catena-Poly[[[aqua­silver(I)]-μ-4,4′-bipyridine-κ(2) N:N′] 4-amino­benzoate nitrate hydrate]

In the structure of the title compound, 2[Ag(C(10)H(8)N(2))(H(2)O)](C(7)H(6)NO(2))(NO(3))·H(2)O, the Ag(I) atom is three-coordinated in a T-shaped configuration by two N atoms from two symmetry-related 4,4′-bipyridine (bipy) ligands at short distances and by one water O atom at a longer distance. Ea...

Descripción completa

Detalles Bibliográficos
Autores principales: Zhang, Yong-Mei, Hou, Dong-Yan, Xin, Guang, Li, Tie-Chun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983544/
https://www.ncbi.nlm.nih.gov/pubmed/21580232
http://dx.doi.org/10.1107/S1600536810005052
_version_ 1782191897746341888
author Zhang, Yong-Mei
Hou, Dong-Yan
Xin, Guang
Li, Tie-Chun
author_facet Zhang, Yong-Mei
Hou, Dong-Yan
Xin, Guang
Li, Tie-Chun
author_sort Zhang, Yong-Mei
collection PubMed
description In the structure of the title compound, 2[Ag(C(10)H(8)N(2))(H(2)O)](C(7)H(6)NO(2))(NO(3))·H(2)O, the Ag(I) atom is three-coordinated in a T-shaped configuration by two N atoms from two symmetry-related 4,4′-bipyridine (bipy) ligands at short distances and by one water O atom at a longer distance. Each bipy ligand bridges two neighbouring Ag(I) atoms, forming a chain structure extending parallel to [101]. The complete 4-amino­benzoate anion, the nitrate anion and the uncoordinated water mol­ecule are located on mirror planes: together with the coordinated water mol­ecule, they form N—H⋯O, O—H⋯O and O—H⋯N hydrogen bonds, stabilizing the crystal structure.
format Text
id pubmed-2983544
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29835442010-12-30 catena-Poly[[[aqua­silver(I)]-μ-4,4′-bipyridine-κ(2) N:N′] 4-amino­benzoate nitrate hydrate] Zhang, Yong-Mei Hou, Dong-Yan Xin, Guang Li, Tie-Chun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the structure of the title compound, 2[Ag(C(10)H(8)N(2))(H(2)O)](C(7)H(6)NO(2))(NO(3))·H(2)O, the Ag(I) atom is three-coordinated in a T-shaped configuration by two N atoms from two symmetry-related 4,4′-bipyridine (bipy) ligands at short distances and by one water O atom at a longer distance. Each bipy ligand bridges two neighbouring Ag(I) atoms, forming a chain structure extending parallel to [101]. The complete 4-amino­benzoate anion, the nitrate anion and the uncoordinated water mol­ecule are located on mirror planes: together with the coordinated water mol­ecule, they form N—H⋯O, O—H⋯O and O—H⋯N hydrogen bonds, stabilizing the crystal structure. International Union of Crystallography 2010-02-13 /pmc/articles/PMC2983544/ /pubmed/21580232 http://dx.doi.org/10.1107/S1600536810005052 Text en © Zhang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Yong-Mei
Hou, Dong-Yan
Xin, Guang
Li, Tie-Chun
catena-Poly[[[aqua­silver(I)]-μ-4,4′-bipyridine-κ(2) N:N′] 4-amino­benzoate nitrate hydrate]
title catena-Poly[[[aqua­silver(I)]-μ-4,4′-bipyridine-κ(2) N:N′] 4-amino­benzoate nitrate hydrate]
title_full catena-Poly[[[aqua­silver(I)]-μ-4,4′-bipyridine-κ(2) N:N′] 4-amino­benzoate nitrate hydrate]
title_fullStr catena-Poly[[[aqua­silver(I)]-μ-4,4′-bipyridine-κ(2) N:N′] 4-amino­benzoate nitrate hydrate]
title_full_unstemmed catena-Poly[[[aqua­silver(I)]-μ-4,4′-bipyridine-κ(2) N:N′] 4-amino­benzoate nitrate hydrate]
title_short catena-Poly[[[aqua­silver(I)]-μ-4,4′-bipyridine-κ(2) N:N′] 4-amino­benzoate nitrate hydrate]
title_sort catena-poly[[[aqua­silver(i)]-μ-4,4′-bipyridine-κ(2) n:n′] 4-amino­benzoate nitrate hydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983544/
https://www.ncbi.nlm.nih.gov/pubmed/21580232
http://dx.doi.org/10.1107/S1600536810005052
work_keys_str_mv AT zhangyongmei catenapolyaquasilverim44bipyridinek2nn4aminobenzoatenitratehydrate
AT houdongyan catenapolyaquasilverim44bipyridinek2nn4aminobenzoatenitratehydrate
AT xinguang catenapolyaquasilverim44bipyridinek2nn4aminobenzoatenitratehydrate
AT litiechun catenapolyaquasilverim44bipyridinek2nn4aminobenzoatenitratehydrate

Ejemplares similares