catena-Poly[[bis­(pyrazine-2-carbox­amide)mercury(II)]-di-μ-chlorido]

In the polymeric title compound, [HgCl(2)(C(5)H(5)N(3)O)(2)](n), the Hg(II) atom (site symmetry [Image: see text]) adopts a distorted trans-HgN(2)Cl(4) octa­hedral coordination geometry. In the crystal, adjacent mercury ions are bridged by pairs of chloride ions, generating infinite [100] chains, an...

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Detalles Bibliográficos
Autores principales: Azhdari Tehrani, Alireza, Mir Mohammad Sadegh, Bahareh, Khavasi, Hamid Reza
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983533/
https://www.ncbi.nlm.nih.gov/pubmed/21580214
http://dx.doi.org/10.1107/S1600536810003879
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author Azhdari Tehrani, Alireza
Mir Mohammad Sadegh, Bahareh
Khavasi, Hamid Reza
author_facet Azhdari Tehrani, Alireza
Mir Mohammad Sadegh, Bahareh
Khavasi, Hamid Reza
author_sort Azhdari Tehrani, Alireza
collection PubMed
description In the polymeric title compound, [HgCl(2)(C(5)H(5)N(3)O)(2)](n), the Hg(II) atom (site symmetry [Image: see text]) adopts a distorted trans-HgN(2)Cl(4) octa­hedral coordination geometry. In the crystal, adjacent mercury ions are bridged by pairs of chloride ions, generating infinite [100] chains, and N—H⋯O and N—H⋯(N,N) hydrogen bonds help to consolidate the packing.
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spelling pubmed-29835332010-12-30 catena-Poly[[bis­(pyrazine-2-carbox­amide)mercury(II)]-di-μ-chlorido] Azhdari Tehrani, Alireza Mir Mohammad Sadegh, Bahareh Khavasi, Hamid Reza Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the polymeric title compound, [HgCl(2)(C(5)H(5)N(3)O)(2)](n), the Hg(II) atom (site symmetry [Image: see text]) adopts a distorted trans-HgN(2)Cl(4) octa­hedral coordination geometry. In the crystal, adjacent mercury ions are bridged by pairs of chloride ions, generating infinite [100] chains, and N—H⋯O and N—H⋯(N,N) hydrogen bonds help to consolidate the packing. International Union of Crystallography 2010-02-06 /pmc/articles/PMC2983533/ /pubmed/21580214 http://dx.doi.org/10.1107/S1600536810003879 Text en © Azhdari Tehrani et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Azhdari Tehrani, Alireza
Mir Mohammad Sadegh, Bahareh
Khavasi, Hamid Reza
catena-Poly[[bis­(pyrazine-2-carbox­amide)mercury(II)]-di-μ-chlorido]
title catena-Poly[[bis­(pyrazine-2-carbox­amide)mercury(II)]-di-μ-chlorido]
title_full catena-Poly[[bis­(pyrazine-2-carbox­amide)mercury(II)]-di-μ-chlorido]
title_fullStr catena-Poly[[bis­(pyrazine-2-carbox­amide)mercury(II)]-di-μ-chlorido]
title_full_unstemmed catena-Poly[[bis­(pyrazine-2-carbox­amide)mercury(II)]-di-μ-chlorido]
title_short catena-Poly[[bis­(pyrazine-2-carbox­amide)mercury(II)]-di-μ-chlorido]
title_sort catena-poly[[bis­(pyrazine-2-carbox­amide)mercury(ii)]-di-μ-chlorido]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983533/
https://www.ncbi.nlm.nih.gov/pubmed/21580214
http://dx.doi.org/10.1107/S1600536810003879
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