Cargando…
2-[(2,6-Dichlorobenzyl)amino]-N-(4-methylthiazol-2-yl)acetamide
In the title compound, C(13)H(13)Cl(2)N(3)OS, the thiazole and benzene rings are roughly parallel to one another in two layers [dihedral angle = 5.08 (2)°] because the N—C—C—N—C chain that links the two rings is folded [N—C—C—N torsion angle = 12.0 (2)°] rather than fully extended. An intramolecul...
Autores principales: | , , , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983532/ https://www.ncbi.nlm.nih.gov/pubmed/21580292 http://dx.doi.org/10.1107/S1600536810003089 |
_version_ | 1782191894872195072 |
---|---|
author | Luo, Jie Zhao, Gui-Long Shao, Hua Wang, Yu-Li Qu, Bao-Han |
author_facet | Luo, Jie Zhao, Gui-Long Shao, Hua Wang, Yu-Li Qu, Bao-Han |
author_sort | Luo, Jie |
collection | PubMed |
description | In the title compound, C(13)H(13)Cl(2)N(3)OS, the thiazole and benzene rings are roughly parallel to one another in two layers [dihedral angle = 5.08 (2)°] because the N—C—C—N—C chain that links the two rings is folded [N—C—C—N torsion angle = 12.0 (2)°] rather than fully extended. An intramolecular N—H⋯N interaction occurs. In the crystal, weak intermolecular N—H⋯N and C—H⋯O interactions are present and π–π interactions are indicated by the short distances [3.507 (3)–3.665 (2) Å] between the centroids of the thiazole and benzene rings. |
format | Text |
id | pubmed-2983532 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29835322010-12-30 2-[(2,6-Dichlorobenzyl)amino]-N-(4-methylthiazol-2-yl)acetamide Luo, Jie Zhao, Gui-Long Shao, Hua Wang, Yu-Li Qu, Bao-Han Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(13)H(13)Cl(2)N(3)OS, the thiazole and benzene rings are roughly parallel to one another in two layers [dihedral angle = 5.08 (2)°] because the N—C—C—N—C chain that links the two rings is folded [N—C—C—N torsion angle = 12.0 (2)°] rather than fully extended. An intramolecular N—H⋯N interaction occurs. In the crystal, weak intermolecular N—H⋯N and C—H⋯O interactions are present and π–π interactions are indicated by the short distances [3.507 (3)–3.665 (2) Å] between the centroids of the thiazole and benzene rings. International Union of Crystallography 2010-02-03 /pmc/articles/PMC2983532/ /pubmed/21580292 http://dx.doi.org/10.1107/S1600536810003089 Text en © Luo et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Luo, Jie Zhao, Gui-Long Shao, Hua Wang, Yu-Li Qu, Bao-Han 2-[(2,6-Dichlorobenzyl)amino]-N-(4-methylthiazol-2-yl)acetamide |
title | 2-[(2,6-Dichlorobenzyl)amino]-N-(4-methylthiazol-2-yl)acetamide |
title_full | 2-[(2,6-Dichlorobenzyl)amino]-N-(4-methylthiazol-2-yl)acetamide |
title_fullStr | 2-[(2,6-Dichlorobenzyl)amino]-N-(4-methylthiazol-2-yl)acetamide |
title_full_unstemmed | 2-[(2,6-Dichlorobenzyl)amino]-N-(4-methylthiazol-2-yl)acetamide |
title_short | 2-[(2,6-Dichlorobenzyl)amino]-N-(4-methylthiazol-2-yl)acetamide |
title_sort | 2-[(2,6-dichlorobenzyl)amino]-n-(4-methylthiazol-2-yl)acetamide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983532/ https://www.ncbi.nlm.nih.gov/pubmed/21580292 http://dx.doi.org/10.1107/S1600536810003089 |
work_keys_str_mv | AT luojie 226dichlorobenzylaminon4methylthiazol2ylacetamide AT zhaoguilong 226dichlorobenzylaminon4methylthiazol2ylacetamide AT shaohua 226dichlorobenzylaminon4methylthiazol2ylacetamide AT wangyuli 226dichlorobenzylaminon4methylthiazol2ylacetamide AT qubaohan 226dichlorobenzylaminon4methylthiazol2ylacetamide |