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Bis[μ-N,N′-bis(2,6-diisopropylphenyl)ethene-1,2-diamido]-1,4(η(2));1:2κ(4) N:N;3:4κ(4) N:N-bis(diethyl ether)-1κO,4κO-di-μ-hydrido-2:3κ(4) H:H-2,3-dichromium(II)-1,4-dilithium(I) pentane hemisolvate

The title compound, [Cr(2)Li(2)(C(26)H(36)N(2))(2)(μ-H)(2)(C(4)H(10)O)(2)]·0.5C(5)H(12), is a binuclear chromium complex bridged by two hydrogen atoms. Each chromium atom is coordinated in a distorted square-planar geometry by one chelating bis­(2,6-diisopropyl­phen­yl)ethene-1,2-diamido ligand via...

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Detalles Bibliográficos
Autores principales: Peitz, Stephan, Peulecke, Normen, Müller, Bernd H., Spannenberg, Anke, Rosenthal, Uwe
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983495/
https://www.ncbi.nlm.nih.gov/pubmed/21580241
http://dx.doi.org/10.1107/S160053681000560X
Descripción
Sumario:The title compound, [Cr(2)Li(2)(C(26)H(36)N(2))(2)(μ-H)(2)(C(4)H(10)O)(2)]·0.5C(5)H(12), is a binuclear chromium complex bridged by two hydrogen atoms. Each chromium atom is coordinated in a distorted square-planar geometry by one chelating bis­(2,6-diisopropyl­phen­yl)ethene-1,2-diamido ligand via its two N atoms. Additionally, two diametrically opposed lithium ether adducts coordinate in an η(4) mode on the backbone of the ligands. There is a crystallographic inversion center in the middle of the Cr(2)H(2) ring. One of the isopropyl groups is disordered over two positions in a 0.567 (7):0.433 (7) ratio. Disorder is also observed in the pentane hemisolvate molecule.