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2,7-Dimethoxy­-1-(4-nitro­benzo­yl)-naphthalene

In the title compound, C(19)H(15)NO(5), the dihedral angle between the naphthalene ring system and the benzene ring is 61.97 (5)°. The dihedral between the naphthalene ring system and the bridging carbonyl C—C(=O)—C plane is 54.68 (6)°, far larger than that [12.54 (7)°] between the phenyl group and...

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Autores principales: Watanabe, Shoji, Nakaema, Kosuke, Nishijima, Takahiro, Okamoto, Akiko, Yonezawa, Noriyuki
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983576/
https://www.ncbi.nlm.nih.gov/pubmed/21580373
http://dx.doi.org/10.1107/S1600536810005398
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author Watanabe, Shoji
Nakaema, Kosuke
Nishijima, Takahiro
Okamoto, Akiko
Yonezawa, Noriyuki
author_facet Watanabe, Shoji
Nakaema, Kosuke
Nishijima, Takahiro
Okamoto, Akiko
Yonezawa, Noriyuki
author_sort Watanabe, Shoji
collection PubMed
description In the title compound, C(19)H(15)NO(5), the dihedral angle between the naphthalene ring system and the benzene ring is 61.97 (5)°. The dihedral between the naphthalene ring system and the bridging carbonyl C—C(=O)—C plane is 54.68 (6)°, far larger than that [12.54 (7)°] between the phenyl group and the bridging carbonyl group. The nitro group and the phenyl ring are almost coplanar [O—N—C—C torsion angle = 2.94 (19)°]. In the crystal, mol­ecules are linked by C—H⋯π inter­actions and the phenyl rings are involved in a centrosymmetric π–π inter­action with a perpendicular distance of 3.523 Å and a lateral offset of 1.497 Å. In addition, weak inter­molecular C—H⋯O hydrogen bonds are formed between an H atom of one meth­oxy group and a nearby carbonyl O atom.
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spelling pubmed-29835762010-12-30 2,7-Dimethoxy­-1-(4-nitro­benzo­yl)-naphthalene Watanabe, Shoji Nakaema, Kosuke Nishijima, Takahiro Okamoto, Akiko Yonezawa, Noriyuki Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(19)H(15)NO(5), the dihedral angle between the naphthalene ring system and the benzene ring is 61.97 (5)°. The dihedral between the naphthalene ring system and the bridging carbonyl C—C(=O)—C plane is 54.68 (6)°, far larger than that [12.54 (7)°] between the phenyl group and the bridging carbonyl group. The nitro group and the phenyl ring are almost coplanar [O—N—C—C torsion angle = 2.94 (19)°]. In the crystal, mol­ecules are linked by C—H⋯π inter­actions and the phenyl rings are involved in a centrosymmetric π–π inter­action with a perpendicular distance of 3.523 Å and a lateral offset of 1.497 Å. In addition, weak inter­molecular C—H⋯O hydrogen bonds are formed between an H atom of one meth­oxy group and a nearby carbonyl O atom. International Union of Crystallography 2010-02-13 /pmc/articles/PMC2983576/ /pubmed/21580373 http://dx.doi.org/10.1107/S1600536810005398 Text en © Watanabe et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Watanabe, Shoji
Nakaema, Kosuke
Nishijima, Takahiro
Okamoto, Akiko
Yonezawa, Noriyuki
2,7-Dimethoxy­-1-(4-nitro­benzo­yl)-naphthalene
title 2,7-Dimethoxy­-1-(4-nitro­benzo­yl)-naphthalene
title_full 2,7-Dimethoxy­-1-(4-nitro­benzo­yl)-naphthalene
title_fullStr 2,7-Dimethoxy­-1-(4-nitro­benzo­yl)-naphthalene
title_full_unstemmed 2,7-Dimethoxy­-1-(4-nitro­benzo­yl)-naphthalene
title_short 2,7-Dimethoxy­-1-(4-nitro­benzo­yl)-naphthalene
title_sort 2,7-dimethoxy­-1-(4-nitro­benzo­yl)-naphthalene
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983576/
https://www.ncbi.nlm.nih.gov/pubmed/21580373
http://dx.doi.org/10.1107/S1600536810005398
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