxy)carbonylmethyl]carbamate
The structure of the title compound, C(26)H(29)NO(7), at 173 K has an intermolecular N—H⋯O hydrogen bond. This is one of the few examples where a mono-ketone pentacycloundecane (PCU) molecule exibits hydrogen bonding in the solid state. The dihedral angles of the amide and ester groups are norma...
Autores principales: | Karpoormath, Rajshekhar, Govender, Thavendran, Govender, Patrick, Kruger, Hendrik G., Maguire, Glenn E. M. |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983419/ https://www.ncbi.nlm.nih.gov/pubmed/21587584 http://dx.doi.org/10.1107/S1600536810036627 |
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