2-Amino-5-bromo­pyridine–benzoic acid (1/1)

In the title adduct, C(5)H(5)BrN(2)·C(7)H(6)O(2), the carboxyl group of the benzoic acid mol­ecule is twisted away from the attached ring by 12.97 (11)°. The 2-amino-5-bromo­pyridine mol­ecules inter­act with the carboxylic group of neighbouring benzoic acid mol­ecules through N—H⋯O and O—H⋯N hydrog...

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Detalles Bibliográficos
Autores principales: Hemamalini, Madhukar, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983551/
https://www.ncbi.nlm.nih.gov/pubmed/21580411
http://dx.doi.org/10.1107/S1600536810005969
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author Hemamalini, Madhukar
Fun, Hoong-Kun
author_facet Hemamalini, Madhukar
Fun, Hoong-Kun
author_sort Hemamalini, Madhukar
collection PubMed
description In the title adduct, C(5)H(5)BrN(2)·C(7)H(6)O(2), the carboxyl group of the benzoic acid mol­ecule is twisted away from the attached ring by 12.97 (11)°. The 2-amino-5-bromo­pyridine mol­ecules inter­act with the carboxylic group of neighbouring benzoic acid mol­ecules through N—H⋯O and O—H⋯N hydrogen bonds, forming cyclic R (2) (2)(8) hydrogen-bonded motifs and linking the mol­ecules into a two-dimensional network lying parallel to (100). The crystal structure is further stabilized by weak C—H⋯O hydrogen bonds.
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spelling pubmed-29835512010-12-30 2-Amino-5-bromo­pyridine–benzoic acid (1/1) Hemamalini, Madhukar Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title adduct, C(5)H(5)BrN(2)·C(7)H(6)O(2), the carboxyl group of the benzoic acid mol­ecule is twisted away from the attached ring by 12.97 (11)°. The 2-amino-5-bromo­pyridine mol­ecules inter­act with the carboxylic group of neighbouring benzoic acid mol­ecules through N—H⋯O and O—H⋯N hydrogen bonds, forming cyclic R (2) (2)(8) hydrogen-bonded motifs and linking the mol­ecules into a two-dimensional network lying parallel to (100). The crystal structure is further stabilized by weak C—H⋯O hydrogen bonds. International Union of Crystallography 2010-02-20 /pmc/articles/PMC2983551/ /pubmed/21580411 http://dx.doi.org/10.1107/S1600536810005969 Text en © Hemamalini and Fun 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Hemamalini, Madhukar
Fun, Hoong-Kun
2-Amino-5-bromo­pyridine–benzoic acid (1/1)
title 2-Amino-5-bromo­pyridine–benzoic acid (1/1)
title_full 2-Amino-5-bromo­pyridine–benzoic acid (1/1)
title_fullStr 2-Amino-5-bromo­pyridine–benzoic acid (1/1)
title_full_unstemmed 2-Amino-5-bromo­pyridine–benzoic acid (1/1)
title_short 2-Amino-5-bromo­pyridine–benzoic acid (1/1)
title_sort 2-amino-5-bromo­pyridine–benzoic acid (1/1)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983551/
https://www.ncbi.nlm.nih.gov/pubmed/21580411
http://dx.doi.org/10.1107/S1600536810005969
work_keys_str_mv AT hemamalinimadhukar 2amino5bromopyridinebenzoicacid11
AT funhoongkun 2amino5bromopyridinebenzoicacid11

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