Poly[[aqua­[μ-1,4-bis­(3-pyridylmeth­yl)piperazine-κ(2) N:N′](μ-isophthalato-κ(2) O (1):O (3))copper(II)]

In the title compound, [Cu(C(8)H(4)O(4))(C(16)H(20)N(4))(H(2)O)](n), square-pyramidally coordinated Cu(II) ions are linked into [Cu(H(2)O)(isophthalate)](n) coordination polymer chains by isophthalate dianions. These chains are connected into undulating [Cu(H(2)O)(isophthalate)(3-bpmp)](n) [3-bmp is...

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Detalles Bibliográficos
Autores principales: Gandolfo, Chaun M., LaDuca, Robert L.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983567/
https://www.ncbi.nlm.nih.gov/pubmed/21580257
http://dx.doi.org/10.1107/S160053681000632X
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author Gandolfo, Chaun M.
LaDuca, Robert L.
author_facet Gandolfo, Chaun M.
LaDuca, Robert L.
author_sort Gandolfo, Chaun M.
collection PubMed
description In the title compound, [Cu(C(8)H(4)O(4))(C(16)H(20)N(4))(H(2)O)](n), square-pyramidally coordinated Cu(II) ions are linked into [Cu(H(2)O)(isophthalate)](n) coordination polymer chains by isophthalate dianions. These chains are connected into undulating [Cu(H(2)O)(isophthalate)(3-bpmp)](n) [3-bmp is bis­(3-pyridylmeth­yl)piperazine] layers by 3-bpmp tethering ligands. The pseudo three-dimensional structure of the title compound is fostered by inter­layer O—H⋯O hydrogen bonding between the aqua ligands and unligated isophthalate O atoms. The selected crystal was non-merohedrally twinned. Only reflections from the major twin component were used in the solution and refinement.
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spelling pubmed-29835672010-12-30 Poly[[aqua­[μ-1,4-bis­(3-pyridylmeth­yl)piperazine-κ(2) N:N′](μ-isophthalato-κ(2) O (1):O (3))copper(II)] Gandolfo, Chaun M. LaDuca, Robert L. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(8)H(4)O(4))(C(16)H(20)N(4))(H(2)O)](n), square-pyramidally coordinated Cu(II) ions are linked into [Cu(H(2)O)(isophthalate)](n) coordination polymer chains by isophthalate dianions. These chains are connected into undulating [Cu(H(2)O)(isophthalate)(3-bpmp)](n) [3-bmp is bis­(3-pyridylmeth­yl)piperazine] layers by 3-bpmp tethering ligands. The pseudo three-dimensional structure of the title compound is fostered by inter­layer O—H⋯O hydrogen bonding between the aqua ligands and unligated isophthalate O atoms. The selected crystal was non-merohedrally twinned. Only reflections from the major twin component were used in the solution and refinement. International Union of Crystallography 2010-02-20 /pmc/articles/PMC2983567/ /pubmed/21580257 http://dx.doi.org/10.1107/S160053681000632X Text en © Gandolfo and LaDuca 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Gandolfo, Chaun M.
LaDuca, Robert L.
Poly[[aqua­[μ-1,4-bis­(3-pyridylmeth­yl)piperazine-κ(2) N:N′](μ-isophthalato-κ(2) O (1):O (3))copper(II)]
title Poly[[aqua­[μ-1,4-bis­(3-pyridylmeth­yl)piperazine-κ(2) N:N′](μ-isophthalato-κ(2) O (1):O (3))copper(II)]
title_full Poly[[aqua­[μ-1,4-bis­(3-pyridylmeth­yl)piperazine-κ(2) N:N′](μ-isophthalato-κ(2) O (1):O (3))copper(II)]
title_fullStr Poly[[aqua­[μ-1,4-bis­(3-pyridylmeth­yl)piperazine-κ(2) N:N′](μ-isophthalato-κ(2) O (1):O (3))copper(II)]
title_full_unstemmed Poly[[aqua­[μ-1,4-bis­(3-pyridylmeth­yl)piperazine-κ(2) N:N′](μ-isophthalato-κ(2) O (1):O (3))copper(II)]
title_short Poly[[aqua­[μ-1,4-bis­(3-pyridylmeth­yl)piperazine-κ(2) N:N′](μ-isophthalato-κ(2) O (1):O (3))copper(II)]
title_sort poly[[aqua­[μ-1,4-bis­(3-pyridylmeth­yl)piperazine-κ(2) n:n′](μ-isophthalato-κ(2) o (1):o (3))copper(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983567/
https://www.ncbi.nlm.nih.gov/pubmed/21580257
http://dx.doi.org/10.1107/S160053681000632X
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AT laducarobertl polyaquam14bis3pyridylmethylpiperazinek2nnmisophthalatok2o1o3copperii

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