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catena-Poly[[[aqua[(2-hydroxyphenyl)acetato-κ(2) O,O′]lead(II)]-μ(3)-[(2-hydroxyphenyl)acetato-κ(4) O:O,O′:O′]] monohydrate]
In the title complex, {[Pb(C(8)H(7)O(3))(2)(H(2)O)]·H(2)O}(n), the Pb(II) atom is seven-coordinated by six carboxylate O atoms from four different 2-hydroxyphenylacetate (2-dph) ligands and one water molecule, displaying a hemidirected irregular geometry, with the empty side of the metal ion cap...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983550/ https://www.ncbi.nlm.nih.gov/pubmed/21580222 http://dx.doi.org/10.1107/S1600536810004162 |
| _version_ | 1782191899284602880 |
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| author | Xiao, Jun-Xia Wu, Xian-Ge Qin, Liang |
| author_facet | Xiao, Jun-Xia Wu, Xian-Ge Qin, Liang |
| author_sort | Xiao, Jun-Xia |
| collection | PubMed |
| description | In the title complex, {[Pb(C(8)H(7)O(3))(2)(H(2)O)]·H(2)O}(n), the Pb(II) atom is seven-coordinated by six carboxylate O atoms from four different 2-hydroxyphenylacetate (2-dph) ligands and one water molecule, displaying a hemidirected irregular geometry, with the empty side of the metal ion capped by a benzene ring forming a Pb⋯π contact [Pb⋯centroid distance = 3.342 (2) Å]. One 2-dph ligand functions in a bridging mode and connects Pb ions into a linear chain. The crystal packing is governed by intra- and intermolecular O—H⋯O hydrogen bonds. |
| format | Text |
| id | pubmed-2983550 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29835502010-12-30 catena-Poly[[[aqua[(2-hydroxyphenyl)acetato-κ(2) O,O′]lead(II)]-μ(3)-[(2-hydroxyphenyl)acetato-κ(4) O:O,O′:O′]] monohydrate] Xiao, Jun-Xia Wu, Xian-Ge Qin, Liang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, {[Pb(C(8)H(7)O(3))(2)(H(2)O)]·H(2)O}(n), the Pb(II) atom is seven-coordinated by six carboxylate O atoms from four different 2-hydroxyphenylacetate (2-dph) ligands and one water molecule, displaying a hemidirected irregular geometry, with the empty side of the metal ion capped by a benzene ring forming a Pb⋯π contact [Pb⋯centroid distance = 3.342 (2) Å]. One 2-dph ligand functions in a bridging mode and connects Pb ions into a linear chain. The crystal packing is governed by intra- and intermolecular O—H⋯O hydrogen bonds. International Union of Crystallography 2010-02-06 /pmc/articles/PMC2983550/ /pubmed/21580222 http://dx.doi.org/10.1107/S1600536810004162 Text en © Xiao et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Xiao, Jun-Xia Wu, Xian-Ge Qin, Liang catena-Poly[[[aqua[(2-hydroxyphenyl)acetato-κ(2) O,O′]lead(II)]-μ(3)-[(2-hydroxyphenyl)acetato-κ(4) O:O,O′:O′]] monohydrate] |
| title |
catena-Poly[[[aqua[(2-hydroxyphenyl)acetato-κ(2)
O,O′]lead(II)]-μ(3)-[(2-hydroxyphenyl)acetato-κ(4)
O:O,O′:O′]] monohydrate] |
| title_full |
catena-Poly[[[aqua[(2-hydroxyphenyl)acetato-κ(2)
O,O′]lead(II)]-μ(3)-[(2-hydroxyphenyl)acetato-κ(4)
O:O,O′:O′]] monohydrate] |
| title_fullStr |
catena-Poly[[[aqua[(2-hydroxyphenyl)acetato-κ(2)
O,O′]lead(II)]-μ(3)-[(2-hydroxyphenyl)acetato-κ(4)
O:O,O′:O′]] monohydrate] |
| title_full_unstemmed |
catena-Poly[[[aqua[(2-hydroxyphenyl)acetato-κ(2)
O,O′]lead(II)]-μ(3)-[(2-hydroxyphenyl)acetato-κ(4)
O:O,O′:O′]] monohydrate] |
| title_short |
catena-Poly[[[aqua[(2-hydroxyphenyl)acetato-κ(2)
O,O′]lead(II)]-μ(3)-[(2-hydroxyphenyl)acetato-κ(4)
O:O,O′:O′]] monohydrate] |
| title_sort | catena-poly[[[aqua[(2-hydroxyphenyl)acetato-κ(2)
o,o′]lead(ii)]-μ(3)-[(2-hydroxyphenyl)acetato-κ(4)
o:o,o′:o′]] monohydrate] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983550/ https://www.ncbi.nlm.nih.gov/pubmed/21580222 http://dx.doi.org/10.1107/S1600536810004162 |
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