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Aqua{N-[(4-methylphenyl)sulfonyl]glycinato(2−)-κ(2) N,O}(1,10-phenanthroline)copper(II)
In the title complex, [Cu(C(9)H(9)NO(4)S)(C(12)H(8)N(2))(H(2)O)], the Cu(II) ion is coordinated in a distorted square-pyramidal geometry by the two N atoms from a 1,10-phenanthroline ligand, one N atom from the deprotonated amino group of an N-tosylglycinate ligand, one O atom from the carboxylate...
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983433/ https://www.ncbi.nlm.nih.gov/pubmed/21587403 http://dx.doi.org/10.1107/S1600536810036135 |
Sumario: | In the title complex, [Cu(C(9)H(9)NO(4)S)(C(12)H(8)N(2))(H(2)O)], the Cu(II) ion is coordinated in a distorted square-pyramidal geometry by the two N atoms from a 1,10-phenanthroline ligand, one N atom from the deprotonated amino group of an N-tosylglycinate ligand, one O atom from the carboxylate part of the N-tosylglycinate ligand and a water O atom. Intermolecular O—H⋯O hydrogen bonds involving the water H atoms link neighboring molecules into supramolecular chains along [010]. Weak π–π stacking interactions [centroid–centroid distances of 3.456 (1) and 3.691 (1) Å] between the benzene rings of 1,10-phenanthroline ligands of adjacent molecules extend the chains into a layer structure parallel to (001). |
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