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1,5-Bis[(E)-1-(2-hydroxyphenyl)ethylidene]thiocarbonohydrazide monohydrate
In the title compound, C(17)H(18)N(4)O(2)S·H(2)O, the thiourea derivative is almost planar, with an r.m.s. deviation for the non-H atoms of 0.057 Å. The hydroxyl groups lie to the same side of the molecule as the thione S atom, a conformation that allows the formation of intramolecular O—H⋯S and...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983601/ https://www.ncbi.nlm.nih.gov/pubmed/21580324 http://dx.doi.org/10.1107/S1600536810004241 |
Sumario: | In the title compound, C(17)H(18)N(4)O(2)S·H(2)O, the thiourea derivative is almost planar, with an r.m.s. deviation for the non-H atoms of 0.057 Å. The hydroxyl groups lie to the same side of the molecule as the thione S atom, a conformation that allows the formation of intramolecular O—H⋯S and O—H⋯N hydrogen bonds. In the crystal structure, the thiourea and water molecules self-assemble into a two-dimensional array by a combination of O(water)—H⋯O(hydroxyl), N—H⋯O(water) and O(water)—H⋯S hydrogen bonds and C—H⋯π interactions. |
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