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Bis{N,N,N-trimethyl-2-oxo-2-[2-(2,3,4- trihydroxybenzylidene)hydrazinyl]ethanaminium} tetrachloridozincate(II) methanol solvate
The asymmetric unit of the title compound, (C(12)H(18)N(3)O(4))(2)[ZnCl(4)]·CH(3)OH, consists of two Girard reagent-based cations, a tetrachloridozincate anion and a molecule of methanol as solvate. These components are interconnected in the crystal structure by an extensive network of O—H⋯O, N—...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983568/ https://www.ncbi.nlm.nih.gov/pubmed/21580264 http://dx.doi.org/10.1107/S160053681000615X |
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author | Novaković, Sladjana B. Drašković, Bojana M. Vojinović-Ješić, Ljiljana S. Češljević, Valerija I. Leovac, Vukadin M. |
author_facet | Novaković, Sladjana B. Drašković, Bojana M. Vojinović-Ješić, Ljiljana S. Češljević, Valerija I. Leovac, Vukadin M. |
author_sort | Novaković, Sladjana B. |
collection | PubMed |
description | The asymmetric unit of the title compound, (C(12)H(18)N(3)O(4))(2)[ZnCl(4)]·CH(3)OH, consists of two Girard reagent-based cations, a tetrachloridozincate anion and a molecule of methanol as solvate. These components are interconnected in the crystal structure by an extensive network of O—H⋯O, N—H⋯O, C—H⋯O, O—H⋯N, O—H⋯Cl, N—H⋯Cl and C—H⋯Cl hydrogen bonds. The shortest intermolecular interaction is realized between the cation and anion [H⋯Cl = 2.29 (5) Å; O—H⋯Cl = 167 (3)°]. C—H⋯O interactions also play a important role in the interconnection of the cations. |
format | Text |
id | pubmed-2983568 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29835682010-12-30 Bis{N,N,N-trimethyl-2-oxo-2-[2-(2,3,4- trihydroxybenzylidene)hydrazinyl]ethanaminium} tetrachloridozincate(II) methanol solvate Novaković, Sladjana B. Drašković, Bojana M. Vojinović-Ješić, Ljiljana S. Češljević, Valerija I. Leovac, Vukadin M. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, (C(12)H(18)N(3)O(4))(2)[ZnCl(4)]·CH(3)OH, consists of two Girard reagent-based cations, a tetrachloridozincate anion and a molecule of methanol as solvate. These components are interconnected in the crystal structure by an extensive network of O—H⋯O, N—H⋯O, C—H⋯O, O—H⋯N, O—H⋯Cl, N—H⋯Cl and C—H⋯Cl hydrogen bonds. The shortest intermolecular interaction is realized between the cation and anion [H⋯Cl = 2.29 (5) Å; O—H⋯Cl = 167 (3)°]. C—H⋯O interactions also play a important role in the interconnection of the cations. International Union of Crystallography 2010-02-24 /pmc/articles/PMC2983568/ /pubmed/21580264 http://dx.doi.org/10.1107/S160053681000615X Text en © Novaković et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Novaković, Sladjana B. Drašković, Bojana M. Vojinović-Ješić, Ljiljana S. Češljević, Valerija I. Leovac, Vukadin M. Bis{N,N,N-trimethyl-2-oxo-2-[2-(2,3,4- trihydroxybenzylidene)hydrazinyl]ethanaminium} tetrachloridozincate(II) methanol solvate |
title | Bis{N,N,N-trimethyl-2-oxo-2-[2-(2,3,4- trihydroxybenzylidene)hydrazinyl]ethanaminium} tetrachloridozincate(II) methanol solvate
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title_full | Bis{N,N,N-trimethyl-2-oxo-2-[2-(2,3,4- trihydroxybenzylidene)hydrazinyl]ethanaminium} tetrachloridozincate(II) methanol solvate
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title_fullStr | Bis{N,N,N-trimethyl-2-oxo-2-[2-(2,3,4- trihydroxybenzylidene)hydrazinyl]ethanaminium} tetrachloridozincate(II) methanol solvate
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title_full_unstemmed | Bis{N,N,N-trimethyl-2-oxo-2-[2-(2,3,4- trihydroxybenzylidene)hydrazinyl]ethanaminium} tetrachloridozincate(II) methanol solvate
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title_short | Bis{N,N,N-trimethyl-2-oxo-2-[2-(2,3,4- trihydroxybenzylidene)hydrazinyl]ethanaminium} tetrachloridozincate(II) methanol solvate
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title_sort | bis{n,n,n-trimethyl-2-oxo-2-[2-(2,3,4- trihydroxybenzylidene)hydrazinyl]ethanaminium} tetrachloridozincate(ii) methanol solvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983568/ https://www.ncbi.nlm.nih.gov/pubmed/21580264 http://dx.doi.org/10.1107/S160053681000615X |
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