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1,1′-(p-Phenyl­enedimethyl­ene)dipyridinium bis­(hexa­fluoridophosphate)

The title salt, C(18)H(18)N(2) (2+)·2PF(6) (−), exists as non-inter­acting cations and anions. In the cation, the pyridine and phenyl­ene rings are aligned at 62.9 (1)°; the pyridine ring lies on a special position of m site symmetry and the phenyl­ene ring on a special position of 2/m site symmetry...

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Detalles Bibliográficos
Autores principales: Abdul Rahim, Munirah Sufiyah, Alias, Yatimah, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983422/
https://www.ncbi.nlm.nih.gov/pubmed/21587624
http://dx.doi.org/10.1107/S1600536810037992
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author Abdul Rahim, Munirah Sufiyah
Alias, Yatimah
Ng, Seik Weng
author_facet Abdul Rahim, Munirah Sufiyah
Alias, Yatimah
Ng, Seik Weng
author_sort Abdul Rahim, Munirah Sufiyah
collection PubMed
description The title salt, C(18)H(18)N(2) (2+)·2PF(6) (−), exists as non-inter­acting cations and anions. In the cation, the pyridine and phenyl­ene rings are aligned at 62.9 (1)°; the pyridine ring lies on a special position of m site symmetry and the phenyl­ene ring on a special position of 2/m site symmetry. The angle at the methyl­ene C atom is 112.8 (1)°. The anion lies on a special position of m site symmetry; four F atoms lie on this mirror plane.
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spelling pubmed-29834222010-12-30 1,1′-(p-Phenyl­enedimethyl­ene)dipyridinium bis­(hexa­fluoridophosphate) Abdul Rahim, Munirah Sufiyah Alias, Yatimah Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Organic Papers The title salt, C(18)H(18)N(2) (2+)·2PF(6) (−), exists as non-inter­acting cations and anions. In the cation, the pyridine and phenyl­ene rings are aligned at 62.9 (1)°; the pyridine ring lies on a special position of m site symmetry and the phenyl­ene ring on a special position of 2/m site symmetry. The angle at the methyl­ene C atom is 112.8 (1)°. The anion lies on a special position of m site symmetry; four F atoms lie on this mirror plane. International Union of Crystallography 2010-09-30 /pmc/articles/PMC2983422/ /pubmed/21587624 http://dx.doi.org/10.1107/S1600536810037992 Text en © Abdul Rahim et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Abdul Rahim, Munirah Sufiyah
Alias, Yatimah
Ng, Seik Weng
1,1′-(p-Phenyl­enedimethyl­ene)dipyridinium bis­(hexa­fluoridophosphate)
title 1,1′-(p-Phenyl­enedimethyl­ene)dipyridinium bis­(hexa­fluoridophosphate)
title_full 1,1′-(p-Phenyl­enedimethyl­ene)dipyridinium bis­(hexa­fluoridophosphate)
title_fullStr 1,1′-(p-Phenyl­enedimethyl­ene)dipyridinium bis­(hexa­fluoridophosphate)
title_full_unstemmed 1,1′-(p-Phenyl­enedimethyl­ene)dipyridinium bis­(hexa­fluoridophosphate)
title_short 1,1′-(p-Phenyl­enedimethyl­ene)dipyridinium bis­(hexa­fluoridophosphate)
title_sort 1,1′-(p-phenyl­enedimethyl­ene)dipyridinium bis­(hexa­fluoridophosphate)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983422/
https://www.ncbi.nlm.nih.gov/pubmed/21587624
http://dx.doi.org/10.1107/S1600536810037992
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