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2-[(E)-4-(Diethylamino)styryl]-1-methylpyridinium iodide
In the title compound, C(18)H(23)N(2) (+)·I(−), the cation exists in the E configuration with respect to the ethenyl C=C bond. The pyridinium and benzene rings are nearly coplanar, making a dihedral angle of 4.63 (7)°. The two ethyl groups of the diethylamino substituent point in opposite direction...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983428/ https://www.ncbi.nlm.nih.gov/pubmed/21587611 http://dx.doi.org/10.1107/S1600536810037505 |
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author | Kaewmanee, Narissara Chanawanno, Kullapa Chantrapromma, Suchada Fun, Hoong-Kun |
author_facet | Kaewmanee, Narissara Chanawanno, Kullapa Chantrapromma, Suchada Fun, Hoong-Kun |
author_sort | Kaewmanee, Narissara |
collection | PubMed |
description | In the title compound, C(18)H(23)N(2) (+)·I(−), the cation exists in the E configuration with respect to the ethenyl C=C bond. The pyridinium and benzene rings are nearly coplanar, making a dihedral angle of 4.63 (7)°. The two ethyl groups of the diethylamino substituent point in opposite directions with respect to the benzene plane. In the crystal, the cation and the iodide anion are linked by a weak C—H⋯I interaction. The cations are stacked in an anti-parallel manner along the a axis by a π–π interaction with a centroid–centroid distance of 3.5262 (9) Å. The crystal structure is further stabilized by C—H⋯π interactions. |
format | Text |
id | pubmed-2983428 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29834282010-12-30 2-[(E)-4-(Diethylamino)styryl]-1-methylpyridinium iodide Kaewmanee, Narissara Chanawanno, Kullapa Chantrapromma, Suchada Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(18)H(23)N(2) (+)·I(−), the cation exists in the E configuration with respect to the ethenyl C=C bond. The pyridinium and benzene rings are nearly coplanar, making a dihedral angle of 4.63 (7)°. The two ethyl groups of the diethylamino substituent point in opposite directions with respect to the benzene plane. In the crystal, the cation and the iodide anion are linked by a weak C—H⋯I interaction. The cations are stacked in an anti-parallel manner along the a axis by a π–π interaction with a centroid–centroid distance of 3.5262 (9) Å. The crystal structure is further stabilized by C—H⋯π interactions. International Union of Crystallography 2010-09-25 /pmc/articles/PMC2983428/ /pubmed/21587611 http://dx.doi.org/10.1107/S1600536810037505 Text en © Kaewmanee et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Kaewmanee, Narissara Chanawanno, Kullapa Chantrapromma, Suchada Fun, Hoong-Kun 2-[(E)-4-(Diethylamino)styryl]-1-methylpyridinium iodide |
title | 2-[(E)-4-(Diethylamino)styryl]-1-methylpyridinium iodide |
title_full | 2-[(E)-4-(Diethylamino)styryl]-1-methylpyridinium iodide |
title_fullStr | 2-[(E)-4-(Diethylamino)styryl]-1-methylpyridinium iodide |
title_full_unstemmed | 2-[(E)-4-(Diethylamino)styryl]-1-methylpyridinium iodide |
title_short | 2-[(E)-4-(Diethylamino)styryl]-1-methylpyridinium iodide |
title_sort | 2-[(e)-4-(diethylamino)styryl]-1-methylpyridinium iodide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983428/ https://www.ncbi.nlm.nih.gov/pubmed/21587611 http://dx.doi.org/10.1107/S1600536810037505 |
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