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Decaaqua-1κ(5) O,4κ(5) O-bis(μ-nitrilotriacetato)-1:2κ(5) O:N,O′,O′′,O′′′;3:4κ(5) N,O,O′,O′′:O′′′-μ-oxido-2:3κ(2) O:O-diperoxido-2κ(2) O,O′;3κ(2) O,O′-1,4-dicopper(II)-2,3-dititanium(IV) heptahydrate
The tetranuclear title compound, [Cu(2)Ti(2)(C(6)H(6)NO(6))(2)O(O(2))(2)(H(2)O)(10)]·7H(2)O, lies about a twofold rotation axis that passes through the bridging oxide atom. The titanium atom is N,O,O′,O′′-chelated by the nitrilotriacetate and O,O′-chelated by the peroidxo group and is coordinated...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983515/ https://www.ncbi.nlm.nih.gov/pubmed/21580221 http://dx.doi.org/10.1107/S1600536810004198 |
| _version_ | 1782191890673696768 |
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| author | Xie, Xiao-Hua Wang, Bai-Mu Ng, Seik Weng |
| author_facet | Xie, Xiao-Hua Wang, Bai-Mu Ng, Seik Weng |
| author_sort | Xie, Xiao-Hua |
| collection | PubMed |
| description | The tetranuclear title compound, [Cu(2)Ti(2)(C(6)H(6)NO(6))(2)O(O(2))(2)(H(2)O)(10)]·7H(2)O, lies about a twofold rotation axis that passes through the bridging oxide atom. The titanium atom is N,O,O′,O′′-chelated by the nitrilotriacetate and O,O′-chelated by the peroidxo group and is coordinated to the bridging O atom in an overall pentagonal-bipyramidal geometry. The O atom of one of the carboxylate –CO(2) groups binds to the water-coordinated Cu atom, whose coordination polyhedron is an elongated octahedron. Adjacent tetranuclear molecules are linked through the coordinated and uncoordinated water molecules by O—H⋯O hydrogen bonds into a three-dimensional network. |
| format | Text |
| id | pubmed-2983515 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29835152010-12-30 Decaaqua-1κ(5) O,4κ(5) O-bis(μ-nitrilotriacetato)-1:2κ(5) O:N,O′,O′′,O′′′;3:4κ(5) N,O,O′,O′′:O′′′-μ-oxido-2:3κ(2) O:O-diperoxido-2κ(2) O,O′;3κ(2) O,O′-1,4-dicopper(II)-2,3-dititanium(IV) heptahydrate Xie, Xiao-Hua Wang, Bai-Mu Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The tetranuclear title compound, [Cu(2)Ti(2)(C(6)H(6)NO(6))(2)O(O(2))(2)(H(2)O)(10)]·7H(2)O, lies about a twofold rotation axis that passes through the bridging oxide atom. The titanium atom is N,O,O′,O′′-chelated by the nitrilotriacetate and O,O′-chelated by the peroidxo group and is coordinated to the bridging O atom in an overall pentagonal-bipyramidal geometry. The O atom of one of the carboxylate –CO(2) groups binds to the water-coordinated Cu atom, whose coordination polyhedron is an elongated octahedron. Adjacent tetranuclear molecules are linked through the coordinated and uncoordinated water molecules by O—H⋯O hydrogen bonds into a three-dimensional network. International Union of Crystallography 2010-02-06 /pmc/articles/PMC2983515/ /pubmed/21580221 http://dx.doi.org/10.1107/S1600536810004198 Text en © Xie et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Xie, Xiao-Hua Wang, Bai-Mu Ng, Seik Weng Decaaqua-1κ(5) O,4κ(5) O-bis(μ-nitrilotriacetato)-1:2κ(5) O:N,O′,O′′,O′′′;3:4κ(5) N,O,O′,O′′:O′′′-μ-oxido-2:3κ(2) O:O-diperoxido-2κ(2) O,O′;3κ(2) O,O′-1,4-dicopper(II)-2,3-dititanium(IV) heptahydrate |
| title | Decaaqua-1κ(5)
O,4κ(5)
O-bis(μ-nitrilotriacetato)-1:2κ(5)
O:N,O′,O′′,O′′′;3:4κ(5)
N,O,O′,O′′:O′′′-μ-oxido-2:3κ(2)
O:O-diperoxido-2κ(2)
O,O′;3κ(2)
O,O′-1,4-dicopper(II)-2,3-dititanium(IV) heptahydrate |
| title_full | Decaaqua-1κ(5)
O,4κ(5)
O-bis(μ-nitrilotriacetato)-1:2κ(5)
O:N,O′,O′′,O′′′;3:4κ(5)
N,O,O′,O′′:O′′′-μ-oxido-2:3κ(2)
O:O-diperoxido-2κ(2)
O,O′;3κ(2)
O,O′-1,4-dicopper(II)-2,3-dititanium(IV) heptahydrate |
| title_fullStr | Decaaqua-1κ(5)
O,4κ(5)
O-bis(μ-nitrilotriacetato)-1:2κ(5)
O:N,O′,O′′,O′′′;3:4κ(5)
N,O,O′,O′′:O′′′-μ-oxido-2:3κ(2)
O:O-diperoxido-2κ(2)
O,O′;3κ(2)
O,O′-1,4-dicopper(II)-2,3-dititanium(IV) heptahydrate |
| title_full_unstemmed | Decaaqua-1κ(5)
O,4κ(5)
O-bis(μ-nitrilotriacetato)-1:2κ(5)
O:N,O′,O′′,O′′′;3:4κ(5)
N,O,O′,O′′:O′′′-μ-oxido-2:3κ(2)
O:O-diperoxido-2κ(2)
O,O′;3κ(2)
O,O′-1,4-dicopper(II)-2,3-dititanium(IV) heptahydrate |
| title_short | Decaaqua-1κ(5)
O,4κ(5)
O-bis(μ-nitrilotriacetato)-1:2κ(5)
O:N,O′,O′′,O′′′;3:4κ(5)
N,O,O′,O′′:O′′′-μ-oxido-2:3κ(2)
O:O-diperoxido-2κ(2)
O,O′;3κ(2)
O,O′-1,4-dicopper(II)-2,3-dititanium(IV) heptahydrate |
| title_sort | decaaqua-1κ(5)
o,4κ(5)
o-bis(μ-nitrilotriacetato)-1:2κ(5)
o:n,o′,o′′,o′′′;3:4κ(5)
n,o,o′,o′′:o′′′-μ-oxido-2:3κ(2)
o:o-diperoxido-2κ(2)
o,o′;3κ(2)
o,o′-1,4-dicopper(ii)-2,3-dititanium(iv) heptahydrate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983515/ https://www.ncbi.nlm.nih.gov/pubmed/21580221 http://dx.doi.org/10.1107/S1600536810004198 |
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