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2-[(E)-4-(Diethyl­amino)­styr­yl]-1-methyl­pyridinium iodide

In the title compound, C(18)H(23)N(2) (+)·I(−), the cation exists in the E configuration with respect to the ethenyl C=C bond. The pyridinium and benzene rings are nearly coplanar, making a dihedral angle of 4.63 (7)°. The two ethyl groups of the diethyl­amino substituent point in opposite direction...

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Detalles Bibliográficos
Autores principales: Kaewmanee, Narissara, Chanawanno, Kullapa, Chantrapromma, Suchada, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983428/
https://www.ncbi.nlm.nih.gov/pubmed/21587611
http://dx.doi.org/10.1107/S1600536810037505
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author Kaewmanee, Narissara
Chanawanno, Kullapa
Chantrapromma, Suchada
Fun, Hoong-Kun
author_facet Kaewmanee, Narissara
Chanawanno, Kullapa
Chantrapromma, Suchada
Fun, Hoong-Kun
author_sort Kaewmanee, Narissara
collection PubMed
description In the title compound, C(18)H(23)N(2) (+)·I(−), the cation exists in the E configuration with respect to the ethenyl C=C bond. The pyridinium and benzene rings are nearly coplanar, making a dihedral angle of 4.63 (7)°. The two ethyl groups of the diethyl­amino substituent point in opposite directions with respect to the benzene plane. In the crystal, the cation and the iodide anion are linked by a weak C—H⋯I inter­action. The cations are stacked in an anti-parallel manner along the a axis by a π–π inter­action with a centroid–centroid distance of 3.5262 (9) Å. The crystal structure is further stabilized by C—H⋯π inter­actions.
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spelling pubmed-29834282010-12-30 2-[(E)-4-(Diethyl­amino)­styr­yl]-1-methyl­pyridinium iodide Kaewmanee, Narissara Chanawanno, Kullapa Chantrapromma, Suchada Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(18)H(23)N(2) (+)·I(−), the cation exists in the E configuration with respect to the ethenyl C=C bond. The pyridinium and benzene rings are nearly coplanar, making a dihedral angle of 4.63 (7)°. The two ethyl groups of the diethyl­amino substituent point in opposite directions with respect to the benzene plane. In the crystal, the cation and the iodide anion are linked by a weak C—H⋯I inter­action. The cations are stacked in an anti-parallel manner along the a axis by a π–π inter­action with a centroid–centroid distance of 3.5262 (9) Å. The crystal structure is further stabilized by C—H⋯π inter­actions. International Union of Crystallography 2010-09-25 /pmc/articles/PMC2983428/ /pubmed/21587611 http://dx.doi.org/10.1107/S1600536810037505 Text en © Kaewmanee et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kaewmanee, Narissara
Chanawanno, Kullapa
Chantrapromma, Suchada
Fun, Hoong-Kun
2-[(E)-4-(Diethyl­amino)­styr­yl]-1-methyl­pyridinium iodide
title 2-[(E)-4-(Diethyl­amino)­styr­yl]-1-methyl­pyridinium iodide
title_full 2-[(E)-4-(Diethyl­amino)­styr­yl]-1-methyl­pyridinium iodide
title_fullStr 2-[(E)-4-(Diethyl­amino)­styr­yl]-1-methyl­pyridinium iodide
title_full_unstemmed 2-[(E)-4-(Diethyl­amino)­styr­yl]-1-methyl­pyridinium iodide
title_short 2-[(E)-4-(Diethyl­amino)­styr­yl]-1-methyl­pyridinium iodide
title_sort 2-[(e)-4-(diethyl­amino)­styr­yl]-1-methyl­pyridinium iodide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983428/
https://www.ncbi.nlm.nih.gov/pubmed/21587611
http://dx.doi.org/10.1107/S1600536810037505
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