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1,5-Bis[(E)-1-(2-hydroxyphenyl)ethyl­idene]thiocarbonohydrazide mono­hydrate

In the title compound, C(17)H(18)N(4)O(2)S·H(2)O, the thio­urea derivative is almost planar, with an r.m.s. deviation for the non-H atoms of 0.057 Å. The hydroxyl groups lie to the same side of the mol­ecule as the thione S atom, a conformation that allows the formation of intra­molecular O—H⋯S and...

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Autores principales: Affan, Md. Abu, Chee, Dayang N. A., Ahmad, Fasihuddin B., Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983601/
https://www.ncbi.nlm.nih.gov/pubmed/21580324
http://dx.doi.org/10.1107/S1600536810004241
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author Affan, Md. Abu
Chee, Dayang N. A.
Ahmad, Fasihuddin B.
Tiekink, Edward R. T.
author_facet Affan, Md. Abu
Chee, Dayang N. A.
Ahmad, Fasihuddin B.
Tiekink, Edward R. T.
author_sort Affan, Md. Abu
collection PubMed
description In the title compound, C(17)H(18)N(4)O(2)S·H(2)O, the thio­urea derivative is almost planar, with an r.m.s. deviation for the non-H atoms of 0.057 Å. The hydroxyl groups lie to the same side of the mol­ecule as the thione S atom, a conformation that allows the formation of intra­molecular O—H⋯S and O—H⋯N hydrogen bonds. In the crystal structure, the thio­urea and water mol­ecules self-assemble into a two-dimensional array by a combination of O(water)—H⋯O(hydrox­yl), N—H⋯O(water) and O(water)—H⋯S hydrogen bonds and C—H⋯π inter­actions.
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spelling pubmed-29836012010-12-30 1,5-Bis[(E)-1-(2-hydroxyphenyl)ethyl­idene]thiocarbonohydrazide mono­hydrate Affan, Md. Abu Chee, Dayang N. A. Ahmad, Fasihuddin B. Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(17)H(18)N(4)O(2)S·H(2)O, the thio­urea derivative is almost planar, with an r.m.s. deviation for the non-H atoms of 0.057 Å. The hydroxyl groups lie to the same side of the mol­ecule as the thione S atom, a conformation that allows the formation of intra­molecular O—H⋯S and O—H⋯N hydrogen bonds. In the crystal structure, the thio­urea and water mol­ecules self-assemble into a two-dimensional array by a combination of O(water)—H⋯O(hydrox­yl), N—H⋯O(water) and O(water)—H⋯S hydrogen bonds and C—H⋯π inter­actions. International Union of Crystallography 2010-02-06 /pmc/articles/PMC2983601/ /pubmed/21580324 http://dx.doi.org/10.1107/S1600536810004241 Text en © Affan et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Affan, Md. Abu
Chee, Dayang N. A.
Ahmad, Fasihuddin B.
Tiekink, Edward R. T.
1,5-Bis[(E)-1-(2-hydroxyphenyl)ethyl­idene]thiocarbonohydrazide mono­hydrate
title 1,5-Bis[(E)-1-(2-hydroxyphenyl)ethyl­idene]thiocarbonohydrazide mono­hydrate
title_full 1,5-Bis[(E)-1-(2-hydroxyphenyl)ethyl­idene]thiocarbonohydrazide mono­hydrate
title_fullStr 1,5-Bis[(E)-1-(2-hydroxyphenyl)ethyl­idene]thiocarbonohydrazide mono­hydrate
title_full_unstemmed 1,5-Bis[(E)-1-(2-hydroxyphenyl)ethyl­idene]thiocarbonohydrazide mono­hydrate
title_short 1,5-Bis[(E)-1-(2-hydroxyphenyl)ethyl­idene]thiocarbonohydrazide mono­hydrate
title_sort 1,5-bis[(e)-1-(2-hydroxyphenyl)ethyl­idene]thiocarbonohydrazide mono­hydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983601/
https://www.ncbi.nlm.nih.gov/pubmed/21580324
http://dx.doi.org/10.1107/S1600536810004241
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