Tetra­aqua­bis(3-fluoro­pyridine-4-carboxyl­ato-κN)zinc(II) dihydrate

In the title compound, [Zn(C(6)H(3)FNO(2))(2)(H(2)O)(4)]·2H(2)O, the Zn(II) atom is octa­hedrally coordinated in a ZnO(4)N(2) environment by two 3-fluoro­pyridine-4-carboxyl­ate (3-fpy4-cbx) ligands and four water mol­ecules. The [Zn(3-fpy4-cbx)(2)(H(2)O)(4)] mol­ecules form a three-dimensional netw...

Descripción completa

Detalles Bibliográficos
Autores principales: Fleming, Jonetha, Kelley, Jennifer, Peterson, LeRoy, Smith, Mark D., zur Loye, Hans-Conrad
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983599/
https://www.ncbi.nlm.nih.gov/pubmed/21580201
http://dx.doi.org/10.1107/S1600536810003284
Descripción
Sumario:In the title compound, [Zn(C(6)H(3)FNO(2))(2)(H(2)O)(4)]·2H(2)O, the Zn(II) atom is octa­hedrally coordinated in a ZnO(4)N(2) environment by two 3-fluoro­pyridine-4-carboxyl­ate (3-fpy4-cbx) ligands and four water mol­ecules. The [Zn(3-fpy4-cbx)(2)(H(2)O)(4)] mol­ecules form a three-dimensional network through strong O—H⋯O and weak O—H⋯F hydrogen bonds between 3-fpy4-cbx and water mol­ecules. The crystal used for data collection was a twin, with the twin law corresponding to a 180° rotation about the real-space [001] axis. The major twin fraction refined to 0.795 (1).

Ejemplares similares