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Bis(2-{[2,8-bis­(trifluoro­meth­yl)quinolin-4-yl](hydr­oxy)meth­yl}piperidin-1-ium) tetra­chloridodiphenyl­stannate(IV)

In the title salt, (C(17)H(17)F(6)N(2)O)(2)[Sn(C(6)H(5))(2)Cl(4)], the complete anion is generated by crystallograaphic inversion symmetry, giving a trans-SnC(2)Cl(4) octa­hedral coordination geometry for the metal atom. In the cation, the quinoline residue is almost normal to the other atoms, so th...

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Autores principales: Wardell, James L., Wardell, Solange M. S. V., Tiekink, Edward R. T., de Lima, Geraldo M.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983573/
https://www.ncbi.nlm.nih.gov/pubmed/21580269
http://dx.doi.org/10.1107/S1600536810006574
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author Wardell, James L.
Wardell, Solange M. S. V.
Tiekink, Edward R. T.
de Lima, Geraldo M.
author_facet Wardell, James L.
Wardell, Solange M. S. V.
Tiekink, Edward R. T.
de Lima, Geraldo M.
author_sort Wardell, James L.
collection PubMed
description In the title salt, (C(17)H(17)F(6)N(2)O)(2)[Sn(C(6)H(5))(2)Cl(4)], the complete anion is generated by crystallograaphic inversion symmetry, giving a trans-SnC(2)Cl(4) octa­hedral coordination geometry for the metal atom. In the cation, the quinoline residue is almost normal to the other atoms, so that the ion has an L-shaped conformation [the C—C—C—C torsion angle linking the fused-ring systems is 100.9 (7)°]; the six-membered piperidin-1-ium ring has a chair conformation. An intra­molecular N—H⋯O inter­action occurs. In the crystal, N—H⋯Cl and O—H⋯Cl hydrogen bonds link the components into a supra­molecular chain propagating along the a axis. C—H⋯Cl inter­actions are also present.
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spelling pubmed-29835732010-12-30 Bis(2-{[2,8-bis­(trifluoro­meth­yl)quinolin-4-yl](hydr­oxy)meth­yl}piperidin-1-ium) tetra­chloridodiphenyl­stannate(IV) Wardell, James L. Wardell, Solange M. S. V. Tiekink, Edward R. T. de Lima, Geraldo M. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title salt, (C(17)H(17)F(6)N(2)O)(2)[Sn(C(6)H(5))(2)Cl(4)], the complete anion is generated by crystallograaphic inversion symmetry, giving a trans-SnC(2)Cl(4) octa­hedral coordination geometry for the metal atom. In the cation, the quinoline residue is almost normal to the other atoms, so that the ion has an L-shaped conformation [the C—C—C—C torsion angle linking the fused-ring systems is 100.9 (7)°]; the six-membered piperidin-1-ium ring has a chair conformation. An intra­molecular N—H⋯O inter­action occurs. In the crystal, N—H⋯Cl and O—H⋯Cl hydrogen bonds link the components into a supra­molecular chain propagating along the a axis. C—H⋯Cl inter­actions are also present. International Union of Crystallography 2010-02-27 /pmc/articles/PMC2983573/ /pubmed/21580269 http://dx.doi.org/10.1107/S1600536810006574 Text en © Wardell et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wardell, James L.
Wardell, Solange M. S. V.
Tiekink, Edward R. T.
de Lima, Geraldo M.
Bis(2-{[2,8-bis­(trifluoro­meth­yl)quinolin-4-yl](hydr­oxy)meth­yl}piperidin-1-ium) tetra­chloridodiphenyl­stannate(IV)
title Bis(2-{[2,8-bis­(trifluoro­meth­yl)quinolin-4-yl](hydr­oxy)meth­yl}piperidin-1-ium) tetra­chloridodiphenyl­stannate(IV)
title_full Bis(2-{[2,8-bis­(trifluoro­meth­yl)quinolin-4-yl](hydr­oxy)meth­yl}piperidin-1-ium) tetra­chloridodiphenyl­stannate(IV)
title_fullStr Bis(2-{[2,8-bis­(trifluoro­meth­yl)quinolin-4-yl](hydr­oxy)meth­yl}piperidin-1-ium) tetra­chloridodiphenyl­stannate(IV)
title_full_unstemmed Bis(2-{[2,8-bis­(trifluoro­meth­yl)quinolin-4-yl](hydr­oxy)meth­yl}piperidin-1-ium) tetra­chloridodiphenyl­stannate(IV)
title_short Bis(2-{[2,8-bis­(trifluoro­meth­yl)quinolin-4-yl](hydr­oxy)meth­yl}piperidin-1-ium) tetra­chloridodiphenyl­stannate(IV)
title_sort bis(2-{[2,8-bis­(trifluoro­meth­yl)quinolin-4-yl](hydr­oxy)meth­yl}piperidin-1-ium) tetra­chloridodiphenyl­stannate(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983573/
https://www.ncbi.nlm.nih.gov/pubmed/21580269
http://dx.doi.org/10.1107/S1600536810006574
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