Bis(phenyl­sulfin­yl)methane

Two independent mol­ecules comprise the asymmetric unit of the title compound, C(13)H(12)O(2)S(2), which differ in terms of minor variations in the relative orientations of the benzene rings [the O–S–C–C torsion angles for the first independent mol­ecule are −6.66 (17) and −12.88 (19)° compared with...

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Detalles Bibliográficos
Autores principales: Wardell, Solange M. S. V., de Lima, Geraldo M., Wardell, James L., Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983518/
https://www.ncbi.nlm.nih.gov/pubmed/21580405
http://dx.doi.org/10.1107/S1600536810005957
Descripción
Sumario:Two independent mol­ecules comprise the asymmetric unit of the title compound, C(13)H(12)O(2)S(2), which differ in terms of minor variations in the relative orientations of the benzene rings [the O–S–C–C torsion angles for the first independent mol­ecule are −6.66 (17) and −12.88 (19)° compared with −21.70 (18) and 4.83 (16)° for the second mol­ecule]. Supra­molecular chains sustained by C—H⋯O contacts and aligned along the a axis are found in the crystal structure. These are held in place in the three dimensional structure by C—H⋯π inter­actions.

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