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Di-μ-chlorido-bis­{[4-chloro-2-(dimethyl­amino­meth­yl)phenyl-κ(2) C (1),N]palladium(II)}

The title compound, [Pd(2)(C(9)H(11)ClN)(2)Cl(2)], consists of two Pd atoms which are bridged by two Cl atoms, forming a centrosymmetric binuclear complex with a square-planar coordination for each of the Pd atoms. The Pd atom is chelated by one N and one C atom from a 4-chloro-2-(dimethyl­amino­met...

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Detalles Bibliográficos
Autores principales: Sang, Yankui, Hong, Qiaomin, Qiu, Wenwei, Liu, Qiancai, Yang, Fan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983531/
https://www.ncbi.nlm.nih.gov/pubmed/21580207
http://dx.doi.org/10.1107/S1600536810003569
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author Sang, Yankui
Hong, Qiaomin
Qiu, Wenwei
Liu, Qiancai
Yang, Fan
author_facet Sang, Yankui
Hong, Qiaomin
Qiu, Wenwei
Liu, Qiancai
Yang, Fan
author_sort Sang, Yankui
collection PubMed
description The title compound, [Pd(2)(C(9)H(11)ClN)(2)Cl(2)], consists of two Pd atoms which are bridged by two Cl atoms, forming a centrosymmetric binuclear complex with a square-planar coordination for each of the Pd atoms. The Pd atom is chelated by one N and one C atom from a 4-chloro-2-(dimethyl­amino­meth­yl)phenyl ligand, forming a five-membered ring (N—Pd—C—C—C). In the crystal structure, weak C—H ⋯Cl hydrogen bonds link the mol­ecules in rows.
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spelling pubmed-29835312010-12-30 Di-μ-chlorido-bis­{[4-chloro-2-(dimethyl­amino­meth­yl)phenyl-κ(2) C (1),N]palladium(II)} Sang, Yankui Hong, Qiaomin Qiu, Wenwei Liu, Qiancai Yang, Fan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Pd(2)(C(9)H(11)ClN)(2)Cl(2)], consists of two Pd atoms which are bridged by two Cl atoms, forming a centrosymmetric binuclear complex with a square-planar coordination for each of the Pd atoms. The Pd atom is chelated by one N and one C atom from a 4-chloro-2-(dimethyl­amino­meth­yl)phenyl ligand, forming a five-membered ring (N—Pd—C—C—C). In the crystal structure, weak C—H ⋯Cl hydrogen bonds link the mol­ecules in rows. International Union of Crystallography 2010-02-03 /pmc/articles/PMC2983531/ /pubmed/21580207 http://dx.doi.org/10.1107/S1600536810003569 Text en © Sang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Sang, Yankui
Hong, Qiaomin
Qiu, Wenwei
Liu, Qiancai
Yang, Fan
Di-μ-chlorido-bis­{[4-chloro-2-(dimethyl­amino­meth­yl)phenyl-κ(2) C (1),N]palladium(II)}
title Di-μ-chlorido-bis­{[4-chloro-2-(dimethyl­amino­meth­yl)phenyl-κ(2) C (1),N]palladium(II)}
title_full Di-μ-chlorido-bis­{[4-chloro-2-(dimethyl­amino­meth­yl)phenyl-κ(2) C (1),N]palladium(II)}
title_fullStr Di-μ-chlorido-bis­{[4-chloro-2-(dimethyl­amino­meth­yl)phenyl-κ(2) C (1),N]palladium(II)}
title_full_unstemmed Di-μ-chlorido-bis­{[4-chloro-2-(dimethyl­amino­meth­yl)phenyl-κ(2) C (1),N]palladium(II)}
title_short Di-μ-chlorido-bis­{[4-chloro-2-(dimethyl­amino­meth­yl)phenyl-κ(2) C (1),N]palladium(II)}
title_sort di-μ-chlorido-bis­{[4-chloro-2-(dimethyl­amino­meth­yl)phenyl-κ(2) c (1),n]palladium(ii)}
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983531/
https://www.ncbi.nlm.nih.gov/pubmed/21580207
http://dx.doi.org/10.1107/S1600536810003569
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