3-(1-Methyl-3-imidazolio)propane­sulfonate: a precursor to a Brønsted acid ionic liquid

The title compound, C(7)H(12)N(2)O(3)S, is a zwitterion precursor to a Brønsted acid ionic liquid with potential as an acid catalyst. The C—N—C—C torsion angle of 100.05 (8)° allows the positively charged imidazolium head group and the negatively charged sulfonate group to inter­act with neighboring...

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Detalles Bibliográficos
Autores principales: Reichert, W. Matthew, Trulove, Paul C., De Long, Hugh C.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983509/
https://www.ncbi.nlm.nih.gov/pubmed/21580354
http://dx.doi.org/10.1107/S1600536810004344
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author Reichert, W. Matthew
Trulove, Paul C.
De Long, Hugh C.
author_facet Reichert, W. Matthew
Trulove, Paul C.
De Long, Hugh C.
author_sort Reichert, W. Matthew
collection PubMed
description The title compound, C(7)H(12)N(2)O(3)S, is a zwitterion precursor to a Brønsted acid ionic liquid with potential as an acid catalyst. The C—N—C—C torsion angle of 100.05 (8)° allows the positively charged imidazolium head group and the negatively charged sulfonate group to inter­act with neighboring zwitterions, forming a C—H⋯O hydrogen-bonding network; the shortest among these inter­actions is 2.9512 (9) Å. The C—H⋯O inter­actions can be described by graph-set notation as two R (2) (2)(16) and one R (2) (2)(5) hydrogen-bonded rings.
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spelling pubmed-29835092010-12-30 3-(1-Methyl-3-imidazolio)propane­sulfonate: a precursor to a Brønsted acid ionic liquid Reichert, W. Matthew Trulove, Paul C. De Long, Hugh C. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(7)H(12)N(2)O(3)S, is a zwitterion precursor to a Brønsted acid ionic liquid with potential as an acid catalyst. The C—N—C—C torsion angle of 100.05 (8)° allows the positively charged imidazolium head group and the negatively charged sulfonate group to inter­act with neighboring zwitterions, forming a C—H⋯O hydrogen-bonding network; the shortest among these inter­actions is 2.9512 (9) Å. The C—H⋯O inter­actions can be described by graph-set notation as two R (2) (2)(16) and one R (2) (2)(5) hydrogen-bonded rings. International Union of Crystallography 2010-02-13 /pmc/articles/PMC2983509/ /pubmed/21580354 http://dx.doi.org/10.1107/S1600536810004344 Text en © Reichert et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Reichert, W. Matthew
Trulove, Paul C.
De Long, Hugh C.
3-(1-Methyl-3-imidazolio)propane­sulfonate: a precursor to a Brønsted acid ionic liquid
title 3-(1-Methyl-3-imidazolio)propane­sulfonate: a precursor to a Brønsted acid ionic liquid
title_full 3-(1-Methyl-3-imidazolio)propane­sulfonate: a precursor to a Brønsted acid ionic liquid
title_fullStr 3-(1-Methyl-3-imidazolio)propane­sulfonate: a precursor to a Brønsted acid ionic liquid
title_full_unstemmed 3-(1-Methyl-3-imidazolio)propane­sulfonate: a precursor to a Brønsted acid ionic liquid
title_short 3-(1-Methyl-3-imidazolio)propane­sulfonate: a precursor to a Brønsted acid ionic liquid
title_sort 3-(1-methyl-3-imidazolio)propane­sulfonate: a precursor to a brønsted acid ionic liquid
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983509/
https://www.ncbi.nlm.nih.gov/pubmed/21580354
http://dx.doi.org/10.1107/S1600536810004344
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AT trulovepaulc 31methyl3imidazoliopropanesulfonateaprecursortoabrønstedacidionicliquid
AT delonghughc 31methyl3imidazoliopropanesulfonateaprecursortoabrønstedacidionicliquid

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