8-Hy­droxy-2-methyl­quinolinium dibromido(2-methyl­quinolin-8-olato-κ(2) N,O)zincate(II) methanol monosolvate

The anion of the title salt, (C(10)H(10)NO)[ZnBr(2)(C(10)H(8)NO)]·CH(3)OH, has its metal atom N,O-chelated by the deprotonated 2-methyl-8-hy­droxy­quinoline ligand. The hy­droxy unit of the cation is a hydrogen-bond donor to the alkoxide O atom of the tetra­hedrally coordinated anion, whereas the am...

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Detalles Bibliográficos
Autores principales: Najafi, Ezzatollah, Amini, Mostafa M., Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983420/
https://www.ncbi.nlm.nih.gov/pubmed/21587420
http://dx.doi.org/10.1107/S1600536810036706
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author Najafi, Ezzatollah
Amini, Mostafa M.
Ng, Seik Weng
author_facet Najafi, Ezzatollah
Amini, Mostafa M.
Ng, Seik Weng
author_sort Najafi, Ezzatollah
collection PubMed
description The anion of the title salt, (C(10)H(10)NO)[ZnBr(2)(C(10)H(8)NO)]·CH(3)OH, has its metal atom N,O-chelated by the deprotonated 2-methyl-8-hy­droxy­quinoline ligand. The hy­droxy unit of the cation is a hydrogen-bond donor to the alkoxide O atom of the tetra­hedrally coordinated anion, whereas the ammonium cation is a hydrogen-bond donor to the methano­lic O atom. In the crystal, adjacent ion pairs and solvent mol­ecules are linked by a methanol–halogen O—H⋯Br hydrogen bond, generating a chain running along the a axis.
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spelling pubmed-29834202010-12-30 8-Hy­droxy-2-methyl­quinolinium dibromido(2-methyl­quinolin-8-olato-κ(2) N,O)zincate(II) methanol monosolvate Najafi, Ezzatollah Amini, Mostafa M. Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The anion of the title salt, (C(10)H(10)NO)[ZnBr(2)(C(10)H(8)NO)]·CH(3)OH, has its metal atom N,O-chelated by the deprotonated 2-methyl-8-hy­droxy­quinoline ligand. The hy­droxy unit of the cation is a hydrogen-bond donor to the alkoxide O atom of the tetra­hedrally coordinated anion, whereas the ammonium cation is a hydrogen-bond donor to the methano­lic O atom. In the crystal, adjacent ion pairs and solvent mol­ecules are linked by a methanol–halogen O—H⋯Br hydrogen bond, generating a chain running along the a axis. International Union of Crystallography 2010-09-18 /pmc/articles/PMC2983420/ /pubmed/21587420 http://dx.doi.org/10.1107/S1600536810036706 Text en © Najafi et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Najafi, Ezzatollah
Amini, Mostafa M.
Ng, Seik Weng
8-Hy­droxy-2-methyl­quinolinium dibromido(2-methyl­quinolin-8-olato-κ(2) N,O)zincate(II) methanol monosolvate
title 8-Hy­droxy-2-methyl­quinolinium dibromido(2-methyl­quinolin-8-olato-κ(2) N,O)zincate(II) methanol monosolvate
title_full 8-Hy­droxy-2-methyl­quinolinium dibromido(2-methyl­quinolin-8-olato-κ(2) N,O)zincate(II) methanol monosolvate
title_fullStr 8-Hy­droxy-2-methyl­quinolinium dibromido(2-methyl­quinolin-8-olato-κ(2) N,O)zincate(II) methanol monosolvate
title_full_unstemmed 8-Hy­droxy-2-methyl­quinolinium dibromido(2-methyl­quinolin-8-olato-κ(2) N,O)zincate(II) methanol monosolvate
title_short 8-Hy­droxy-2-methyl­quinolinium dibromido(2-methyl­quinolin-8-olato-κ(2) N,O)zincate(II) methanol monosolvate
title_sort 8-hy­droxy-2-methyl­quinolinium dibromido(2-methyl­quinolin-8-olato-κ(2) n,o)zincate(ii) methanol monosolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983420/
https://www.ncbi.nlm.nih.gov/pubmed/21587420
http://dx.doi.org/10.1107/S1600536810036706
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AT aminimostafam 8hydroxy2methylquinoliniumdibromido2methylquinolin8olatok2nozincateiimethanolmonosolvate
AT ngseikweng 8hydroxy2methylquinoliniumdibromido2methylquinolin8olatok2nozincateiimethanolmonosolvate

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