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1,5-Bis[(E)-1-(2-hydroxyphenyl)ethylidene]thiocarbonohydrazide monohydrate
In the title compound, C(17)H(18)N(4)O(2)S·H(2)O, the thiourea derivative is almost planar, with an r.m.s. deviation for the non-H atoms of 0.057 Å. The hydroxyl groups lie to the same side of the molecule as the thione S atom, a conformation that allows the formation of intramolecular O—H⋯S and...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983601/ https://www.ncbi.nlm.nih.gov/pubmed/21580324 http://dx.doi.org/10.1107/S1600536810004241 |
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author | Affan, Md. Abu Chee, Dayang N. A. Ahmad, Fasihuddin B. Tiekink, Edward R. T. |
author_facet | Affan, Md. Abu Chee, Dayang N. A. Ahmad, Fasihuddin B. Tiekink, Edward R. T. |
author_sort | Affan, Md. Abu |
collection | PubMed |
description | In the title compound, C(17)H(18)N(4)O(2)S·H(2)O, the thiourea derivative is almost planar, with an r.m.s. deviation for the non-H atoms of 0.057 Å. The hydroxyl groups lie to the same side of the molecule as the thione S atom, a conformation that allows the formation of intramolecular O—H⋯S and O—H⋯N hydrogen bonds. In the crystal structure, the thiourea and water molecules self-assemble into a two-dimensional array by a combination of O(water)—H⋯O(hydroxyl), N—H⋯O(water) and O(water)—H⋯S hydrogen bonds and C—H⋯π interactions. |
format | Text |
id | pubmed-2983601 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29836012010-12-30 1,5-Bis[(E)-1-(2-hydroxyphenyl)ethylidene]thiocarbonohydrazide monohydrate Affan, Md. Abu Chee, Dayang N. A. Ahmad, Fasihuddin B. Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(17)H(18)N(4)O(2)S·H(2)O, the thiourea derivative is almost planar, with an r.m.s. deviation for the non-H atoms of 0.057 Å. The hydroxyl groups lie to the same side of the molecule as the thione S atom, a conformation that allows the formation of intramolecular O—H⋯S and O—H⋯N hydrogen bonds. In the crystal structure, the thiourea and water molecules self-assemble into a two-dimensional array by a combination of O(water)—H⋯O(hydroxyl), N—H⋯O(water) and O(water)—H⋯S hydrogen bonds and C—H⋯π interactions. International Union of Crystallography 2010-02-06 /pmc/articles/PMC2983601/ /pubmed/21580324 http://dx.doi.org/10.1107/S1600536810004241 Text en © Affan et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Affan, Md. Abu Chee, Dayang N. A. Ahmad, Fasihuddin B. Tiekink, Edward R. T. 1,5-Bis[(E)-1-(2-hydroxyphenyl)ethylidene]thiocarbonohydrazide monohydrate |
title | 1,5-Bis[(E)-1-(2-hydroxyphenyl)ethylidene]thiocarbonohydrazide monohydrate |
title_full | 1,5-Bis[(E)-1-(2-hydroxyphenyl)ethylidene]thiocarbonohydrazide monohydrate |
title_fullStr | 1,5-Bis[(E)-1-(2-hydroxyphenyl)ethylidene]thiocarbonohydrazide monohydrate |
title_full_unstemmed | 1,5-Bis[(E)-1-(2-hydroxyphenyl)ethylidene]thiocarbonohydrazide monohydrate |
title_short | 1,5-Bis[(E)-1-(2-hydroxyphenyl)ethylidene]thiocarbonohydrazide monohydrate |
title_sort | 1,5-bis[(e)-1-(2-hydroxyphenyl)ethylidene]thiocarbonohydrazide monohydrate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983601/ https://www.ncbi.nlm.nih.gov/pubmed/21580324 http://dx.doi.org/10.1107/S1600536810004241 |
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