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catena-Poly[[[aqua­(5-nitro­benzene-1,2,3-tricarboxyl­ato-κO (1))nickel(II)]-di-μ-aqua-[diaqua­sodium]-di-μ-aqua] tetra­hydrate]

In the title complex, {[NaNi(C(9)H(2)NO(8))(H(2)O)(7)]·4H(2)O}(n), the Ni(II) atom has a distorted octa­hedral coordination, defined by five O atoms from five water mol­ecules and one O atom from one 5-nitro­benzene-1,2,3-tricarboxyl­ate ligand. The Na cation is coordinated by six water O atoms in a...

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Detalles Bibliográficos
Autores principales: Tan, Zheng-De, Yi, Bing
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983560/
https://www.ncbi.nlm.nih.gov/pubmed/21580274
http://dx.doi.org/10.1107/S1600536810006872
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author Tan, Zheng-De
Yi, Bing
author_facet Tan, Zheng-De
Yi, Bing
author_sort Tan, Zheng-De
collection PubMed
description In the title complex, {[NaNi(C(9)H(2)NO(8))(H(2)O)(7)]·4H(2)O}(n), the Ni(II) atom has a distorted octa­hedral coordination, defined by five O atoms from five water mol­ecules and one O atom from one 5-nitro­benzene-1,2,3-tricarboxyl­ate ligand. The Na cation is coordinated by six water O atoms in an irregular trigonal-prismatic geometry. There are seven coordinated water mol­ecules in the asymmetic unit. The Ni and Na atoms are linked by water bridges, forming infinite chains, which are connected by strong O—H⋯O hydrogen bonds involving the coordinated and uncoordinated water mol­ecules into a three-dimensional network.
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spelling pubmed-29835602010-12-30 catena-Poly[[[aqua­(5-nitro­benzene-1,2,3-tricarboxyl­ato-κO (1))nickel(II)]-di-μ-aqua-[diaqua­sodium]-di-μ-aqua] tetra­hydrate] Tan, Zheng-De Yi, Bing Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, {[NaNi(C(9)H(2)NO(8))(H(2)O)(7)]·4H(2)O}(n), the Ni(II) atom has a distorted octa­hedral coordination, defined by five O atoms from five water mol­ecules and one O atom from one 5-nitro­benzene-1,2,3-tricarboxyl­ate ligand. The Na cation is coordinated by six water O atoms in an irregular trigonal-prismatic geometry. There are seven coordinated water mol­ecules in the asymmetic unit. The Ni and Na atoms are linked by water bridges, forming infinite chains, which are connected by strong O—H⋯O hydrogen bonds involving the coordinated and uncoordinated water mol­ecules into a three-dimensional network. International Union of Crystallography 2010-02-27 /pmc/articles/PMC2983560/ /pubmed/21580274 http://dx.doi.org/10.1107/S1600536810006872 Text en © Tan and Yi 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Tan, Zheng-De
Yi, Bing
catena-Poly[[[aqua­(5-nitro­benzene-1,2,3-tricarboxyl­ato-κO (1))nickel(II)]-di-μ-aqua-[diaqua­sodium]-di-μ-aqua] tetra­hydrate]
title catena-Poly[[[aqua­(5-nitro­benzene-1,2,3-tricarboxyl­ato-κO (1))nickel(II)]-di-μ-aqua-[diaqua­sodium]-di-μ-aqua] tetra­hydrate]
title_full catena-Poly[[[aqua­(5-nitro­benzene-1,2,3-tricarboxyl­ato-κO (1))nickel(II)]-di-μ-aqua-[diaqua­sodium]-di-μ-aqua] tetra­hydrate]
title_fullStr catena-Poly[[[aqua­(5-nitro­benzene-1,2,3-tricarboxyl­ato-κO (1))nickel(II)]-di-μ-aqua-[diaqua­sodium]-di-μ-aqua] tetra­hydrate]
title_full_unstemmed catena-Poly[[[aqua­(5-nitro­benzene-1,2,3-tricarboxyl­ato-κO (1))nickel(II)]-di-μ-aqua-[diaqua­sodium]-di-μ-aqua] tetra­hydrate]
title_short catena-Poly[[[aqua­(5-nitro­benzene-1,2,3-tricarboxyl­ato-κO (1))nickel(II)]-di-μ-aqua-[diaqua­sodium]-di-μ-aqua] tetra­hydrate]
title_sort catena-poly[[[aqua­(5-nitro­benzene-1,2,3-tricarboxyl­ato-κo (1))nickel(ii)]-di-μ-aqua-[diaqua­sodium]-di-μ-aqua] tetra­hydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983560/
https://www.ncbi.nlm.nih.gov/pubmed/21580274
http://dx.doi.org/10.1107/S1600536810006872
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