Tetra­aqua­bis(3-fluoro­pyridine-4-carboxyl­ato-κN)zinc(II) dihydrate

In the title compound, [Zn(C(6)H(3)FNO(2))(2)(H(2)O)(4)]·2H(2)O, the Zn(II) atom is octa­hedrally coordinated in a ZnO(4)N(2) environment by two 3-fluoro­pyridine-4-carboxyl­ate (3-fpy4-cbx) ligands and four water mol­ecules. The [Zn(3-fpy4-cbx)(2)(H(2)O)(4)] mol­ecules form a three-dimensional netw...

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Detalles Bibliográficos
Autores principales: Fleming, Jonetha, Kelley, Jennifer, Peterson, LeRoy, Smith, Mark D., zur Loye, Hans-Conrad
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983599/
https://www.ncbi.nlm.nih.gov/pubmed/21580201
http://dx.doi.org/10.1107/S1600536810003284
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author Fleming, Jonetha
Kelley, Jennifer
Peterson, LeRoy
Smith, Mark D.
zur Loye, Hans-Conrad
author_facet Fleming, Jonetha
Kelley, Jennifer
Peterson, LeRoy
Smith, Mark D.
zur Loye, Hans-Conrad
author_sort Fleming, Jonetha
collection PubMed
description In the title compound, [Zn(C(6)H(3)FNO(2))(2)(H(2)O)(4)]·2H(2)O, the Zn(II) atom is octa­hedrally coordinated in a ZnO(4)N(2) environment by two 3-fluoro­pyridine-4-carboxyl­ate (3-fpy4-cbx) ligands and four water mol­ecules. The [Zn(3-fpy4-cbx)(2)(H(2)O)(4)] mol­ecules form a three-dimensional network through strong O—H⋯O and weak O—H⋯F hydrogen bonds between 3-fpy4-cbx and water mol­ecules. The crystal used for data collection was a twin, with the twin law corresponding to a 180° rotation about the real-space [001] axis. The major twin fraction refined to 0.795 (1).
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spelling pubmed-29835992010-12-30 Tetra­aqua­bis(3-fluoro­pyridine-4-carboxyl­ato-κN)zinc(II) dihydrate Fleming, Jonetha Kelley, Jennifer Peterson, LeRoy Smith, Mark D. zur Loye, Hans-Conrad Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Zn(C(6)H(3)FNO(2))(2)(H(2)O)(4)]·2H(2)O, the Zn(II) atom is octa­hedrally coordinated in a ZnO(4)N(2) environment by two 3-fluoro­pyridine-4-carboxyl­ate (3-fpy4-cbx) ligands and four water mol­ecules. The [Zn(3-fpy4-cbx)(2)(H(2)O)(4)] mol­ecules form a three-dimensional network through strong O—H⋯O and weak O—H⋯F hydrogen bonds between 3-fpy4-cbx and water mol­ecules. The crystal used for data collection was a twin, with the twin law corresponding to a 180° rotation about the real-space [001] axis. The major twin fraction refined to 0.795 (1). International Union of Crystallography 2010-02-03 /pmc/articles/PMC2983599/ /pubmed/21580201 http://dx.doi.org/10.1107/S1600536810003284 Text en © Fleming et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Fleming, Jonetha
Kelley, Jennifer
Peterson, LeRoy
Smith, Mark D.
zur Loye, Hans-Conrad
Tetra­aqua­bis(3-fluoro­pyridine-4-carboxyl­ato-κN)zinc(II) dihydrate
title Tetra­aqua­bis(3-fluoro­pyridine-4-carboxyl­ato-κN)zinc(II) dihydrate
title_full Tetra­aqua­bis(3-fluoro­pyridine-4-carboxyl­ato-κN)zinc(II) dihydrate
title_fullStr Tetra­aqua­bis(3-fluoro­pyridine-4-carboxyl­ato-κN)zinc(II) dihydrate
title_full_unstemmed Tetra­aqua­bis(3-fluoro­pyridine-4-carboxyl­ato-κN)zinc(II) dihydrate
title_short Tetra­aqua­bis(3-fluoro­pyridine-4-carboxyl­ato-κN)zinc(II) dihydrate
title_sort tetra­aqua­bis(3-fluoro­pyridine-4-carboxyl­ato-κn)zinc(ii) dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983599/
https://www.ncbi.nlm.nih.gov/pubmed/21580201
http://dx.doi.org/10.1107/S1600536810003284
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AT smithmarkd tetraaquabis3fluoropyridine4carboxylatoknzinciidihydrate
AT zurloyehansconrad tetraaquabis3fluoropyridine4carboxylatoknzinciidihydrate

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