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2-Aminopyridinium trifluoroacetate
The asymmetric unit of the title compound, C(5)H(7)N(2) (+)·C(2)F(3)O(2) (−), contains four independent 2-aminopyridinium cations and four independent trifluoroacetate anions. In the crystal structure, these ions are linked by N—H⋯O hydrogen bonds, forming four cation–anion pairs each containing a...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983566/ https://www.ncbi.nlm.nih.gov/pubmed/21580433 http://dx.doi.org/10.1107/S1600536810006392 |
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author | Hemamalini, Madhukar Fun, Hoong-Kun |
author_facet | Hemamalini, Madhukar Fun, Hoong-Kun |
author_sort | Hemamalini, Madhukar |
collection | PubMed |
description | The asymmetric unit of the title compound, C(5)H(7)N(2) (+)·C(2)F(3)O(2) (−), contains four independent 2-aminopyridinium cations and four independent trifluoroacetate anions. In the crystal structure, these ions are linked by N—H⋯O hydrogen bonds, forming four cation–anion pairs each containing an R (2) (2)(8) ring motif. The ion pairs are linked into two independent chains along [100] by N—H⋯O hydrogen bonds. In addition, C—H⋯O and C—H⋯F hydrogen bonds and π⋯π interactions [centoid–centroid separation = 3.6007 (17) Å] are observed. |
format | Text |
id | pubmed-2983566 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29835662010-12-30 2-Aminopyridinium trifluoroacetate Hemamalini, Madhukar Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(5)H(7)N(2) (+)·C(2)F(3)O(2) (−), contains four independent 2-aminopyridinium cations and four independent trifluoroacetate anions. In the crystal structure, these ions are linked by N—H⋯O hydrogen bonds, forming four cation–anion pairs each containing an R (2) (2)(8) ring motif. The ion pairs are linked into two independent chains along [100] by N—H⋯O hydrogen bonds. In addition, C—H⋯O and C—H⋯F hydrogen bonds and π⋯π interactions [centoid–centroid separation = 3.6007 (17) Å] are observed. International Union of Crystallography 2010-02-27 /pmc/articles/PMC2983566/ /pubmed/21580433 http://dx.doi.org/10.1107/S1600536810006392 Text en © Hemamalini and Fun 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Hemamalini, Madhukar Fun, Hoong-Kun 2-Aminopyridinium trifluoroacetate |
title | 2-Aminopyridinium trifluoroacetate |
title_full | 2-Aminopyridinium trifluoroacetate |
title_fullStr | 2-Aminopyridinium trifluoroacetate |
title_full_unstemmed | 2-Aminopyridinium trifluoroacetate |
title_short | 2-Aminopyridinium trifluoroacetate |
title_sort | 2-aminopyridinium trifluoroacetate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983566/ https://www.ncbi.nlm.nih.gov/pubmed/21580433 http://dx.doi.org/10.1107/S1600536810006392 |
work_keys_str_mv | AT hemamalinimadhukar 2aminopyridiniumtrifluoroacetate AT funhoongkun 2aminopyridiniumtrifluoroacetate |