catena-Poly[trimethyl­phenyl­ammonium [[bromidocad­mate(II)]-μ-bromido-μ-chlorido]]

In the title salt, (C(9)H(14)N)[CdBr(2)Cl], the Cd(II) atom is five-coordinated in a trigonal-bipyramidal coordination environment. All three of the halogen sites show disorder as a result of substitution of Cl for Br or Br for Cl. Two of the three halogen atoms are involved in bridging a pair of Cd...

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Detalles Bibliográficos
Autores principales: Lo, Kong Mun, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983584/
https://www.ncbi.nlm.nih.gov/pubmed/21580250
http://dx.doi.org/10.1107/S1600536810005817
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author Lo, Kong Mun
Ng, Seik Weng
author_facet Lo, Kong Mun
Ng, Seik Weng
author_sort Lo, Kong Mun
collection PubMed
description In the title salt, (C(9)H(14)N)[CdBr(2)Cl], the Cd(II) atom is five-coordinated in a trigonal-bipyramidal coordination environment. All three of the halogen sites show disorder as a result of substitution of Cl for Br or Br for Cl. Two of the three halogen atoms are involved in bridging a pair of Cd(II) atoms, generating a linear polyanionic chain motif.
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spelling pubmed-29835842010-12-30 catena-Poly[trimethyl­phenyl­ammonium [[bromidocad­mate(II)]-μ-bromido-μ-chlorido]] Lo, Kong Mun Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title salt, (C(9)H(14)N)[CdBr(2)Cl], the Cd(II) atom is five-coordinated in a trigonal-bipyramidal coordination environment. All three of the halogen sites show disorder as a result of substitution of Cl for Br or Br for Cl. Two of the three halogen atoms are involved in bridging a pair of Cd(II) atoms, generating a linear polyanionic chain motif. International Union of Crystallography 2010-02-17 /pmc/articles/PMC2983584/ /pubmed/21580250 http://dx.doi.org/10.1107/S1600536810005817 Text en © Lo and Ng 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Lo, Kong Mun
Ng, Seik Weng
catena-Poly[trimethyl­phenyl­ammonium [[bromidocad­mate(II)]-μ-bromido-μ-chlorido]]
title catena-Poly[trimethyl­phenyl­ammonium [[bromidocad­mate(II)]-μ-bromido-μ-chlorido]]
title_full catena-Poly[trimethyl­phenyl­ammonium [[bromidocad­mate(II)]-μ-bromido-μ-chlorido]]
title_fullStr catena-Poly[trimethyl­phenyl­ammonium [[bromidocad­mate(II)]-μ-bromido-μ-chlorido]]
title_full_unstemmed catena-Poly[trimethyl­phenyl­ammonium [[bromidocad­mate(II)]-μ-bromido-μ-chlorido]]
title_short catena-Poly[trimethyl­phenyl­ammonium [[bromidocad­mate(II)]-μ-bromido-μ-chlorido]]
title_sort catena-poly[trimethyl­phenyl­ammonium [[bromidocad­mate(ii)]-μ-bromido-μ-chlorido]]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983584/
https://www.ncbi.nlm.nih.gov/pubmed/21580250
http://dx.doi.org/10.1107/S1600536810005817
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