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Poly[[(2,2′-bipyridine)(μ(3)-2-sulfonatobenzoato)lead(II)] dihydrate]
In the title compound, {[Pb(sbc)(bpy)]·2H(2)O}(n) [bpy is 2,2′-bipyridine (C(10)H(8)N(2)) and sbc is the 2-sulfonatobenzoate dianion (C(7)H(4)O(5)S)], the Pb(II) ion is bonded to four O atoms including carboxylate and sulfonate from three sbc dianions, and two N atoms from a chelating 2,2′-bipyridi...
Autores principales: | , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983600/ https://www.ncbi.nlm.nih.gov/pubmed/21580252 http://dx.doi.org/10.1107/S1600536810005763 |
Sumario: | In the title compound, {[Pb(sbc)(bpy)]·2H(2)O}(n) [bpy is 2,2′-bipyridine (C(10)H(8)N(2)) and sbc is the 2-sulfonatobenzoate dianion (C(7)H(4)O(5)S)], the Pb(II) ion is bonded to four O atoms including carboxylate and sulfonate from three sbc dianions, and two N atoms from a chelating 2,2′-bipyridine ligand. The sbc ligand acts as a μ(3)-bridging ligand by one O atom of the sulfonate group and the two O atoms of the carboxylate. Of these two last O atoms, one builds up a dinuclear framework arranged around an inversion center whereas the second one links each dinuclear unit, forming a chain extending along the b axis. These polymeric chains are linked through O—H⋯O hydrogen bonds involving the water molecules, forming a layer parallel to (10[Image: see text]). |
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