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Poly[[(2,2′-bipyridine)­(μ(3)-2-sulfonatobenzoato)lead(II)] dihydrate]

In the title compound, {[Pb(sbc)(bpy)]·2H(2)O}(n) [bpy is 2,2′-bipyridine (C(10)H(8)N(2)) and sbc is the 2-sulfonatobenzoate dianion (C(7)H(4)O(5)S)], the Pb(II) ion is bonded to four O atoms including carboxyl­ate and sulfonate from three sbc dianions, and two N atoms from a chelating 2,2′-bipyridi...

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Detalles Bibliográficos
Autores principales: Yang, Li-Qing, Li, Xin-Hua
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983600/
https://www.ncbi.nlm.nih.gov/pubmed/21580252
http://dx.doi.org/10.1107/S1600536810005763
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author Yang, Li-Qing
Li, Xin-Hua
author_facet Yang, Li-Qing
Li, Xin-Hua
author_sort Yang, Li-Qing
collection PubMed
description In the title compound, {[Pb(sbc)(bpy)]·2H(2)O}(n) [bpy is 2,2′-bipyridine (C(10)H(8)N(2)) and sbc is the 2-sulfonatobenzoate dianion (C(7)H(4)O(5)S)], the Pb(II) ion is bonded to four O atoms including carboxyl­ate and sulfonate from three sbc dianions, and two N atoms from a chelating 2,2′-bipyridine ligand. The sbc ligand acts as a μ(3)-bridging ligand by one O atom of the sulfonate group and the two O atoms of the carboxyl­ate. Of these two last O atoms, one builds up a dinuclear framework arranged around an inversion center whereas the second one links each dinuclear unit, forming a chain extending along the b axis. These polymeric chains are linked through O—H⋯O hydrogen bonds involving the water mol­ecules, forming a layer parallel to (10[Image: see text]).
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spelling pubmed-29836002010-12-30 Poly[[(2,2′-bipyridine)­(μ(3)-2-sulfonatobenzoato)lead(II)] dihydrate] Yang, Li-Qing Li, Xin-Hua Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Pb(sbc)(bpy)]·2H(2)O}(n) [bpy is 2,2′-bipyridine (C(10)H(8)N(2)) and sbc is the 2-sulfonatobenzoate dianion (C(7)H(4)O(5)S)], the Pb(II) ion is bonded to four O atoms including carboxyl­ate and sulfonate from three sbc dianions, and two N atoms from a chelating 2,2′-bipyridine ligand. The sbc ligand acts as a μ(3)-bridging ligand by one O atom of the sulfonate group and the two O atoms of the carboxyl­ate. Of these two last O atoms, one builds up a dinuclear framework arranged around an inversion center whereas the second one links each dinuclear unit, forming a chain extending along the b axis. These polymeric chains are linked through O—H⋯O hydrogen bonds involving the water mol­ecules, forming a layer parallel to (10[Image: see text]). International Union of Crystallography 2010-02-17 /pmc/articles/PMC2983600/ /pubmed/21580252 http://dx.doi.org/10.1107/S1600536810005763 Text en © Yang and Li 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yang, Li-Qing
Li, Xin-Hua
Poly[[(2,2′-bipyridine)­(μ(3)-2-sulfonatobenzoato)lead(II)] dihydrate]
title Poly[[(2,2′-bipyridine)­(μ(3)-2-sulfonatobenzoato)lead(II)] dihydrate]
title_full Poly[[(2,2′-bipyridine)­(μ(3)-2-sulfonatobenzoato)lead(II)] dihydrate]
title_fullStr Poly[[(2,2′-bipyridine)­(μ(3)-2-sulfonatobenzoato)lead(II)] dihydrate]
title_full_unstemmed Poly[[(2,2′-bipyridine)­(μ(3)-2-sulfonatobenzoato)lead(II)] dihydrate]
title_short Poly[[(2,2′-bipyridine)­(μ(3)-2-sulfonatobenzoato)lead(II)] dihydrate]
title_sort poly[[(2,2′-bipyridine)­(μ(3)-2-sulfonatobenzoato)lead(ii)] dihydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983600/
https://www.ncbi.nlm.nih.gov/pubmed/21580252
http://dx.doi.org/10.1107/S1600536810005763
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AT lixinhua poly22bipyridinem32sulfonatobenzoatoleadiidihydrate