Cargando…
2-Ethyl-6-(2-pyridyl)-5,6,6a,11b-tetrahydro-7H-indeno[2,1-c]quinoline
The title compound, C(23)H(22)N(2), was obtained using the three-component imino Diels–Alder reaction via a one-pot condensation between anilines, α-pyridinecarboxyaldehyde and indene using BF(3)·OEt(2) as the catalyst. The molecular structure reveals the cis-form as the unique diastereoisomer. T...
Autores principales: | , , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983536/ https://www.ncbi.nlm.nih.gov/pubmed/21580425 http://dx.doi.org/10.1107/S1600536810005805 |
_version_ | 1782191895821156352 |
---|---|
author | Bohórquez, Arnold R. Romero Kouznetsov, Vladimir V. González, Teresa Briceño, Alexander |
author_facet | Bohórquez, Arnold R. Romero Kouznetsov, Vladimir V. González, Teresa Briceño, Alexander |
author_sort | Bohórquez, Arnold R. Romero |
collection | PubMed |
description | The title compound, C(23)H(22)N(2), was obtained using the three-component imino Diels–Alder reaction via a one-pot condensation between anilines, α-pyridinecarboxyaldehyde and indene using BF(3)·OEt(2) as the catalyst. The molecular structure reveals the cis-form as the unique diastereoisomer. The crystal structure comprises one-dimensional zigzag ribbons connected via N—H⋯N hydrogen bonds. C—H⋯π interactions also occur. |
format | Text |
id | pubmed-2983536 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29835362010-12-30 2-Ethyl-6-(2-pyridyl)-5,6,6a,11b-tetrahydro-7H-indeno[2,1-c]quinoline Bohórquez, Arnold R. Romero Kouznetsov, Vladimir V. González, Teresa Briceño, Alexander Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(23)H(22)N(2), was obtained using the three-component imino Diels–Alder reaction via a one-pot condensation between anilines, α-pyridinecarboxyaldehyde and indene using BF(3)·OEt(2) as the catalyst. The molecular structure reveals the cis-form as the unique diastereoisomer. The crystal structure comprises one-dimensional zigzag ribbons connected via N—H⋯N hydrogen bonds. C—H⋯π interactions also occur. International Union of Crystallography 2010-02-20 /pmc/articles/PMC2983536/ /pubmed/21580425 http://dx.doi.org/10.1107/S1600536810005805 Text en © Bohórquez et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Bohórquez, Arnold R. Romero Kouznetsov, Vladimir V. González, Teresa Briceño, Alexander 2-Ethyl-6-(2-pyridyl)-5,6,6a,11b-tetrahydro-7H-indeno[2,1-c]quinoline |
title | 2-Ethyl-6-(2-pyridyl)-5,6,6a,11b-tetrahydro-7H-indeno[2,1-c]quinoline |
title_full | 2-Ethyl-6-(2-pyridyl)-5,6,6a,11b-tetrahydro-7H-indeno[2,1-c]quinoline |
title_fullStr | 2-Ethyl-6-(2-pyridyl)-5,6,6a,11b-tetrahydro-7H-indeno[2,1-c]quinoline |
title_full_unstemmed | 2-Ethyl-6-(2-pyridyl)-5,6,6a,11b-tetrahydro-7H-indeno[2,1-c]quinoline |
title_short | 2-Ethyl-6-(2-pyridyl)-5,6,6a,11b-tetrahydro-7H-indeno[2,1-c]quinoline |
title_sort | 2-ethyl-6-(2-pyridyl)-5,6,6a,11b-tetrahydro-7h-indeno[2,1-c]quinoline |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983536/ https://www.ncbi.nlm.nih.gov/pubmed/21580425 http://dx.doi.org/10.1107/S1600536810005805 |
work_keys_str_mv | AT bohorquezarnoldrromero 2ethyl62pyridyl566a11btetrahydro7hindeno21cquinoline AT kouznetsovvladimirv 2ethyl62pyridyl566a11btetrahydro7hindeno21cquinoline AT gonzalezteresa 2ethyl62pyridyl566a11btetrahydro7hindeno21cquinoline AT bricenoalexander 2ethyl62pyridyl566a11btetrahydro7hindeno21cquinoline |