8-Hy­droxy-2-methyl­quinolinium dibromido(2-methyl­quinolin-8-olato-κ(2) N,O)zincate(II) methanol monosolvate

The anion of the title salt, (C(10)H(10)NO)[ZnBr(2)(C(10)H(8)NO)]·CH(3)OH, has its metal atom N,O-chelated by the deprotonated 2-methyl-8-hy­droxy­quinoline ligand. The hy­droxy unit of the cation is a hydrogen-bond donor to the alkoxide O atom of the tetra­hedrally coordinated anion, whereas the am...

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Detalles Bibliográficos
Autores principales: Najafi, Ezzatollah, Amini, Mostafa M., Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983420/
https://www.ncbi.nlm.nih.gov/pubmed/21587420
http://dx.doi.org/10.1107/S1600536810036706
Descripción
Sumario:The anion of the title salt, (C(10)H(10)NO)[ZnBr(2)(C(10)H(8)NO)]·CH(3)OH, has its metal atom N,O-chelated by the deprotonated 2-methyl-8-hy­droxy­quinoline ligand. The hy­droxy unit of the cation is a hydrogen-bond donor to the alkoxide O atom of the tetra­hedrally coordinated anion, whereas the ammonium cation is a hydrogen-bond donor to the methano­lic O atom. In the crystal, adjacent ion pairs and solvent mol­ecules are linked by a methanol–halogen O—H⋯Br hydrogen bond, generating a chain running along the a axis.

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