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2,7-Dimethoxy-1-(4-nitrobenzoyl)-naphthalene
In the title compound, C(19)H(15)NO(5), the dihedral angle between the naphthalene ring system and the benzene ring is 61.97 (5)°. The dihedral between the naphthalene ring system and the bridging carbonyl C—C(=O)—C plane is 54.68 (6)°, far larger than that [12.54 (7)°] between the phenyl group and...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983576/ https://www.ncbi.nlm.nih.gov/pubmed/21580373 http://dx.doi.org/10.1107/S1600536810005398 |
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author | Watanabe, Shoji Nakaema, Kosuke Nishijima, Takahiro Okamoto, Akiko Yonezawa, Noriyuki |
author_facet | Watanabe, Shoji Nakaema, Kosuke Nishijima, Takahiro Okamoto, Akiko Yonezawa, Noriyuki |
author_sort | Watanabe, Shoji |
collection | PubMed |
description | In the title compound, C(19)H(15)NO(5), the dihedral angle between the naphthalene ring system and the benzene ring is 61.97 (5)°. The dihedral between the naphthalene ring system and the bridging carbonyl C—C(=O)—C plane is 54.68 (6)°, far larger than that [12.54 (7)°] between the phenyl group and the bridging carbonyl group. The nitro group and the phenyl ring are almost coplanar [O—N—C—C torsion angle = 2.94 (19)°]. In the crystal, molecules are linked by C—H⋯π interactions and the phenyl rings are involved in a centrosymmetric π–π interaction with a perpendicular distance of 3.523 Å and a lateral offset of 1.497 Å. In addition, weak intermolecular C—H⋯O hydrogen bonds are formed between an H atom of one methoxy group and a nearby carbonyl O atom. |
format | Text |
id | pubmed-2983576 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29835762010-12-30 2,7-Dimethoxy-1-(4-nitrobenzoyl)-naphthalene Watanabe, Shoji Nakaema, Kosuke Nishijima, Takahiro Okamoto, Akiko Yonezawa, Noriyuki Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(19)H(15)NO(5), the dihedral angle between the naphthalene ring system and the benzene ring is 61.97 (5)°. The dihedral between the naphthalene ring system and the bridging carbonyl C—C(=O)—C plane is 54.68 (6)°, far larger than that [12.54 (7)°] between the phenyl group and the bridging carbonyl group. The nitro group and the phenyl ring are almost coplanar [O—N—C—C torsion angle = 2.94 (19)°]. In the crystal, molecules are linked by C—H⋯π interactions and the phenyl rings are involved in a centrosymmetric π–π interaction with a perpendicular distance of 3.523 Å and a lateral offset of 1.497 Å. In addition, weak intermolecular C—H⋯O hydrogen bonds are formed between an H atom of one methoxy group and a nearby carbonyl O atom. International Union of Crystallography 2010-02-13 /pmc/articles/PMC2983576/ /pubmed/21580373 http://dx.doi.org/10.1107/S1600536810005398 Text en © Watanabe et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Watanabe, Shoji Nakaema, Kosuke Nishijima, Takahiro Okamoto, Akiko Yonezawa, Noriyuki 2,7-Dimethoxy-1-(4-nitrobenzoyl)-naphthalene |
title | 2,7-Dimethoxy-1-(4-nitrobenzoyl)-naphthalene |
title_full | 2,7-Dimethoxy-1-(4-nitrobenzoyl)-naphthalene |
title_fullStr | 2,7-Dimethoxy-1-(4-nitrobenzoyl)-naphthalene |
title_full_unstemmed | 2,7-Dimethoxy-1-(4-nitrobenzoyl)-naphthalene |
title_short | 2,7-Dimethoxy-1-(4-nitrobenzoyl)-naphthalene |
title_sort | 2,7-dimethoxy-1-(4-nitrobenzoyl)-naphthalene |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983576/ https://www.ncbi.nlm.nih.gov/pubmed/21580373 http://dx.doi.org/10.1107/S1600536810005398 |
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