Cargando…
2-Aminopyridinium trifluoroacetate
The asymmetric unit of the title compound, C(5)H(7)N(2) (+)·C(2)F(3)O(2) (−), contains four independent 2-aminopyridinium cations and four independent trifluoroacetate anions. In the crystal structure, these ions are linked by N—H⋯O hydrogen bonds, forming four cation–anion pairs each containing a...
Autores principales: | , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983566/ https://www.ncbi.nlm.nih.gov/pubmed/21580433 http://dx.doi.org/10.1107/S1600536810006392 |
Sumario: | The asymmetric unit of the title compound, C(5)H(7)N(2) (+)·C(2)F(3)O(2) (−), contains four independent 2-aminopyridinium cations and four independent trifluoroacetate anions. In the crystal structure, these ions are linked by N—H⋯O hydrogen bonds, forming four cation–anion pairs each containing an R (2) (2)(8) ring motif. The ion pairs are linked into two independent chains along [100] by N—H⋯O hydrogen bonds. In addition, C—H⋯O and C—H⋯F hydrogen bonds and π⋯π interactions [centoid–centroid separation = 3.6007 (17) Å] are observed. |
---|