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2-Amino­pyridinium trifluoro­acetate

The asymmetric unit of the title compound, C(5)H(7)N(2) (+)·C(2)F(3)O(2) (−), contains four independent 2-amino­pyridinium cations and four independent trifluoro­acetate anions. In the crystal structure, these ions are linked by N—H⋯O hydrogen bonds, forming four cation–anion pairs each containing a...

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Detalles Bibliográficos
Autores principales: Hemamalini, Madhukar, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983566/
https://www.ncbi.nlm.nih.gov/pubmed/21580433
http://dx.doi.org/10.1107/S1600536810006392
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author Hemamalini, Madhukar
Fun, Hoong-Kun
author_facet Hemamalini, Madhukar
Fun, Hoong-Kun
author_sort Hemamalini, Madhukar
collection PubMed
description The asymmetric unit of the title compound, C(5)H(7)N(2) (+)·C(2)F(3)O(2) (−), contains four independent 2-amino­pyridinium cations and four independent trifluoro­acetate anions. In the crystal structure, these ions are linked by N—H⋯O hydrogen bonds, forming four cation–anion pairs each containing an R (2) (2)(8) ring motif. The ion pairs are linked into two independent chains along [100] by N—H⋯O hydrogen bonds. In addition, C—H⋯O and C—H⋯F hydrogen bonds and π⋯π inter­actions [centoid–centroid separation = 3.6007 (17) Å] are observed.
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spelling pubmed-29835662010-12-30 2-Amino­pyridinium trifluoro­acetate Hemamalini, Madhukar Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(5)H(7)N(2) (+)·C(2)F(3)O(2) (−), contains four independent 2-amino­pyridinium cations and four independent trifluoro­acetate anions. In the crystal structure, these ions are linked by N—H⋯O hydrogen bonds, forming four cation–anion pairs each containing an R (2) (2)(8) ring motif. The ion pairs are linked into two independent chains along [100] by N—H⋯O hydrogen bonds. In addition, C—H⋯O and C—H⋯F hydrogen bonds and π⋯π inter­actions [centoid–centroid separation = 3.6007 (17) Å] are observed. International Union of Crystallography 2010-02-27 /pmc/articles/PMC2983566/ /pubmed/21580433 http://dx.doi.org/10.1107/S1600536810006392 Text en © Hemamalini and Fun 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Hemamalini, Madhukar
Fun, Hoong-Kun
2-Amino­pyridinium trifluoro­acetate
title 2-Amino­pyridinium trifluoro­acetate
title_full 2-Amino­pyridinium trifluoro­acetate
title_fullStr 2-Amino­pyridinium trifluoro­acetate
title_full_unstemmed 2-Amino­pyridinium trifluoro­acetate
title_short 2-Amino­pyridinium trifluoro­acetate
title_sort 2-amino­pyridinium trifluoro­acetate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983566/
https://www.ncbi.nlm.nih.gov/pubmed/21580433
http://dx.doi.org/10.1107/S1600536810006392
work_keys_str_mv AT hemamalinimadhukar 2aminopyridiniumtrifluoroacetate
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