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Aqua{N-[(4-methylphenyl)sulfonyl]glycinato(2−)-κ(2) N,O}(1,10-phenanthroline)copper(II)
In the title complex, [Cu(C(9)H(9)NO(4)S)(C(12)H(8)N(2))(H(2)O)], the Cu(II) ion is coordinated in a distorted square-pyramidal geometry by the two N atoms from a 1,10-phenanthroline ligand, one N atom from the deprotonated amino group of an N-tosylglycinate ligand, one O atom from the carboxylate...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983433/ https://www.ncbi.nlm.nih.gov/pubmed/21587403 http://dx.doi.org/10.1107/S1600536810036135 |
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author | Huang, Miao-Ling |
author_facet | Huang, Miao-Ling |
author_sort | Huang, Miao-Ling |
collection | PubMed |
description | In the title complex, [Cu(C(9)H(9)NO(4)S)(C(12)H(8)N(2))(H(2)O)], the Cu(II) ion is coordinated in a distorted square-pyramidal geometry by the two N atoms from a 1,10-phenanthroline ligand, one N atom from the deprotonated amino group of an N-tosylglycinate ligand, one O atom from the carboxylate part of the N-tosylglycinate ligand and a water O atom. Intermolecular O—H⋯O hydrogen bonds involving the water H atoms link neighboring molecules into supramolecular chains along [010]. Weak π–π stacking interactions [centroid–centroid distances of 3.456 (1) and 3.691 (1) Å] between the benzene rings of 1,10-phenanthroline ligands of adjacent molecules extend the chains into a layer structure parallel to (001). |
format | Text |
id | pubmed-2983433 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29834332010-12-30 Aqua{N-[(4-methylphenyl)sulfonyl]glycinato(2−)-κ(2) N,O}(1,10-phenanthroline)copper(II) Huang, Miao-Ling Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cu(C(9)H(9)NO(4)S)(C(12)H(8)N(2))(H(2)O)], the Cu(II) ion is coordinated in a distorted square-pyramidal geometry by the two N atoms from a 1,10-phenanthroline ligand, one N atom from the deprotonated amino group of an N-tosylglycinate ligand, one O atom from the carboxylate part of the N-tosylglycinate ligand and a water O atom. Intermolecular O—H⋯O hydrogen bonds involving the water H atoms link neighboring molecules into supramolecular chains along [010]. Weak π–π stacking interactions [centroid–centroid distances of 3.456 (1) and 3.691 (1) Å] between the benzene rings of 1,10-phenanthroline ligands of adjacent molecules extend the chains into a layer structure parallel to (001). International Union of Crystallography 2010-09-15 /pmc/articles/PMC2983433/ /pubmed/21587403 http://dx.doi.org/10.1107/S1600536810036135 Text en © Miao-Ling Huang 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Huang, Miao-Ling Aqua{N-[(4-methylphenyl)sulfonyl]glycinato(2−)-κ(2) N,O}(1,10-phenanthroline)copper(II) |
title | Aqua{N-[(4-methylphenyl)sulfonyl]glycinato(2−)-κ(2)
N,O}(1,10-phenanthroline)copper(II) |
title_full | Aqua{N-[(4-methylphenyl)sulfonyl]glycinato(2−)-κ(2)
N,O}(1,10-phenanthroline)copper(II) |
title_fullStr | Aqua{N-[(4-methylphenyl)sulfonyl]glycinato(2−)-κ(2)
N,O}(1,10-phenanthroline)copper(II) |
title_full_unstemmed | Aqua{N-[(4-methylphenyl)sulfonyl]glycinato(2−)-κ(2)
N,O}(1,10-phenanthroline)copper(II) |
title_short | Aqua{N-[(4-methylphenyl)sulfonyl]glycinato(2−)-κ(2)
N,O}(1,10-phenanthroline)copper(II) |
title_sort | aqua{n-[(4-methylphenyl)sulfonyl]glycinato(2−)-κ(2)
n,o}(1,10-phenanthroline)copper(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983433/ https://www.ncbi.nlm.nih.gov/pubmed/21587403 http://dx.doi.org/10.1107/S1600536810036135 |
work_keys_str_mv | AT huangmiaoling aquan4methylphenylsulfonylglycinato2k2no110phenanthrolinecopperii |