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2-Iodo-4,6-dimethyl­pyrimidine

In the title compound, C(6)H(7)IN(2), the non-H atoms of the mol­ecule are located on a crystallographic mirror plane; the H atoms of the methyl groups are therefore disordered over two positions of equal occupancy. In the crystal structure, short inter­molecular I⋯N contacts [3.390 (3) Å] are found...

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Autores principales: Jiang, Qing-Min, Mao, Gui-Yun, Hao, Lu-Ye, Hao, Xin-Qi, Song, Mao-Ping
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983557/
https://www.ncbi.nlm.nih.gov/pubmed/21580429
http://dx.doi.org/10.1107/S1600536810005660
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author Jiang, Qing-Min
Mao, Gui-Yun
Hao, Lu-Ye
Hao, Xin-Qi
Song, Mao-Ping
author_facet Jiang, Qing-Min
Mao, Gui-Yun
Hao, Lu-Ye
Hao, Xin-Qi
Song, Mao-Ping
author_sort Jiang, Qing-Min
collection PubMed
description In the title compound, C(6)H(7)IN(2), the non-H atoms of the mol­ecule are located on a crystallographic mirror plane; the H atoms of the methyl groups are therefore disordered over two positions of equal occupancy. In the crystal structure, short inter­molecular I⋯N contacts [3.390 (3) Å] are found, linking the mol­ecules into zigzag chains. In addition, there are inter­molecular π–π stacking inter­actions between the pyrimidine rings of adjacent mol­ecules [centroid–centroid distance = 3.5168 (10) Å], resulting in a two-dimensional supra­molecular architecture.
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spelling pubmed-29835572010-12-30 2-Iodo-4,6-dimethyl­pyrimidine Jiang, Qing-Min Mao, Gui-Yun Hao, Lu-Ye Hao, Xin-Qi Song, Mao-Ping Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(6)H(7)IN(2), the non-H atoms of the mol­ecule are located on a crystallographic mirror plane; the H atoms of the methyl groups are therefore disordered over two positions of equal occupancy. In the crystal structure, short inter­molecular I⋯N contacts [3.390 (3) Å] are found, linking the mol­ecules into zigzag chains. In addition, there are inter­molecular π–π stacking inter­actions between the pyrimidine rings of adjacent mol­ecules [centroid–centroid distance = 3.5168 (10) Å], resulting in a two-dimensional supra­molecular architecture. International Union of Crystallography 2010-02-24 /pmc/articles/PMC2983557/ /pubmed/21580429 http://dx.doi.org/10.1107/S1600536810005660 Text en © Jiang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Jiang, Qing-Min
Mao, Gui-Yun
Hao, Lu-Ye
Hao, Xin-Qi
Song, Mao-Ping
2-Iodo-4,6-dimethyl­pyrimidine
title 2-Iodo-4,6-dimethyl­pyrimidine
title_full 2-Iodo-4,6-dimethyl­pyrimidine
title_fullStr 2-Iodo-4,6-dimethyl­pyrimidine
title_full_unstemmed 2-Iodo-4,6-dimethyl­pyrimidine
title_short 2-Iodo-4,6-dimethyl­pyrimidine
title_sort 2-iodo-4,6-dimethyl­pyrimidine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983557/
https://www.ncbi.nlm.nih.gov/pubmed/21580429
http://dx.doi.org/10.1107/S1600536810005660
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