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Bis(2-{[2,8-bis(trifluoromethyl)quinolin-4-yl](hydroxy)methyl}piperidin-1-ium) tetrachloridodiphenylstannate(IV)
In the title salt, (C(17)H(17)F(6)N(2)O)(2)[Sn(C(6)H(5))(2)Cl(4)], the complete anion is generated by crystallograaphic inversion symmetry, giving a trans-SnC(2)Cl(4) octahedral coordination geometry for the metal atom. In the cation, the quinoline residue is almost normal to the other atoms, so th...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983573/ https://www.ncbi.nlm.nih.gov/pubmed/21580269 http://dx.doi.org/10.1107/S1600536810006574 |
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author | Wardell, James L. Wardell, Solange M. S. V. Tiekink, Edward R. T. de Lima, Geraldo M. |
author_facet | Wardell, James L. Wardell, Solange M. S. V. Tiekink, Edward R. T. de Lima, Geraldo M. |
author_sort | Wardell, James L. |
collection | PubMed |
description | In the title salt, (C(17)H(17)F(6)N(2)O)(2)[Sn(C(6)H(5))(2)Cl(4)], the complete anion is generated by crystallograaphic inversion symmetry, giving a trans-SnC(2)Cl(4) octahedral coordination geometry for the metal atom. In the cation, the quinoline residue is almost normal to the other atoms, so that the ion has an L-shaped conformation [the C—C—C—C torsion angle linking the fused-ring systems is 100.9 (7)°]; the six-membered piperidin-1-ium ring has a chair conformation. An intramolecular N—H⋯O interaction occurs. In the crystal, N—H⋯Cl and O—H⋯Cl hydrogen bonds link the components into a supramolecular chain propagating along the a axis. C—H⋯Cl interactions are also present. |
format | Text |
id | pubmed-2983573 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29835732010-12-30 Bis(2-{[2,8-bis(trifluoromethyl)quinolin-4-yl](hydroxy)methyl}piperidin-1-ium) tetrachloridodiphenylstannate(IV) Wardell, James L. Wardell, Solange M. S. V. Tiekink, Edward R. T. de Lima, Geraldo M. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title salt, (C(17)H(17)F(6)N(2)O)(2)[Sn(C(6)H(5))(2)Cl(4)], the complete anion is generated by crystallograaphic inversion symmetry, giving a trans-SnC(2)Cl(4) octahedral coordination geometry for the metal atom. In the cation, the quinoline residue is almost normal to the other atoms, so that the ion has an L-shaped conformation [the C—C—C—C torsion angle linking the fused-ring systems is 100.9 (7)°]; the six-membered piperidin-1-ium ring has a chair conformation. An intramolecular N—H⋯O interaction occurs. In the crystal, N—H⋯Cl and O—H⋯Cl hydrogen bonds link the components into a supramolecular chain propagating along the a axis. C—H⋯Cl interactions are also present. International Union of Crystallography 2010-02-27 /pmc/articles/PMC2983573/ /pubmed/21580269 http://dx.doi.org/10.1107/S1600536810006574 Text en © Wardell et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Wardell, James L. Wardell, Solange M. S. V. Tiekink, Edward R. T. de Lima, Geraldo M. Bis(2-{[2,8-bis(trifluoromethyl)quinolin-4-yl](hydroxy)methyl}piperidin-1-ium) tetrachloridodiphenylstannate(IV) |
title | Bis(2-{[2,8-bis(trifluoromethyl)quinolin-4-yl](hydroxy)methyl}piperidin-1-ium) tetrachloridodiphenylstannate(IV) |
title_full | Bis(2-{[2,8-bis(trifluoromethyl)quinolin-4-yl](hydroxy)methyl}piperidin-1-ium) tetrachloridodiphenylstannate(IV) |
title_fullStr | Bis(2-{[2,8-bis(trifluoromethyl)quinolin-4-yl](hydroxy)methyl}piperidin-1-ium) tetrachloridodiphenylstannate(IV) |
title_full_unstemmed | Bis(2-{[2,8-bis(trifluoromethyl)quinolin-4-yl](hydroxy)methyl}piperidin-1-ium) tetrachloridodiphenylstannate(IV) |
title_short | Bis(2-{[2,8-bis(trifluoromethyl)quinolin-4-yl](hydroxy)methyl}piperidin-1-ium) tetrachloridodiphenylstannate(IV) |
title_sort | bis(2-{[2,8-bis(trifluoromethyl)quinolin-4-yl](hydroxy)methyl}piperidin-1-ium) tetrachloridodiphenylstannate(iv) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983573/ https://www.ncbi.nlm.nih.gov/pubmed/21580269 http://dx.doi.org/10.1107/S1600536810006574 |
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