Cargando…

Bis{N,N,N-trimethyl-2-oxo-2-[2-(2,3,4- trihydroxy­benzyl­idene)hydrazin­yl]ethanaminium} tetra­chlorido­zincate(II) methanol solvate

The asymmetric unit of the title compound, (C(12)H(18)N(3)O(4))(2)[ZnCl(4)]·CH(3)OH, consists of two Girard reagent-based cations, a tetra­chlorido­zincate anion and a mol­ecule of methanol as solvate. These components are inter­connected in the crystal structure by an extensive network of O—H⋯O, N—...

Descripción completa

Detalles Bibliográficos
Autores principales: Novaković, Sladjana B., Drašković, Bojana M., Vojinović-Ješić, Ljiljana S., Češljević, Valerija I., Leovac, Vukadin M.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983568/
https://www.ncbi.nlm.nih.gov/pubmed/21580264
http://dx.doi.org/10.1107/S160053681000615X
_version_ 1782191903495684096
author Novaković, Sladjana B.
Drašković, Bojana M.
Vojinović-Ješić, Ljiljana S.
Češljević, Valerija I.
Leovac, Vukadin M.
author_facet Novaković, Sladjana B.
Drašković, Bojana M.
Vojinović-Ješić, Ljiljana S.
Češljević, Valerija I.
Leovac, Vukadin M.
author_sort Novaković, Sladjana B.
collection PubMed
description The asymmetric unit of the title compound, (C(12)H(18)N(3)O(4))(2)[ZnCl(4)]·CH(3)OH, consists of two Girard reagent-based cations, a tetra­chlorido­zincate anion and a mol­ecule of methanol as solvate. These components are inter­connected in the crystal structure by an extensive network of O—H⋯O, N—H⋯O, C—H⋯O, O—H⋯N, O—H⋯Cl, N—H⋯Cl and C—H⋯Cl hydrogen bonds. The shortest inter­molecular inter­action is realized between the cation and anion [H⋯Cl = 2.29 (5) Å; O—H⋯Cl = 167 (3)°]. C—H⋯O inter­actions also play a important role in the inter­connection of the cations.
format Text
id pubmed-2983568
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29835682010-12-30 Bis{N,N,N-trimethyl-2-oxo-2-[2-(2,3,4- trihydroxy­benzyl­idene)hydrazin­yl]ethanaminium} tetra­chlorido­zincate(II) methanol solvate Novaković, Sladjana B. Drašković, Bojana M. Vojinović-Ješić, Ljiljana S. Češljević, Valerija I. Leovac, Vukadin M. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, (C(12)H(18)N(3)O(4))(2)[ZnCl(4)]·CH(3)OH, consists of two Girard reagent-based cations, a tetra­chlorido­zincate anion and a mol­ecule of methanol as solvate. These components are inter­connected in the crystal structure by an extensive network of O—H⋯O, N—H⋯O, C—H⋯O, O—H⋯N, O—H⋯Cl, N—H⋯Cl and C—H⋯Cl hydrogen bonds. The shortest inter­molecular inter­action is realized between the cation and anion [H⋯Cl = 2.29 (5) Å; O—H⋯Cl = 167 (3)°]. C—H⋯O inter­actions also play a important role in the inter­connection of the cations. International Union of Crystallography 2010-02-24 /pmc/articles/PMC2983568/ /pubmed/21580264 http://dx.doi.org/10.1107/S160053681000615X Text en © Novaković et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Novaković, Sladjana B.
Drašković, Bojana M.
Vojinović-Ješić, Ljiljana S.
Češljević, Valerija I.
Leovac, Vukadin M.
Bis{N,N,N-trimethyl-2-oxo-2-[2-(2,3,4- trihydroxy­benzyl­idene)hydrazin­yl]ethanaminium} tetra­chlorido­zincate(II) methanol solvate
title Bis{N,N,N-trimethyl-2-oxo-2-[2-(2,3,4- trihydroxy­benzyl­idene)hydrazin­yl]ethanaminium} tetra­chlorido­zincate(II) methanol solvate
title_full Bis{N,N,N-trimethyl-2-oxo-2-[2-(2,3,4- trihydroxy­benzyl­idene)hydrazin­yl]ethanaminium} tetra­chlorido­zincate(II) methanol solvate
title_fullStr Bis{N,N,N-trimethyl-2-oxo-2-[2-(2,3,4- trihydroxy­benzyl­idene)hydrazin­yl]ethanaminium} tetra­chlorido­zincate(II) methanol solvate
title_full_unstemmed Bis{N,N,N-trimethyl-2-oxo-2-[2-(2,3,4- trihydroxy­benzyl­idene)hydrazin­yl]ethanaminium} tetra­chlorido­zincate(II) methanol solvate
title_short Bis{N,N,N-trimethyl-2-oxo-2-[2-(2,3,4- trihydroxy­benzyl­idene)hydrazin­yl]ethanaminium} tetra­chlorido­zincate(II) methanol solvate
title_sort bis{n,n,n-trimethyl-2-oxo-2-[2-(2,3,4- trihydroxy­benzyl­idene)hydrazin­yl]ethanaminium} tetra­chlorido­zincate(ii) methanol solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983568/
https://www.ncbi.nlm.nih.gov/pubmed/21580264
http://dx.doi.org/10.1107/S160053681000615X
work_keys_str_mv AT novakovicsladjanab bisnnntrimethyl2oxo22234trihydroxybenzylidenehydrazinylethanaminiumtetrachloridozincateiimethanolsolvate
AT draskovicbojanam bisnnntrimethyl2oxo22234trihydroxybenzylidenehydrazinylethanaminiumtetrachloridozincateiimethanolsolvate
AT vojinovicjesicljiljanas bisnnntrimethyl2oxo22234trihydroxybenzylidenehydrazinylethanaminiumtetrachloridozincateiimethanolsolvate
AT cesljevicvalerijai bisnnntrimethyl2oxo22234trihydroxybenzylidenehydrazinylethanaminiumtetrachloridozincateiimethanolsolvate
AT leovacvukadinm bisnnntrimethyl2oxo22234trihydroxybenzylidenehydrazinylethanaminiumtetrachloridozincateiimethanolsolvate