7-Chloro-4-[(E)-2-(2-methoxy­benzyl­idene)hydrazin-1-yl]quinoline monohydrate

In the title hydrate, C(17)H(14)ClN(3)O·H(2)O, the dihedral angle between the quinoline fused-ring system and the benzene ring is 13.4 (2)° and the conformation about the C=N bond is E. In the crystal, N(h)—H⋯O(w) and O(w)—H⋯N(q) (h = hydro­zone, w = water and q = quinoline) hydrogen bonds generate...

Descripción completa

Detalles Bibliográficos
Autores principales: de Souza, Marcus V. N., Howie, R. Alan, Tiekink, Edward R. T., Wardell, James L., Wardell, Solange M. S. V., Kaiser, Carlos R.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983501/
https://www.ncbi.nlm.nih.gov/pubmed/21580438
http://dx.doi.org/10.1107/S1600536810006586
_version_ 1782191887330836480
author de Souza, Marcus V. N.
Howie, R. Alan
Tiekink, Edward R. T.
Wardell, James L.
Wardell, Solange M. S. V.
Kaiser, Carlos R.
author_facet de Souza, Marcus V. N.
Howie, R. Alan
Tiekink, Edward R. T.
Wardell, James L.
Wardell, Solange M. S. V.
Kaiser, Carlos R.
author_sort de Souza, Marcus V. N.
collection PubMed
description In the title hydrate, C(17)H(14)ClN(3)O·H(2)O, the dihedral angle between the quinoline fused-ring system and the benzene ring is 13.4 (2)° and the conformation about the C=N bond is E. In the crystal, N(h)—H⋯O(w) and O(w)—H⋯N(q) (h = hydro­zone, w = water and q = quinoline) hydrogen bonds generate a two-dimenstional network in the ac plane. A weak C—H⋯O inter­action helps to consolidate the packing.
format Text
id pubmed-2983501
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29835012010-12-30 7-Chloro-4-[(E)-2-(2-methoxy­benzyl­idene)hydrazin-1-yl]quinoline monohydrate de Souza, Marcus V. N. Howie, R. Alan Tiekink, Edward R. T. Wardell, James L. Wardell, Solange M. S. V. Kaiser, Carlos R. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title hydrate, C(17)H(14)ClN(3)O·H(2)O, the dihedral angle between the quinoline fused-ring system and the benzene ring is 13.4 (2)° and the conformation about the C=N bond is E. In the crystal, N(h)—H⋯O(w) and O(w)—H⋯N(q) (h = hydro­zone, w = water and q = quinoline) hydrogen bonds generate a two-dimenstional network in the ac plane. A weak C—H⋯O inter­action helps to consolidate the packing. International Union of Crystallography 2010-02-27 /pmc/articles/PMC2983501/ /pubmed/21580438 http://dx.doi.org/10.1107/S1600536810006586 Text en © Souza et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
de Souza, Marcus V. N.
Howie, R. Alan
Tiekink, Edward R. T.
Wardell, James L.
Wardell, Solange M. S. V.
Kaiser, Carlos R.
7-Chloro-4-[(E)-2-(2-methoxy­benzyl­idene)hydrazin-1-yl]quinoline monohydrate
title 7-Chloro-4-[(E)-2-(2-methoxy­benzyl­idene)hydrazin-1-yl]quinoline monohydrate
title_full 7-Chloro-4-[(E)-2-(2-methoxy­benzyl­idene)hydrazin-1-yl]quinoline monohydrate
title_fullStr 7-Chloro-4-[(E)-2-(2-methoxy­benzyl­idene)hydrazin-1-yl]quinoline monohydrate
title_full_unstemmed 7-Chloro-4-[(E)-2-(2-methoxy­benzyl­idene)hydrazin-1-yl]quinoline monohydrate
title_short 7-Chloro-4-[(E)-2-(2-methoxy­benzyl­idene)hydrazin-1-yl]quinoline monohydrate
title_sort 7-chloro-4-[(e)-2-(2-methoxy­benzyl­idene)hydrazin-1-yl]quinoline monohydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983501/
https://www.ncbi.nlm.nih.gov/pubmed/21580438
http://dx.doi.org/10.1107/S1600536810006586
work_keys_str_mv AT desouzamarcusvn 7chloro4e22methoxybenzylidenehydrazin1ylquinolinemonohydrate
AT howieralan 7chloro4e22methoxybenzylidenehydrazin1ylquinolinemonohydrate
AT tiekinkedwardrt 7chloro4e22methoxybenzylidenehydrazin1ylquinolinemonohydrate
AT wardelljamesl 7chloro4e22methoxybenzylidenehydrazin1ylquinolinemonohydrate
AT wardellsolangemsv 7chloro4e22methoxybenzylidenehydrazin1ylquinolinemonohydrate
AT kaisercarlosr 7chloro4e22methoxybenzylidenehydrazin1ylquinolinemonohydrate

Ejemplares similares