(8-Bromo-2-hydroxy-7-methoxy-1-naph­thyl)(4-chlorobenzoyl)methanone

In the title compound, C(18)H(12)BrClO(3), the naphthalene ring system and the benzene ring make a dihedral angle of 82.18 (9)°. The conformation around the central C=O group is such that the C=O bond vector forms a larger angle to the plane of the naphthalene ring system than to the plane of the be...

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Autores principales: Mitsui, Ryosuke, Nakaema, Kosuke, Nagasawa, Atsushi, Noguchi, Keiichi, Yonezawa, Noriyuki
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983574/
https://www.ncbi.nlm.nih.gov/pubmed/21580422
http://dx.doi.org/10.1107/S1600536810006185
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author Mitsui, Ryosuke
Nakaema, Kosuke
Nagasawa, Atsushi
Noguchi, Keiichi
Yonezawa, Noriyuki
author_facet Mitsui, Ryosuke
Nakaema, Kosuke
Nagasawa, Atsushi
Noguchi, Keiichi
Yonezawa, Noriyuki
author_sort Mitsui, Ryosuke
collection PubMed
description In the title compound, C(18)H(12)BrClO(3), the naphthalene ring system and the benzene ring make a dihedral angle of 82.18 (9)°. The conformation around the central C=O group is such that the C=O bond vector forms a larger angle to the plane of the naphthalene ring system than to the plane of the benzene ring, viz. 60.91 (16)° versus 13.94 (16)°. In the crystal structure, two π–π inter­actions formed between the naphthalene ring systems [centroid–centroid distances of 3.8014 (13) and 3.9823 (13) Å] and inter­molecular O—H⋯O and C—H⋯O hydrogen bonds are present.
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spelling pubmed-29835742010-12-30 (8-Bromo-2-hydroxy-7-methoxy-1-naph­thyl)(4-chlorobenzoyl)methanone Mitsui, Ryosuke Nakaema, Kosuke Nagasawa, Atsushi Noguchi, Keiichi Yonezawa, Noriyuki Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(18)H(12)BrClO(3), the naphthalene ring system and the benzene ring make a dihedral angle of 82.18 (9)°. The conformation around the central C=O group is such that the C=O bond vector forms a larger angle to the plane of the naphthalene ring system than to the plane of the benzene ring, viz. 60.91 (16)° versus 13.94 (16)°. In the crystal structure, two π–π inter­actions formed between the naphthalene ring systems [centroid–centroid distances of 3.8014 (13) and 3.9823 (13) Å] and inter­molecular O—H⋯O and C—H⋯O hydrogen bonds are present. International Union of Crystallography 2010-02-20 /pmc/articles/PMC2983574/ /pubmed/21580422 http://dx.doi.org/10.1107/S1600536810006185 Text en © Mitsui et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Mitsui, Ryosuke
Nakaema, Kosuke
Nagasawa, Atsushi
Noguchi, Keiichi
Yonezawa, Noriyuki
(8-Bromo-2-hydroxy-7-methoxy-1-naph­thyl)(4-chlorobenzoyl)methanone
title (8-Bromo-2-hydroxy-7-methoxy-1-naph­thyl)(4-chlorobenzoyl)methanone
title_full (8-Bromo-2-hydroxy-7-methoxy-1-naph­thyl)(4-chlorobenzoyl)methanone
title_fullStr (8-Bromo-2-hydroxy-7-methoxy-1-naph­thyl)(4-chlorobenzoyl)methanone
title_full_unstemmed (8-Bromo-2-hydroxy-7-methoxy-1-naph­thyl)(4-chlorobenzoyl)methanone
title_short (8-Bromo-2-hydroxy-7-methoxy-1-naph­thyl)(4-chlorobenzoyl)methanone
title_sort (8-bromo-2-hydroxy-7-methoxy-1-naph­thyl)(4-chlorobenzoyl)methanone
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983574/
https://www.ncbi.nlm.nih.gov/pubmed/21580422
http://dx.doi.org/10.1107/S1600536810006185
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AT nagasawaatsushi 8bromo2hydroxy7methoxy1naphthyl4chlorobenzoylmethanone
AT noguchikeiichi 8bromo2hydroxy7methoxy1naphthyl4chlorobenzoylmethanone
AT yonezawanoriyuki 8bromo2hydroxy7methoxy1naphthyl4chlorobenzoylmethanone

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