Cargando…
2-Iodo-4,6-dimethylpyrimidine
In the title compound, C(6)H(7)IN(2), the non-H atoms of the molecule are located on a crystallographic mirror plane; the H atoms of the methyl groups are therefore disordered over two positions of equal occupancy. In the crystal structure, short intermolecular I⋯N contacts [3.390 (3) Å] are found...
Autores principales: | , , , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983557/ https://www.ncbi.nlm.nih.gov/pubmed/21580429 http://dx.doi.org/10.1107/S1600536810005660 |
_version_ | 1782191900917235712 |
---|---|
author | Jiang, Qing-Min Mao, Gui-Yun Hao, Lu-Ye Hao, Xin-Qi Song, Mao-Ping |
author_facet | Jiang, Qing-Min Mao, Gui-Yun Hao, Lu-Ye Hao, Xin-Qi Song, Mao-Ping |
author_sort | Jiang, Qing-Min |
collection | PubMed |
description | In the title compound, C(6)H(7)IN(2), the non-H atoms of the molecule are located on a crystallographic mirror plane; the H atoms of the methyl groups are therefore disordered over two positions of equal occupancy. In the crystal structure, short intermolecular I⋯N contacts [3.390 (3) Å] are found, linking the molecules into zigzag chains. In addition, there are intermolecular π–π stacking interactions between the pyrimidine rings of adjacent molecules [centroid–centroid distance = 3.5168 (10) Å], resulting in a two-dimensional supramolecular architecture. |
format | Text |
id | pubmed-2983557 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29835572010-12-30 2-Iodo-4,6-dimethylpyrimidine Jiang, Qing-Min Mao, Gui-Yun Hao, Lu-Ye Hao, Xin-Qi Song, Mao-Ping Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(6)H(7)IN(2), the non-H atoms of the molecule are located on a crystallographic mirror plane; the H atoms of the methyl groups are therefore disordered over two positions of equal occupancy. In the crystal structure, short intermolecular I⋯N contacts [3.390 (3) Å] are found, linking the molecules into zigzag chains. In addition, there are intermolecular π–π stacking interactions between the pyrimidine rings of adjacent molecules [centroid–centroid distance = 3.5168 (10) Å], resulting in a two-dimensional supramolecular architecture. International Union of Crystallography 2010-02-24 /pmc/articles/PMC2983557/ /pubmed/21580429 http://dx.doi.org/10.1107/S1600536810005660 Text en © Jiang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Jiang, Qing-Min Mao, Gui-Yun Hao, Lu-Ye Hao, Xin-Qi Song, Mao-Ping 2-Iodo-4,6-dimethylpyrimidine |
title | 2-Iodo-4,6-dimethylpyrimidine |
title_full | 2-Iodo-4,6-dimethylpyrimidine |
title_fullStr | 2-Iodo-4,6-dimethylpyrimidine |
title_full_unstemmed | 2-Iodo-4,6-dimethylpyrimidine |
title_short | 2-Iodo-4,6-dimethylpyrimidine |
title_sort | 2-iodo-4,6-dimethylpyrimidine |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983557/ https://www.ncbi.nlm.nih.gov/pubmed/21580429 http://dx.doi.org/10.1107/S1600536810005660 |
work_keys_str_mv | AT jiangqingmin 2iodo46dimethylpyrimidine AT maoguiyun 2iodo46dimethylpyrimidine AT haoluye 2iodo46dimethylpyrimidine AT haoxinqi 2iodo46dimethylpyrimidine AT songmaoping 2iodo46dimethylpyrimidine |