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catena-Poly[[[aqua[(2-hydroxyphenyl)acetato-κ(2) O,O′]lead(II)]-μ(3)-[(2-hydroxyphenyl)acetato-κ(4) O:O,O′:O′]] monohydrate]
In the title complex, {[Pb(C(8)H(7)O(3))(2)(H(2)O)]·H(2)O}(n), the Pb(II) atom is seven-coordinated by six carboxylate O atoms from four different 2-hydroxyphenylacetate (2-dph) ligands and one water molecule, displaying a hemidirected irregular geometry, with the empty side of the metal ion cap...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983550/ https://www.ncbi.nlm.nih.gov/pubmed/21580222 http://dx.doi.org/10.1107/S1600536810004162 |
Sumario: | In the title complex, {[Pb(C(8)H(7)O(3))(2)(H(2)O)]·H(2)O}(n), the Pb(II) atom is seven-coordinated by six carboxylate O atoms from four different 2-hydroxyphenylacetate (2-dph) ligands and one water molecule, displaying a hemidirected irregular geometry, with the empty side of the metal ion capped by a benzene ring forming a Pb⋯π contact [Pb⋯centroid distance = 3.342 (2) Å]. One 2-dph ligand functions in a bridging mode and connects Pb ions into a linear chain. The crystal packing is governed by intra- and intermolecular O—H⋯O hydrogen bonds. |
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