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2-Ethyl-6-(2-pyrid­yl)-5,6,6a,11b-tetra­hydro-7H-indeno[2,1-c]quinoline

The title compound, C(23)H(22)N(2), was obtained using the three-component imino Diels–Alder reaction via a one-pot condensation between anilines, α-pyridine­carboxy­aldehyde and indene using BF(3)·OEt(2) as the catalyst. The mol­ecular structure reveals the cis-form as the unique diastereoisomer. T...

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Detalles Bibliográficos
Autores principales: Bohórquez, Arnold R. Romero, Kouznetsov, Vladimir V., González, Teresa, Briceño, Alexander
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983536/
https://www.ncbi.nlm.nih.gov/pubmed/21580425
http://dx.doi.org/10.1107/S1600536810005805
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author Bohórquez, Arnold R. Romero
Kouznetsov, Vladimir V.
González, Teresa
Briceño, Alexander
author_facet Bohórquez, Arnold R. Romero
Kouznetsov, Vladimir V.
González, Teresa
Briceño, Alexander
author_sort Bohórquez, Arnold R. Romero
collection PubMed
description The title compound, C(23)H(22)N(2), was obtained using the three-component imino Diels–Alder reaction via a one-pot condensation between anilines, α-pyridine­carboxy­aldehyde and indene using BF(3)·OEt(2) as the catalyst. The mol­ecular structure reveals the cis-form as the unique diastereoisomer. The crystal structure comprises one-dimensional zigzag ribbons connected via N—H⋯N hydrogen bonds. C—H⋯π inter­actions also occur.
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spelling pubmed-29835362010-12-30 2-Ethyl-6-(2-pyrid­yl)-5,6,6a,11b-tetra­hydro-7H-indeno[2,1-c]quinoline Bohórquez, Arnold R. Romero Kouznetsov, Vladimir V. González, Teresa Briceño, Alexander Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(23)H(22)N(2), was obtained using the three-component imino Diels–Alder reaction via a one-pot condensation between anilines, α-pyridine­carboxy­aldehyde and indene using BF(3)·OEt(2) as the catalyst. The mol­ecular structure reveals the cis-form as the unique diastereoisomer. The crystal structure comprises one-dimensional zigzag ribbons connected via N—H⋯N hydrogen bonds. C—H⋯π inter­actions also occur. International Union of Crystallography 2010-02-20 /pmc/articles/PMC2983536/ /pubmed/21580425 http://dx.doi.org/10.1107/S1600536810005805 Text en © Bohórquez et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Bohórquez, Arnold R. Romero
Kouznetsov, Vladimir V.
González, Teresa
Briceño, Alexander
2-Ethyl-6-(2-pyrid­yl)-5,6,6a,11b-tetra­hydro-7H-indeno[2,1-c]quinoline
title 2-Ethyl-6-(2-pyrid­yl)-5,6,6a,11b-tetra­hydro-7H-indeno[2,1-c]quinoline
title_full 2-Ethyl-6-(2-pyrid­yl)-5,6,6a,11b-tetra­hydro-7H-indeno[2,1-c]quinoline
title_fullStr 2-Ethyl-6-(2-pyrid­yl)-5,6,6a,11b-tetra­hydro-7H-indeno[2,1-c]quinoline
title_full_unstemmed 2-Ethyl-6-(2-pyrid­yl)-5,6,6a,11b-tetra­hydro-7H-indeno[2,1-c]quinoline
title_short 2-Ethyl-6-(2-pyrid­yl)-5,6,6a,11b-tetra­hydro-7H-indeno[2,1-c]quinoline
title_sort 2-ethyl-6-(2-pyrid­yl)-5,6,6a,11b-tetra­hydro-7h-indeno[2,1-c]quinoline
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983536/
https://www.ncbi.nlm.nih.gov/pubmed/21580425
http://dx.doi.org/10.1107/S1600536810005805
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