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2-Amino-5-methyl­pyridinium 3-amino­benzoate

In the title compound, C(6)H(9)N(2) (+)·C(7)H(6)NO(2) (−), the H atom of the N—H group and an H atom of the 2-amino group from the cation are involved in inter­molecular N—H⋯O hydrogen bonds with the O atoms of the carboxyl­ate group of the anion, forming an R (2) (2)(8) ring motif. These ring motif...

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Detalles Bibliográficos
Autores principales: Hemamalini, Madhukar, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983539/
https://www.ncbi.nlm.nih.gov/pubmed/21580381
http://dx.doi.org/10.1107/S1600536810005180
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author Hemamalini, Madhukar
Fun, Hoong-Kun
author_facet Hemamalini, Madhukar
Fun, Hoong-Kun
author_sort Hemamalini, Madhukar
collection PubMed
description In the title compound, C(6)H(9)N(2) (+)·C(7)H(6)NO(2) (−), the H atom of the N—H group and an H atom of the 2-amino group from the cation are involved in inter­molecular N—H⋯O hydrogen bonds with the O atoms of the carboxyl­ate group of the anion, forming an R (2) (2)(8) ring motif. These ring motifs are, in turn, connected by further N—H⋯O hydrogen bonds, forming a two-dimensional network. The crystal structure is further stabilized by π⋯π stacking inter­actions involving the benzene and pyridinium rings with a centroid–centroid distance of 3.7594 (8) Å.
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spelling pubmed-29835392010-12-30 2-Amino-5-methyl­pyridinium 3-amino­benzoate Hemamalini, Madhukar Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(6)H(9)N(2) (+)·C(7)H(6)NO(2) (−), the H atom of the N—H group and an H atom of the 2-amino group from the cation are involved in inter­molecular N—H⋯O hydrogen bonds with the O atoms of the carboxyl­ate group of the anion, forming an R (2) (2)(8) ring motif. These ring motifs are, in turn, connected by further N—H⋯O hydrogen bonds, forming a two-dimensional network. The crystal structure is further stabilized by π⋯π stacking inter­actions involving the benzene and pyridinium rings with a centroid–centroid distance of 3.7594 (8) Å. International Union of Crystallography 2010-02-13 /pmc/articles/PMC2983539/ /pubmed/21580381 http://dx.doi.org/10.1107/S1600536810005180 Text en © Hemamalini and Fun 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Hemamalini, Madhukar
Fun, Hoong-Kun
2-Amino-5-methyl­pyridinium 3-amino­benzoate
title 2-Amino-5-methyl­pyridinium 3-amino­benzoate
title_full 2-Amino-5-methyl­pyridinium 3-amino­benzoate
title_fullStr 2-Amino-5-methyl­pyridinium 3-amino­benzoate
title_full_unstemmed 2-Amino-5-methyl­pyridinium 3-amino­benzoate
title_short 2-Amino-5-methyl­pyridinium 3-amino­benzoate
title_sort 2-amino-5-methyl­pyridinium 3-amino­benzoate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983539/
https://www.ncbi.nlm.nih.gov/pubmed/21580381
http://dx.doi.org/10.1107/S1600536810005180
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