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Bis(3-methyl­phenolato-κO)(nitros­yl-κN)[tris­(3,5-dimethyl­pyrazol-1-yl-κN (2))hydridoborato]molybdenum(II)

The title complex, [Mo(C(15)H(22)BN(6))(C(7)H(7)O)(2)(NO)], contains an {MoNO}(4) core stabilized by κ(3)­-hydrotris­(3,5-dimethyl­pyrazol-1-yl)borate, [Tp(Me2)](−), and two anionic m-cresolate ligands, leading to a distorted octa­hedral geometry for the Mo atom. The short Mo—O bond lengths [1.935 (...

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Detalles Bibliográficos
Autores principales: Nitek, Wojciech, Romańczyk, Piotr P., Lubera, Tomasz, Włodarczyk, Andrzej J.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983427/
https://www.ncbi.nlm.nih.gov/pubmed/21587390
http://dx.doi.org/10.1107/S1600536810033763
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author Nitek, Wojciech
Romańczyk, Piotr P.
Lubera, Tomasz
Włodarczyk, Andrzej J.
author_facet Nitek, Wojciech
Romańczyk, Piotr P.
Lubera, Tomasz
Włodarczyk, Andrzej J.
author_sort Nitek, Wojciech
collection PubMed
description The title complex, [Mo(C(15)H(22)BN(6))(C(7)H(7)O)(2)(NO)], contains an {MoNO}(4) core stabilized by κ(3)­-hydrotris­(3,5-dimethyl­pyrazol-1-yl)borate, [Tp(Me2)](−), and two anionic m-cresolate ligands, leading to a distorted octa­hedral geometry for the Mo atom. The short Mo—O bond lengths [1.935 (2) and 1.971 (2) Å], as well as large Mo—O—Csp (2) angles [134.2 (2) and 143.54 (19)°], indicate dπ(Mo)—pπ(O) inter­actions, which are clearly weaker when compared with {Mo(NO)(Tp(Me2))} alkoxides. The nitrosyl system is virtually linear [179.3 (3)°] with Mo—N and N—O bond lengths of 1.760 (2) and 1.205 (3) Å, respectively. Intra- and inter­molecular C—H((Ph or CH(3)))⋯π((Ph)) inter­actions between adjacent phenyl rings are found in the crystal structure (d (H⋯Ph) in the range 2.743–2.886 Å). One of the Ph rings shows disorder, i.e. swinging in the ring plane.
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spelling pubmed-29834272010-12-30 Bis(3-methyl­phenolato-κO)(nitros­yl-κN)[tris­(3,5-dimethyl­pyrazol-1-yl-κN (2))hydridoborato]molybdenum(II) Nitek, Wojciech Romańczyk, Piotr P. Lubera, Tomasz Włodarczyk, Andrzej J. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Mo(C(15)H(22)BN(6))(C(7)H(7)O)(2)(NO)], contains an {MoNO}(4) core stabilized by κ(3)­-hydrotris­(3,5-dimethyl­pyrazol-1-yl)borate, [Tp(Me2)](−), and two anionic m-cresolate ligands, leading to a distorted octa­hedral geometry for the Mo atom. The short Mo—O bond lengths [1.935 (2) and 1.971 (2) Å], as well as large Mo—O—Csp (2) angles [134.2 (2) and 143.54 (19)°], indicate dπ(Mo)—pπ(O) inter­actions, which are clearly weaker when compared with {Mo(NO)(Tp(Me2))} alkoxides. The nitrosyl system is virtually linear [179.3 (3)°] with Mo—N and N—O bond lengths of 1.760 (2) and 1.205 (3) Å, respectively. Intra- and inter­molecular C—H((Ph or CH(3)))⋯π((Ph)) inter­actions between adjacent phenyl rings are found in the crystal structure (d (H⋯Ph) in the range 2.743–2.886 Å). One of the Ph rings shows disorder, i.e. swinging in the ring plane. International Union of Crystallography 2010-09-11 /pmc/articles/PMC2983427/ /pubmed/21587390 http://dx.doi.org/10.1107/S1600536810033763 Text en © Nitek et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Nitek, Wojciech
Romańczyk, Piotr P.
Lubera, Tomasz
Włodarczyk, Andrzej J.
Bis(3-methyl­phenolato-κO)(nitros­yl-κN)[tris­(3,5-dimethyl­pyrazol-1-yl-κN (2))hydridoborato]molybdenum(II)
title Bis(3-methyl­phenolato-κO)(nitros­yl-κN)[tris­(3,5-dimethyl­pyrazol-1-yl-κN (2))hydridoborato]molybdenum(II)
title_full Bis(3-methyl­phenolato-κO)(nitros­yl-κN)[tris­(3,5-dimethyl­pyrazol-1-yl-κN (2))hydridoborato]molybdenum(II)
title_fullStr Bis(3-methyl­phenolato-κO)(nitros­yl-κN)[tris­(3,5-dimethyl­pyrazol-1-yl-κN (2))hydridoborato]molybdenum(II)
title_full_unstemmed Bis(3-methyl­phenolato-κO)(nitros­yl-κN)[tris­(3,5-dimethyl­pyrazol-1-yl-κN (2))hydridoborato]molybdenum(II)
title_short Bis(3-methyl­phenolato-κO)(nitros­yl-κN)[tris­(3,5-dimethyl­pyrazol-1-yl-κN (2))hydridoborato]molybdenum(II)
title_sort bis(3-methyl­phenolato-κo)(nitros­yl-κn)[tris­(3,5-dimethyl­pyrazol-1-yl-κn (2))hydridoborato]molybdenum(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983427/
https://www.ncbi.nlm.nih.gov/pubmed/21587390
http://dx.doi.org/10.1107/S1600536810033763
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