Bis(phenyl­sulfin­yl)methane

Two independent mol­ecules comprise the asymmetric unit of the title compound, C(13)H(12)O(2)S(2), which differ in terms of minor variations in the relative orientations of the benzene rings [the O–S–C–C torsion angles for the first independent mol­ecule are −6.66 (17) and −12.88 (19)° compared with...

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Detalles Bibliográficos
Autores principales: Wardell, Solange M. S. V., de Lima, Geraldo M., Wardell, James L., Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983518/
https://www.ncbi.nlm.nih.gov/pubmed/21580405
http://dx.doi.org/10.1107/S1600536810005957
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author Wardell, Solange M. S. V.
de Lima, Geraldo M.
Wardell, James L.
Tiekink, Edward R. T.
author_facet Wardell, Solange M. S. V.
de Lima, Geraldo M.
Wardell, James L.
Tiekink, Edward R. T.
author_sort Wardell, Solange M. S. V.
collection PubMed
description Two independent mol­ecules comprise the asymmetric unit of the title compound, C(13)H(12)O(2)S(2), which differ in terms of minor variations in the relative orientations of the benzene rings [the O–S–C–C torsion angles for the first independent mol­ecule are −6.66 (17) and −12.88 (19)° compared with −21.70 (18) and 4.83 (16)° for the second mol­ecule]. Supra­molecular chains sustained by C—H⋯O contacts and aligned along the a axis are found in the crystal structure. These are held in place in the three dimensional structure by C—H⋯π inter­actions.
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spelling pubmed-29835182010-12-30 Bis(phenyl­sulfin­yl)methane Wardell, Solange M. S. V. de Lima, Geraldo M. Wardell, James L. Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers Two independent mol­ecules comprise the asymmetric unit of the title compound, C(13)H(12)O(2)S(2), which differ in terms of minor variations in the relative orientations of the benzene rings [the O–S–C–C torsion angles for the first independent mol­ecule are −6.66 (17) and −12.88 (19)° compared with −21.70 (18) and 4.83 (16)° for the second mol­ecule]. Supra­molecular chains sustained by C—H⋯O contacts and aligned along the a axis are found in the crystal structure. These are held in place in the three dimensional structure by C—H⋯π inter­actions. International Union of Crystallography 2010-02-20 /pmc/articles/PMC2983518/ /pubmed/21580405 http://dx.doi.org/10.1107/S1600536810005957 Text en © Wardell et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Wardell, Solange M. S. V.
de Lima, Geraldo M.
Wardell, James L.
Tiekink, Edward R. T.
Bis(phenyl­sulfin­yl)methane
title Bis(phenyl­sulfin­yl)methane
title_full Bis(phenyl­sulfin­yl)methane
title_fullStr Bis(phenyl­sulfin­yl)methane
title_full_unstemmed Bis(phenyl­sulfin­yl)methane
title_short Bis(phenyl­sulfin­yl)methane
title_sort bis(phenyl­sulfin­yl)methane
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983518/
https://www.ncbi.nlm.nih.gov/pubmed/21580405
http://dx.doi.org/10.1107/S1600536810005957
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AT delimageraldom bisphenylsulfinylmethane
AT wardelljamesl bisphenylsulfinylmethane
AT tiekinkedwardrt bisphenylsulfinylmethane

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