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catena-Poly[bis(μ(4)-adipato-1:2:1′:2′κ(4) O (1):O (1′):O (4):O (4′))bis(N,N-dimethylformamide)-1κO,2κO-dicopper(II)]
In the title polymeric complex, [Cu(2)(C(6)H(8)O(4))(2)(C(3)H(7)NO)(2)](n), the carboxylate groups of the approximately U-shaped adipate dianion each bridge a pair of inversion-related, DMF-coordinated copper(II) atoms, generating a ribbon motif that runs along the b axis. The geometry of the coppe...
| Autores principales: | , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983426/ https://www.ncbi.nlm.nih.gov/pubmed/21587406 http://dx.doi.org/10.1107/S1600536810036093 |
| _version_ | 1782191879817789440 |
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| author | Wu, Guo-Yun Ng, Seik Weng |
| author_facet | Wu, Guo-Yun Ng, Seik Weng |
| author_sort | Wu, Guo-Yun |
| collection | PubMed |
| description | In the title polymeric complex, [Cu(2)(C(6)H(8)O(4))(2)(C(3)H(7)NO)(2)](n), the carboxylate groups of the approximately U-shaped adipate dianion each bridge a pair of inversion-related, DMF-coordinated copper(II) atoms, generating a ribbon motif that runs along the b axis. The geometry of the copper(II) atom is distorted square-pyramidal; the apical site is occupied by the O atom of the DMF molecule whereas the four basal sites are occupied by carboxylate O atoms. |
| format | Text |
| id | pubmed-2983426 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29834262010-12-30 catena-Poly[bis(μ(4)-adipato-1:2:1′:2′κ(4) O (1):O (1′):O (4):O (4′))bis(N,N-dimethylformamide)-1κO,2κO-dicopper(II)] Wu, Guo-Yun Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title polymeric complex, [Cu(2)(C(6)H(8)O(4))(2)(C(3)H(7)NO)(2)](n), the carboxylate groups of the approximately U-shaped adipate dianion each bridge a pair of inversion-related, DMF-coordinated copper(II) atoms, generating a ribbon motif that runs along the b axis. The geometry of the copper(II) atom is distorted square-pyramidal; the apical site is occupied by the O atom of the DMF molecule whereas the four basal sites are occupied by carboxylate O atoms. International Union of Crystallography 2010-09-15 /pmc/articles/PMC2983426/ /pubmed/21587406 http://dx.doi.org/10.1107/S1600536810036093 Text en © Wu and Ng 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Wu, Guo-Yun Ng, Seik Weng catena-Poly[bis(μ(4)-adipato-1:2:1′:2′κ(4) O (1):O (1′):O (4):O (4′))bis(N,N-dimethylformamide)-1κO,2κO-dicopper(II)] |
| title |
catena-Poly[bis(μ(4)-adipato-1:2:1′:2′κ(4)
O
(1):O
(1′):O
(4):O
(4′))bis(N,N-dimethylformamide)-1κO,2κO-dicopper(II)] |
| title_full |
catena-Poly[bis(μ(4)-adipato-1:2:1′:2′κ(4)
O
(1):O
(1′):O
(4):O
(4′))bis(N,N-dimethylformamide)-1κO,2κO-dicopper(II)] |
| title_fullStr |
catena-Poly[bis(μ(4)-adipato-1:2:1′:2′κ(4)
O
(1):O
(1′):O
(4):O
(4′))bis(N,N-dimethylformamide)-1κO,2κO-dicopper(II)] |
| title_full_unstemmed |
catena-Poly[bis(μ(4)-adipato-1:2:1′:2′κ(4)
O
(1):O
(1′):O
(4):O
(4′))bis(N,N-dimethylformamide)-1κO,2κO-dicopper(II)] |
| title_short |
catena-Poly[bis(μ(4)-adipato-1:2:1′:2′κ(4)
O
(1):O
(1′):O
(4):O
(4′))bis(N,N-dimethylformamide)-1κO,2κO-dicopper(II)] |
| title_sort | catena-poly[bis(μ(4)-adipato-1:2:1′:2′κ(4)
o
(1):o
(1′):o
(4):o
(4′))bis(n,n-dimethylformamide)-1κo,2κo-dicopper(ii)] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983426/ https://www.ncbi.nlm.nih.gov/pubmed/21587406 http://dx.doi.org/10.1107/S1600536810036093 |
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