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2-Amino-5-methylpyridinium 3-aminobenzoate
In the title compound, C(6)H(9)N(2) (+)·C(7)H(6)NO(2) (−), the H atom of the N—H group and an H atom of the 2-amino group from the cation are involved in intermolecular N—H⋯O hydrogen bonds with the O atoms of the carboxylate group of the anion, forming an R (2) (2)(8) ring motif. These ring motif...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983539/ https://www.ncbi.nlm.nih.gov/pubmed/21580381 http://dx.doi.org/10.1107/S1600536810005180 |
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author | Hemamalini, Madhukar Fun, Hoong-Kun |
author_facet | Hemamalini, Madhukar Fun, Hoong-Kun |
author_sort | Hemamalini, Madhukar |
collection | PubMed |
description | In the title compound, C(6)H(9)N(2) (+)·C(7)H(6)NO(2) (−), the H atom of the N—H group and an H atom of the 2-amino group from the cation are involved in intermolecular N—H⋯O hydrogen bonds with the O atoms of the carboxylate group of the anion, forming an R (2) (2)(8) ring motif. These ring motifs are, in turn, connected by further N—H⋯O hydrogen bonds, forming a two-dimensional network. The crystal structure is further stabilized by π⋯π stacking interactions involving the benzene and pyridinium rings with a centroid–centroid distance of 3.7594 (8) Å. |
format | Text |
id | pubmed-2983539 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29835392010-12-30 2-Amino-5-methylpyridinium 3-aminobenzoate Hemamalini, Madhukar Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(6)H(9)N(2) (+)·C(7)H(6)NO(2) (−), the H atom of the N—H group and an H atom of the 2-amino group from the cation are involved in intermolecular N—H⋯O hydrogen bonds with the O atoms of the carboxylate group of the anion, forming an R (2) (2)(8) ring motif. These ring motifs are, in turn, connected by further N—H⋯O hydrogen bonds, forming a two-dimensional network. The crystal structure is further stabilized by π⋯π stacking interactions involving the benzene and pyridinium rings with a centroid–centroid distance of 3.7594 (8) Å. International Union of Crystallography 2010-02-13 /pmc/articles/PMC2983539/ /pubmed/21580381 http://dx.doi.org/10.1107/S1600536810005180 Text en © Hemamalini and Fun 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Hemamalini, Madhukar Fun, Hoong-Kun 2-Amino-5-methylpyridinium 3-aminobenzoate |
title | 2-Amino-5-methylpyridinium 3-aminobenzoate |
title_full | 2-Amino-5-methylpyridinium 3-aminobenzoate |
title_fullStr | 2-Amino-5-methylpyridinium 3-aminobenzoate |
title_full_unstemmed | 2-Amino-5-methylpyridinium 3-aminobenzoate |
title_short | 2-Amino-5-methylpyridinium 3-aminobenzoate |
title_sort | 2-amino-5-methylpyridinium 3-aminobenzoate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983539/ https://www.ncbi.nlm.nih.gov/pubmed/21580381 http://dx.doi.org/10.1107/S1600536810005180 |
work_keys_str_mv | AT hemamalinimadhukar 2amino5methylpyridinium3aminobenzoate AT funhoongkun 2amino5methylpyridinium3aminobenzoate |