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Aqua­{N-[(4-methyl­phen­yl)sulfon­yl]glycinato(2−)-κ(2) N,O}(1,10-phenan­throline)copper(II)

In the title complex, [Cu(C(9)H(9)NO(4)S)(C(12)H(8)N(2))(H(2)O)], the Cu(II) ion is coordinated in a distorted square-pyramidal geometry by the two N atoms from a 1,10-phenanthroline ligand, one N atom from the deprotonated amino group of an N-tosyl­glycinate ligand, one O atom from the carboxyl­ate...

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Autor principal: Huang, Miao-Ling
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983433/
https://www.ncbi.nlm.nih.gov/pubmed/21587403
http://dx.doi.org/10.1107/S1600536810036135
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author Huang, Miao-Ling
author_facet Huang, Miao-Ling
author_sort Huang, Miao-Ling
collection PubMed
description In the title complex, [Cu(C(9)H(9)NO(4)S)(C(12)H(8)N(2))(H(2)O)], the Cu(II) ion is coordinated in a distorted square-pyramidal geometry by the two N atoms from a 1,10-phenanthroline ligand, one N atom from the deprotonated amino group of an N-tosyl­glycinate ligand, one O atom from the carboxyl­ate part of the N-tosyl­glycinate ligand and a water O atom. Inter­molecular O—H⋯O hydrogen bonds involving the water H atoms link neighboring mol­ecules into supra­molecular chains along [010]. Weak π–π stacking inter­actions [centroid–centroid distances of 3.456 (1) and 3.691 (1) Å] between the benzene rings of 1,10-phenanthroline ligands of adjacent mol­ecules extend the chains into a layer structure parallel to (001).
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spelling pubmed-29834332010-12-30 Aqua­{N-[(4-methyl­phen­yl)sulfon­yl]glycinato(2−)-κ(2) N,O}(1,10-phenan­throline)copper(II) Huang, Miao-Ling Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cu(C(9)H(9)NO(4)S)(C(12)H(8)N(2))(H(2)O)], the Cu(II) ion is coordinated in a distorted square-pyramidal geometry by the two N atoms from a 1,10-phenanthroline ligand, one N atom from the deprotonated amino group of an N-tosyl­glycinate ligand, one O atom from the carboxyl­ate part of the N-tosyl­glycinate ligand and a water O atom. Inter­molecular O—H⋯O hydrogen bonds involving the water H atoms link neighboring mol­ecules into supra­molecular chains along [010]. Weak π–π stacking inter­actions [centroid–centroid distances of 3.456 (1) and 3.691 (1) Å] between the benzene rings of 1,10-phenanthroline ligands of adjacent mol­ecules extend the chains into a layer structure parallel to (001). International Union of Crystallography 2010-09-15 /pmc/articles/PMC2983433/ /pubmed/21587403 http://dx.doi.org/10.1107/S1600536810036135 Text en © Miao-Ling Huang 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Huang, Miao-Ling
Aqua­{N-[(4-methyl­phen­yl)sulfon­yl]glycinato(2−)-κ(2) N,O}(1,10-phenan­throline)copper(II)
title Aqua­{N-[(4-methyl­phen­yl)sulfon­yl]glycinato(2−)-κ(2) N,O}(1,10-phenan­throline)copper(II)
title_full Aqua­{N-[(4-methyl­phen­yl)sulfon­yl]glycinato(2−)-κ(2) N,O}(1,10-phenan­throline)copper(II)
title_fullStr Aqua­{N-[(4-methyl­phen­yl)sulfon­yl]glycinato(2−)-κ(2) N,O}(1,10-phenan­throline)copper(II)
title_full_unstemmed Aqua­{N-[(4-methyl­phen­yl)sulfon­yl]glycinato(2−)-κ(2) N,O}(1,10-phenan­throline)copper(II)
title_short Aqua­{N-[(4-methyl­phen­yl)sulfon­yl]glycinato(2−)-κ(2) N,O}(1,10-phenan­throline)copper(II)
title_sort aqua­{n-[(4-methyl­phen­yl)sulfon­yl]glycinato(2−)-κ(2) n,o}(1,10-phenan­throline)copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983433/
https://www.ncbi.nlm.nih.gov/pubmed/21587403
http://dx.doi.org/10.1107/S1600536810036135
work_keys_str_mv AT huangmiaoling aquan4methylphenylsulfonylglycinato2k2no110phenanthrolinecopperii