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Bis[N-benzyl-2-(quinolin-8-yloxy)acetamide]dichloridocopper(II) acetonitrile solvate monohydrate
In the title complex, [CuCl(2)(C(18)H(16)N(2)O(2))(2)]·CH(3)CN·H(2)O, the six-coordinated Cu atom is in a distorted octahedral geometry with the donor centers of two O atoms and two N atom from two bidentate ligands, and two chloride ions. In the crystal, pairs of intermolecular N—H⋯ Cl hydrogen b...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983527/ https://www.ncbi.nlm.nih.gov/pubmed/21580237 http://dx.doi.org/10.1107/S1600536810005453 |
| _version_ | 1782191893578252288 |
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| author | Wang, Yuan Wu, Wei-Na Zhao, Rui-Qi Zhang, Ai-Yun Qin, Bao-Feng |
| author_facet | Wang, Yuan Wu, Wei-Na Zhao, Rui-Qi Zhang, Ai-Yun Qin, Bao-Feng |
| author_sort | Wang, Yuan |
| collection | PubMed |
| description | In the title complex, [CuCl(2)(C(18)H(16)N(2)O(2))(2)]·CH(3)CN·H(2)O, the six-coordinated Cu atom is in a distorted octahedral geometry with the donor centers of two O atoms and two N atom from two bidentate ligands, and two chloride ions. In the crystal, pairs of intermolecular N—H⋯ Cl hydrogen bonds form centrosymmetric dimers and intermolecular O—H⋯ O hydrogen bonds between the ligand and the uncoordinated water molecules link the dimers into chains parallel to the c axis. |
| format | Text |
| id | pubmed-2983527 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29835272010-12-30 Bis[N-benzyl-2-(quinolin-8-yloxy)acetamide]dichloridocopper(II) acetonitrile solvate monohydrate Wang, Yuan Wu, Wei-Na Zhao, Rui-Qi Zhang, Ai-Yun Qin, Bao-Feng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [CuCl(2)(C(18)H(16)N(2)O(2))(2)]·CH(3)CN·H(2)O, the six-coordinated Cu atom is in a distorted octahedral geometry with the donor centers of two O atoms and two N atom from two bidentate ligands, and two chloride ions. In the crystal, pairs of intermolecular N—H⋯ Cl hydrogen bonds form centrosymmetric dimers and intermolecular O—H⋯ O hydrogen bonds between the ligand and the uncoordinated water molecules link the dimers into chains parallel to the c axis. International Union of Crystallography 2010-02-13 /pmc/articles/PMC2983527/ /pubmed/21580237 http://dx.doi.org/10.1107/S1600536810005453 Text en © Wang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Wang, Yuan Wu, Wei-Na Zhao, Rui-Qi Zhang, Ai-Yun Qin, Bao-Feng Bis[N-benzyl-2-(quinolin-8-yloxy)acetamide]dichloridocopper(II) acetonitrile solvate monohydrate |
| title | Bis[N-benzyl-2-(quinolin-8-yloxy)acetamide]dichloridocopper(II) acetonitrile solvate monohydrate |
| title_full | Bis[N-benzyl-2-(quinolin-8-yloxy)acetamide]dichloridocopper(II) acetonitrile solvate monohydrate |
| title_fullStr | Bis[N-benzyl-2-(quinolin-8-yloxy)acetamide]dichloridocopper(II) acetonitrile solvate monohydrate |
| title_full_unstemmed | Bis[N-benzyl-2-(quinolin-8-yloxy)acetamide]dichloridocopper(II) acetonitrile solvate monohydrate |
| title_short | Bis[N-benzyl-2-(quinolin-8-yloxy)acetamide]dichloridocopper(II) acetonitrile solvate monohydrate |
| title_sort | bis[n-benzyl-2-(quinolin-8-yloxy)acetamide]dichloridocopper(ii) acetonitrile solvate monohydrate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983527/ https://www.ncbi.nlm.nih.gov/pubmed/21580237 http://dx.doi.org/10.1107/S1600536810005453 |
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