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Poly[[(2,2′-bipyridine)(μ(3)-2-sulfonatobenzoato)lead(II)] dihydrate]
In the title compound, {[Pb(sbc)(bpy)]·2H(2)O}(n) [bpy is 2,2′-bipyridine (C(10)H(8)N(2)) and sbc is the 2-sulfonatobenzoate dianion (C(7)H(4)O(5)S)], the Pb(II) ion is bonded to four O atoms including carboxylate and sulfonate from three sbc dianions, and two N atoms from a chelating 2,2′-bipyridi...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983600/ https://www.ncbi.nlm.nih.gov/pubmed/21580252 http://dx.doi.org/10.1107/S1600536810005763 |
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author | Yang, Li-Qing Li, Xin-Hua |
author_facet | Yang, Li-Qing Li, Xin-Hua |
author_sort | Yang, Li-Qing |
collection | PubMed |
description | In the title compound, {[Pb(sbc)(bpy)]·2H(2)O}(n) [bpy is 2,2′-bipyridine (C(10)H(8)N(2)) and sbc is the 2-sulfonatobenzoate dianion (C(7)H(4)O(5)S)], the Pb(II) ion is bonded to four O atoms including carboxylate and sulfonate from three sbc dianions, and two N atoms from a chelating 2,2′-bipyridine ligand. The sbc ligand acts as a μ(3)-bridging ligand by one O atom of the sulfonate group and the two O atoms of the carboxylate. Of these two last O atoms, one builds up a dinuclear framework arranged around an inversion center whereas the second one links each dinuclear unit, forming a chain extending along the b axis. These polymeric chains are linked through O—H⋯O hydrogen bonds involving the water molecules, forming a layer parallel to (10[Image: see text]). |
format | Text |
id | pubmed-2983600 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29836002010-12-30 Poly[[(2,2′-bipyridine)(μ(3)-2-sulfonatobenzoato)lead(II)] dihydrate] Yang, Li-Qing Li, Xin-Hua Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Pb(sbc)(bpy)]·2H(2)O}(n) [bpy is 2,2′-bipyridine (C(10)H(8)N(2)) and sbc is the 2-sulfonatobenzoate dianion (C(7)H(4)O(5)S)], the Pb(II) ion is bonded to four O atoms including carboxylate and sulfonate from three sbc dianions, and two N atoms from a chelating 2,2′-bipyridine ligand. The sbc ligand acts as a μ(3)-bridging ligand by one O atom of the sulfonate group and the two O atoms of the carboxylate. Of these two last O atoms, one builds up a dinuclear framework arranged around an inversion center whereas the second one links each dinuclear unit, forming a chain extending along the b axis. These polymeric chains are linked through O—H⋯O hydrogen bonds involving the water molecules, forming a layer parallel to (10[Image: see text]). International Union of Crystallography 2010-02-17 /pmc/articles/PMC2983600/ /pubmed/21580252 http://dx.doi.org/10.1107/S1600536810005763 Text en © Yang and Li 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Yang, Li-Qing Li, Xin-Hua Poly[[(2,2′-bipyridine)(μ(3)-2-sulfonatobenzoato)lead(II)] dihydrate] |
title | Poly[[(2,2′-bipyridine)(μ(3)-2-sulfonatobenzoato)lead(II)] dihydrate] |
title_full | Poly[[(2,2′-bipyridine)(μ(3)-2-sulfonatobenzoato)lead(II)] dihydrate] |
title_fullStr | Poly[[(2,2′-bipyridine)(μ(3)-2-sulfonatobenzoato)lead(II)] dihydrate] |
title_full_unstemmed | Poly[[(2,2′-bipyridine)(μ(3)-2-sulfonatobenzoato)lead(II)] dihydrate] |
title_short | Poly[[(2,2′-bipyridine)(μ(3)-2-sulfonatobenzoato)lead(II)] dihydrate] |
title_sort | poly[[(2,2′-bipyridine)(μ(3)-2-sulfonatobenzoato)lead(ii)] dihydrate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983600/ https://www.ncbi.nlm.nih.gov/pubmed/21580252 http://dx.doi.org/10.1107/S1600536810005763 |
work_keys_str_mv | AT yangliqing poly22bipyridinem32sulfonatobenzoatoleadiidihydrate AT lixinhua poly22bipyridinem32sulfonatobenzoatoleadiidihydrate |