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Azido(benzoylacetonato-κ(2) O,O′)[1-phenyl-3-(2-pyridylmethylimino)but-1-en-1-olato-κ(3) N,N′,O]cobalt(III)
In the title complex, [Co(C(16)H(15)N(2)O)(C(10)H(9)O(2))(N(3))], the Co(II) atom adopts an octahedral coordination geometry by a tridentate Schiff base, a bidentate benzoylacetonate and an azide ligand. The imine N atom of the tridentate ligand is trans to the benzoyl O atom of the bidentate liga...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983559/ https://www.ncbi.nlm.nih.gov/pubmed/21580204 http://dx.doi.org/10.1107/S1600536810003338 |
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| author | Datta, Amitabha Sie, Ming-Han Huang, Jui-Hsien Lee, Hon Man |
| author_facet | Datta, Amitabha Sie, Ming-Han Huang, Jui-Hsien Lee, Hon Man |
| author_sort | Datta, Amitabha |
| collection | PubMed |
| description | In the title complex, [Co(C(16)H(15)N(2)O)(C(10)H(9)O(2))(N(3))], the Co(II) atom adopts an octahedral coordination geometry by a tridentate Schiff base, a bidentate benzoylacetonate and an azide ligand. The imine N atom of the tridentate ligand is trans to the benzoyl O atom of the bidentate ligand and the azide ligand is trans to the acetyl O atom of the bidentate ligand. Non-classical intramolecular C(aryl)—H⋯O hydrogen bonds are present in the structure. |
| format | Text |
| id | pubmed-2983559 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29835592010-12-30 Azido(benzoylacetonato-κ(2) O,O′)[1-phenyl-3-(2-pyridylmethylimino)but-1-en-1-olato-κ(3) N,N′,O]cobalt(III) Datta, Amitabha Sie, Ming-Han Huang, Jui-Hsien Lee, Hon Man Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Co(C(16)H(15)N(2)O)(C(10)H(9)O(2))(N(3))], the Co(II) atom adopts an octahedral coordination geometry by a tridentate Schiff base, a bidentate benzoylacetonate and an azide ligand. The imine N atom of the tridentate ligand is trans to the benzoyl O atom of the bidentate ligand and the azide ligand is trans to the acetyl O atom of the bidentate ligand. Non-classical intramolecular C(aryl)—H⋯O hydrogen bonds are present in the structure. International Union of Crystallography 2010-02-03 /pmc/articles/PMC2983559/ /pubmed/21580204 http://dx.doi.org/10.1107/S1600536810003338 Text en © Datta et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Datta, Amitabha Sie, Ming-Han Huang, Jui-Hsien Lee, Hon Man Azido(benzoylacetonato-κ(2) O,O′)[1-phenyl-3-(2-pyridylmethylimino)but-1-en-1-olato-κ(3) N,N′,O]cobalt(III) |
| title | Azido(benzoylacetonato-κ(2)
O,O′)[1-phenyl-3-(2-pyridylmethylimino)but-1-en-1-olato-κ(3)
N,N′,O]cobalt(III) |
| title_full | Azido(benzoylacetonato-κ(2)
O,O′)[1-phenyl-3-(2-pyridylmethylimino)but-1-en-1-olato-κ(3)
N,N′,O]cobalt(III) |
| title_fullStr | Azido(benzoylacetonato-κ(2)
O,O′)[1-phenyl-3-(2-pyridylmethylimino)but-1-en-1-olato-κ(3)
N,N′,O]cobalt(III) |
| title_full_unstemmed | Azido(benzoylacetonato-κ(2)
O,O′)[1-phenyl-3-(2-pyridylmethylimino)but-1-en-1-olato-κ(3)
N,N′,O]cobalt(III) |
| title_short | Azido(benzoylacetonato-κ(2)
O,O′)[1-phenyl-3-(2-pyridylmethylimino)but-1-en-1-olato-κ(3)
N,N′,O]cobalt(III) |
| title_sort | azido(benzoylacetonato-κ(2)
o,o′)[1-phenyl-3-(2-pyridylmethylimino)but-1-en-1-olato-κ(3)
n,n′,o]cobalt(iii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983559/ https://www.ncbi.nlm.nih.gov/pubmed/21580204 http://dx.doi.org/10.1107/S1600536810003338 |
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