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Bis{N-[bis(pyrrolidin-1-yl)phosphoryl]-2,2,2-trichloroacetamide}dinitratodioxidouranium(VI)
The crystal structure of the title compound, [U(NO(3))(2)O(2)(C(10)H(17)Cl(3)N(3)O(2)P)(2)], is composed of centrosymmetric [UO(2)(L)(2)(NO(3))(2)] molecules {L is N-[bis(pyrrolidin-1-yl)phosphoryl]-2,2,2-trichloroacetamide, C(10)H(17)Cl(3)N(3)O(2)P}. The U(VI) ion, located on an inversion cente...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983502/ https://www.ncbi.nlm.nih.gov/pubmed/21580260 http://dx.doi.org/10.1107/S1600536810006422 |
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| author | Znovjyak, Kateryna O. Ovchynnikov, Vladimir A. Moroz, Olesia V. Shishkina, Svitlana V. Amirkhanov, Vladimir M. |
| author_facet | Znovjyak, Kateryna O. Ovchynnikov, Vladimir A. Moroz, Olesia V. Shishkina, Svitlana V. Amirkhanov, Vladimir M. |
| author_sort | Znovjyak, Kateryna O. |
| collection | PubMed |
| description | The crystal structure of the title compound, [U(NO(3))(2)O(2)(C(10)H(17)Cl(3)N(3)O(2)P)(2)], is composed of centrosymmetric [UO(2)(L)(2)(NO(3))(2)] molecules {L is N-[bis(pyrrolidin-1-yl)phosphoryl]-2,2,2-trichloroacetamide, C(10)H(17)Cl(3)N(3)O(2)P}. The U(VI) ion, located on an inversion center, is eight-coordinated with axial oxido ligands and six equatorial oxygen atoms of the phosphoryl and nitrate groups in a slightly distorted hexagonal-bipyramidal geometry. One of the pyrrolidine fragments in the ligand is disordered over two conformation (occupancy ratio 0.58:0.42). Intramolecular N—H⋯O hydrogen bonds between the amine and nitrate groups are found. |
| format | Text |
| id | pubmed-2983502 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29835022010-12-30 Bis{N-[bis(pyrrolidin-1-yl)phosphoryl]-2,2,2-trichloroacetamide}dinitratodioxidouranium(VI) Znovjyak, Kateryna O. Ovchynnikov, Vladimir A. Moroz, Olesia V. Shishkina, Svitlana V. Amirkhanov, Vladimir M. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The crystal structure of the title compound, [U(NO(3))(2)O(2)(C(10)H(17)Cl(3)N(3)O(2)P)(2)], is composed of centrosymmetric [UO(2)(L)(2)(NO(3))(2)] molecules {L is N-[bis(pyrrolidin-1-yl)phosphoryl]-2,2,2-trichloroacetamide, C(10)H(17)Cl(3)N(3)O(2)P}. The U(VI) ion, located on an inversion center, is eight-coordinated with axial oxido ligands and six equatorial oxygen atoms of the phosphoryl and nitrate groups in a slightly distorted hexagonal-bipyramidal geometry. One of the pyrrolidine fragments in the ligand is disordered over two conformation (occupancy ratio 0.58:0.42). Intramolecular N—H⋯O hydrogen bonds between the amine and nitrate groups are found. International Union of Crystallography 2010-02-24 /pmc/articles/PMC2983502/ /pubmed/21580260 http://dx.doi.org/10.1107/S1600536810006422 Text en © Znovjyak et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Znovjyak, Kateryna O. Ovchynnikov, Vladimir A. Moroz, Olesia V. Shishkina, Svitlana V. Amirkhanov, Vladimir M. Bis{N-[bis(pyrrolidin-1-yl)phosphoryl]-2,2,2-trichloroacetamide}dinitratodioxidouranium(VI) |
| title | Bis{N-[bis(pyrrolidin-1-yl)phosphoryl]-2,2,2-trichloroacetamide}dinitratodioxidouranium(VI) |
| title_full | Bis{N-[bis(pyrrolidin-1-yl)phosphoryl]-2,2,2-trichloroacetamide}dinitratodioxidouranium(VI) |
| title_fullStr | Bis{N-[bis(pyrrolidin-1-yl)phosphoryl]-2,2,2-trichloroacetamide}dinitratodioxidouranium(VI) |
| title_full_unstemmed | Bis{N-[bis(pyrrolidin-1-yl)phosphoryl]-2,2,2-trichloroacetamide}dinitratodioxidouranium(VI) |
| title_short | Bis{N-[bis(pyrrolidin-1-yl)phosphoryl]-2,2,2-trichloroacetamide}dinitratodioxidouranium(VI) |
| title_sort | bis{n-[bis(pyrrolidin-1-yl)phosphoryl]-2,2,2-trichloroacetamide}dinitratodioxidouranium(vi) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983502/ https://www.ncbi.nlm.nih.gov/pubmed/21580260 http://dx.doi.org/10.1107/S1600536810006422 |
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