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Di-μ-chlorido-bis{[4-chloro-2-(dimethylaminomethyl)phenyl-κ(2) C (1),N]palladium(II)}
The title compound, [Pd(2)(C(9)H(11)ClN)(2)Cl(2)], consists of two Pd atoms which are bridged by two Cl atoms, forming a centrosymmetric binuclear complex with a square-planar coordination for each of the Pd atoms. The Pd atom is chelated by one N and one C atom from a 4-chloro-2-(dimethylaminomet...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983531/ https://www.ncbi.nlm.nih.gov/pubmed/21580207 http://dx.doi.org/10.1107/S1600536810003569 |
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author | Sang, Yankui Hong, Qiaomin Qiu, Wenwei Liu, Qiancai Yang, Fan |
author_facet | Sang, Yankui Hong, Qiaomin Qiu, Wenwei Liu, Qiancai Yang, Fan |
author_sort | Sang, Yankui |
collection | PubMed |
description | The title compound, [Pd(2)(C(9)H(11)ClN)(2)Cl(2)], consists of two Pd atoms which are bridged by two Cl atoms, forming a centrosymmetric binuclear complex with a square-planar coordination for each of the Pd atoms. The Pd atom is chelated by one N and one C atom from a 4-chloro-2-(dimethylaminomethyl)phenyl ligand, forming a five-membered ring (N—Pd—C—C—C). In the crystal structure, weak C—H ⋯Cl hydrogen bonds link the molecules in rows. |
format | Text |
id | pubmed-2983531 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29835312010-12-30 Di-μ-chlorido-bis{[4-chloro-2-(dimethylaminomethyl)phenyl-κ(2) C (1),N]palladium(II)} Sang, Yankui Hong, Qiaomin Qiu, Wenwei Liu, Qiancai Yang, Fan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Pd(2)(C(9)H(11)ClN)(2)Cl(2)], consists of two Pd atoms which are bridged by two Cl atoms, forming a centrosymmetric binuclear complex with a square-planar coordination for each of the Pd atoms. The Pd atom is chelated by one N and one C atom from a 4-chloro-2-(dimethylaminomethyl)phenyl ligand, forming a five-membered ring (N—Pd—C—C—C). In the crystal structure, weak C—H ⋯Cl hydrogen bonds link the molecules in rows. International Union of Crystallography 2010-02-03 /pmc/articles/PMC2983531/ /pubmed/21580207 http://dx.doi.org/10.1107/S1600536810003569 Text en © Sang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Sang, Yankui Hong, Qiaomin Qiu, Wenwei Liu, Qiancai Yang, Fan Di-μ-chlorido-bis{[4-chloro-2-(dimethylaminomethyl)phenyl-κ(2) C (1),N]palladium(II)} |
title | Di-μ-chlorido-bis{[4-chloro-2-(dimethylaminomethyl)phenyl-κ(2)
C
(1),N]palladium(II)} |
title_full | Di-μ-chlorido-bis{[4-chloro-2-(dimethylaminomethyl)phenyl-κ(2)
C
(1),N]palladium(II)} |
title_fullStr | Di-μ-chlorido-bis{[4-chloro-2-(dimethylaminomethyl)phenyl-κ(2)
C
(1),N]palladium(II)} |
title_full_unstemmed | Di-μ-chlorido-bis{[4-chloro-2-(dimethylaminomethyl)phenyl-κ(2)
C
(1),N]palladium(II)} |
title_short | Di-μ-chlorido-bis{[4-chloro-2-(dimethylaminomethyl)phenyl-κ(2)
C
(1),N]palladium(II)} |
title_sort | di-μ-chlorido-bis{[4-chloro-2-(dimethylaminomethyl)phenyl-κ(2)
c
(1),n]palladium(ii)} |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983531/ https://www.ncbi.nlm.nih.gov/pubmed/21580207 http://dx.doi.org/10.1107/S1600536810003569 |
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