4,4′-Bipyridine–3-nitro­benzoic acid (1/2)

The title compound, C(10)H(8)N(2)·2C(7)H(5)NO(4),was obtained unintentionally as the harvested product of the hydro­thermal reaction between Co(OAc)(2)·4H(2)O and 4,4′-bipyridine in the presence of 3-nitro­phthalic acid. In the reaction, 3-nitro­phthalic acid is transformed into 3-nitro­benzoic acid...

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Detalles Bibliográficos
Autores principales: Zhu, Zhen, Wang, Feng-Qin, Zhao, Yong-Nan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983553/
https://www.ncbi.nlm.nih.gov/pubmed/21580317
http://dx.doi.org/10.1107/S1600536810003594
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author Zhu, Zhen
Wang, Feng-Qin
Zhao, Yong-Nan
author_facet Zhu, Zhen
Wang, Feng-Qin
Zhao, Yong-Nan
author_sort Zhu, Zhen
collection PubMed
description The title compound, C(10)H(8)N(2)·2C(7)H(5)NO(4),was obtained unintentionally as the harvested product of the hydro­thermal reaction between Co(OAc)(2)·4H(2)O and 4,4′-bipyridine in the presence of 3-nitro­phthalic acid. In the reaction, 3-nitro­phthalic acid is transformed into 3-nitro­benzoic acid by an in situ deca­rboxylation reaction, in which the carboxyl­ate group is not deprotonated and is uncoordinated. In the crystal, the uncoordinated 3-nitro­benzoic acid and free 4,4′-bipyridine mol­ecules are linked alternately by O—H⋯N hydrogen bonds into chains, which are assembled by C—H⋯O hydrogen bonds into a three-dimensional supra­molecular network.
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spelling pubmed-29835532010-12-30 4,4′-Bipyridine–3-nitro­benzoic acid (1/2) Zhu, Zhen Wang, Feng-Qin Zhao, Yong-Nan Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(10)H(8)N(2)·2C(7)H(5)NO(4),was obtained unintentionally as the harvested product of the hydro­thermal reaction between Co(OAc)(2)·4H(2)O and 4,4′-bipyridine in the presence of 3-nitro­phthalic acid. In the reaction, 3-nitro­phthalic acid is transformed into 3-nitro­benzoic acid by an in situ deca­rboxylation reaction, in which the carboxyl­ate group is not deprotonated and is uncoordinated. In the crystal, the uncoordinated 3-nitro­benzoic acid and free 4,4′-bipyridine mol­ecules are linked alternately by O—H⋯N hydrogen bonds into chains, which are assembled by C—H⋯O hydrogen bonds into a three-dimensional supra­molecular network. International Union of Crystallography 2010-02-06 /pmc/articles/PMC2983553/ /pubmed/21580317 http://dx.doi.org/10.1107/S1600536810003594 Text en © Zhu et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Zhu, Zhen
Wang, Feng-Qin
Zhao, Yong-Nan
4,4′-Bipyridine–3-nitro­benzoic acid (1/2)
title 4,4′-Bipyridine–3-nitro­benzoic acid (1/2)
title_full 4,4′-Bipyridine–3-nitro­benzoic acid (1/2)
title_fullStr 4,4′-Bipyridine–3-nitro­benzoic acid (1/2)
title_full_unstemmed 4,4′-Bipyridine–3-nitro­benzoic acid (1/2)
title_short 4,4′-Bipyridine–3-nitro­benzoic acid (1/2)
title_sort 4,4′-bipyridine–3-nitro­benzoic acid (1/2)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983553/
https://www.ncbi.nlm.nih.gov/pubmed/21580317
http://dx.doi.org/10.1107/S1600536810003594
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