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catena-Poly[[[aqua(5-nitrobenzene-1,2,3-tricarboxylato-κO (1))nickel(II)]-di-μ-aqua-[diaquasodium]-di-μ-aqua] tetrahydrate]
In the title complex, {[NaNi(C(9)H(2)NO(8))(H(2)O)(7)]·4H(2)O}(n), the Ni(II) atom has a distorted octahedral coordination, defined by five O atoms from five water molecules and one O atom from one 5-nitrobenzene-1,2,3-tricarboxylate ligand. The Na cation is coordinated by six water O atoms in a...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983560/ https://www.ncbi.nlm.nih.gov/pubmed/21580274 http://dx.doi.org/10.1107/S1600536810006872 |
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author | Tan, Zheng-De Yi, Bing |
author_facet | Tan, Zheng-De Yi, Bing |
author_sort | Tan, Zheng-De |
collection | PubMed |
description | In the title complex, {[NaNi(C(9)H(2)NO(8))(H(2)O)(7)]·4H(2)O}(n), the Ni(II) atom has a distorted octahedral coordination, defined by five O atoms from five water molecules and one O atom from one 5-nitrobenzene-1,2,3-tricarboxylate ligand. The Na cation is coordinated by six water O atoms in an irregular trigonal-prismatic geometry. There are seven coordinated water molecules in the asymmetic unit. The Ni and Na atoms are linked by water bridges, forming infinite chains, which are connected by strong O—H⋯O hydrogen bonds involving the coordinated and uncoordinated water molecules into a three-dimensional network. |
format | Text |
id | pubmed-2983560 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29835602010-12-30 catena-Poly[[[aqua(5-nitrobenzene-1,2,3-tricarboxylato-κO (1))nickel(II)]-di-μ-aqua-[diaquasodium]-di-μ-aqua] tetrahydrate] Tan, Zheng-De Yi, Bing Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, {[NaNi(C(9)H(2)NO(8))(H(2)O)(7)]·4H(2)O}(n), the Ni(II) atom has a distorted octahedral coordination, defined by five O atoms from five water molecules and one O atom from one 5-nitrobenzene-1,2,3-tricarboxylate ligand. The Na cation is coordinated by six water O atoms in an irregular trigonal-prismatic geometry. There are seven coordinated water molecules in the asymmetic unit. The Ni and Na atoms are linked by water bridges, forming infinite chains, which are connected by strong O—H⋯O hydrogen bonds involving the coordinated and uncoordinated water molecules into a three-dimensional network. International Union of Crystallography 2010-02-27 /pmc/articles/PMC2983560/ /pubmed/21580274 http://dx.doi.org/10.1107/S1600536810006872 Text en © Tan and Yi 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Tan, Zheng-De Yi, Bing catena-Poly[[[aqua(5-nitrobenzene-1,2,3-tricarboxylato-κO (1))nickel(II)]-di-μ-aqua-[diaquasodium]-di-μ-aqua] tetrahydrate] |
title |
catena-Poly[[[aqua(5-nitrobenzene-1,2,3-tricarboxylato-κO
(1))nickel(II)]-di-μ-aqua-[diaquasodium]-di-μ-aqua] tetrahydrate] |
title_full |
catena-Poly[[[aqua(5-nitrobenzene-1,2,3-tricarboxylato-κO
(1))nickel(II)]-di-μ-aqua-[diaquasodium]-di-μ-aqua] tetrahydrate] |
title_fullStr |
catena-Poly[[[aqua(5-nitrobenzene-1,2,3-tricarboxylato-κO
(1))nickel(II)]-di-μ-aqua-[diaquasodium]-di-μ-aqua] tetrahydrate] |
title_full_unstemmed |
catena-Poly[[[aqua(5-nitrobenzene-1,2,3-tricarboxylato-κO
(1))nickel(II)]-di-μ-aqua-[diaquasodium]-di-μ-aqua] tetrahydrate] |
title_short |
catena-Poly[[[aqua(5-nitrobenzene-1,2,3-tricarboxylato-κO
(1))nickel(II)]-di-μ-aqua-[diaquasodium]-di-μ-aqua] tetrahydrate] |
title_sort | catena-poly[[[aqua(5-nitrobenzene-1,2,3-tricarboxylato-κo
(1))nickel(ii)]-di-μ-aqua-[diaquasodium]-di-μ-aqua] tetrahydrate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983560/ https://www.ncbi.nlm.nih.gov/pubmed/21580274 http://dx.doi.org/10.1107/S1600536810006872 |
work_keys_str_mv | AT tanzhengde catenapolyaqua5nitrobenzene123tricarboxylatoko1nickeliidimaquadiaquasodiumdimaquatetrahydrate AT yibing catenapolyaqua5nitrobenzene123tricarboxylatoko1nickeliidimaquadiaquasodiumdimaquatetrahydrate |