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2-[(E)-4-(Diethylamino)styryl]-1-methylpyridinium iodide
In the title compound, C(18)H(23)N(2) (+)·I(−), the cation exists in the E configuration with respect to the ethenyl C=C bond. The pyridinium and benzene rings are nearly coplanar, making a dihedral angle of 4.63 (7)°. The two ethyl groups of the diethylamino substituent point in opposite direction...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983428/ https://www.ncbi.nlm.nih.gov/pubmed/21587611 http://dx.doi.org/10.1107/S1600536810037505 |
Sumario: | In the title compound, C(18)H(23)N(2) (+)·I(−), the cation exists in the E configuration with respect to the ethenyl C=C bond. The pyridinium and benzene rings are nearly coplanar, making a dihedral angle of 4.63 (7)°. The two ethyl groups of the diethylamino substituent point in opposite directions with respect to the benzene plane. In the crystal, the cation and the iodide anion are linked by a weak C—H⋯I interaction. The cations are stacked in an anti-parallel manner along the a axis by a π–π interaction with a centroid–centroid distance of 3.5262 (9) Å. The crystal structure is further stabilized by C—H⋯π interactions. |
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