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2-[(2,6-Dichloro­benz­yl)amino]-N-(4-methyl­thia­zol-2-yl)acetamide

In the title compound, C(13)H(13)Cl(2)N(3)OS, the thia­zole and benzene rings are roughly parallel to one another in two layers [dihedral angle = 5.08 (2)°] because the N—C—C—N—C chain that links the two rings is folded [N—C—C—N torsion angle = 12.0 (2)°] rather than fully extended. An intra­molecul...

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Detalles Bibliográficos
Autores principales: Luo, Jie, Zhao, Gui-Long, Shao, Hua, Wang, Yu-Li, Qu, Bao-Han
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983532/
https://www.ncbi.nlm.nih.gov/pubmed/21580292
http://dx.doi.org/10.1107/S1600536810003089
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author Luo, Jie
Zhao, Gui-Long
Shao, Hua
Wang, Yu-Li
Qu, Bao-Han
author_facet Luo, Jie
Zhao, Gui-Long
Shao, Hua
Wang, Yu-Li
Qu, Bao-Han
author_sort Luo, Jie
collection PubMed
description In the title compound, C(13)H(13)Cl(2)N(3)OS, the thia­zole and benzene rings are roughly parallel to one another in two layers [dihedral angle = 5.08 (2)°] because the N—C—C—N—C chain that links the two rings is folded [N—C—C—N torsion angle = 12.0 (2)°] rather than fully extended. An intra­molecular N—H⋯N inter­action occurs. In the crystal, weak inter­molecular N—H⋯N and C—H⋯O inter­actions are present and π–π inter­actions are indicated by the short distances [3.507 (3)–3.665 (2) Å] between the centroids of the thia­zole and benzene rings.
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spelling pubmed-29835322010-12-30 2-[(2,6-Dichloro­benz­yl)amino]-N-(4-methyl­thia­zol-2-yl)acetamide Luo, Jie Zhao, Gui-Long Shao, Hua Wang, Yu-Li Qu, Bao-Han Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(13)H(13)Cl(2)N(3)OS, the thia­zole and benzene rings are roughly parallel to one another in two layers [dihedral angle = 5.08 (2)°] because the N—C—C—N—C chain that links the two rings is folded [N—C—C—N torsion angle = 12.0 (2)°] rather than fully extended. An intra­molecular N—H⋯N inter­action occurs. In the crystal, weak inter­molecular N—H⋯N and C—H⋯O inter­actions are present and π–π inter­actions are indicated by the short distances [3.507 (3)–3.665 (2) Å] between the centroids of the thia­zole and benzene rings. International Union of Crystallography 2010-02-03 /pmc/articles/PMC2983532/ /pubmed/21580292 http://dx.doi.org/10.1107/S1600536810003089 Text en © Luo et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Luo, Jie
Zhao, Gui-Long
Shao, Hua
Wang, Yu-Li
Qu, Bao-Han
2-[(2,6-Dichloro­benz­yl)amino]-N-(4-methyl­thia­zol-2-yl)acetamide
title 2-[(2,6-Dichloro­benz­yl)amino]-N-(4-methyl­thia­zol-2-yl)acetamide
title_full 2-[(2,6-Dichloro­benz­yl)amino]-N-(4-methyl­thia­zol-2-yl)acetamide
title_fullStr 2-[(2,6-Dichloro­benz­yl)amino]-N-(4-methyl­thia­zol-2-yl)acetamide
title_full_unstemmed 2-[(2,6-Dichloro­benz­yl)amino]-N-(4-methyl­thia­zol-2-yl)acetamide
title_short 2-[(2,6-Dichloro­benz­yl)amino]-N-(4-methyl­thia­zol-2-yl)acetamide
title_sort 2-[(2,6-dichloro­benz­yl)amino]-n-(4-methyl­thia­zol-2-yl)acetamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983532/
https://www.ncbi.nlm.nih.gov/pubmed/21580292
http://dx.doi.org/10.1107/S1600536810003089
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